The significance of transfer reactions in pulsed laser polymerization experiments

In this work simulation calculations are presented, which carefully analyze pulse initiated polymerization experiments of butyl acrylate in bulk in an extended temperature range published in the recent literature. Taking into account entire data sets of experimental results, a model has been developed which describes the experiments using a single parameter set. Especially the inadequacies in experiments are also captured by the model, that occur evaluating propagation rate coefficients using the pulsed laser polymerization technique at low laser repetition rates and elevated temperatures. Enhanced chain transfer to small species is identified to be responsible for these effects and transfer rate constants are derived from the simulations. The model is then used to test experimental strategies in order to expand the k_p determination towards temperatures higher than 35°C, the maximum temperature for which k_p values of butyl acrylate are available so far. Performing pulsed laser experiments at high laser repetition rates (200 Hz) and initial radical concentrations (1 · 10⁻⁴ mol/L) should prevent the formation of the characteristic structure in the molecular weight distribution to be suppressed by this competing process.     

Homological stability for the mapping class groups of non-orientable surfaces

We prove that the homology of the mapping class groups of non-orientable surfaces stabilizes with the genus of the surface. Combining our result with recent work of Madsen and Weiss, we obtain that the classifying space of the stable mapping class group of non-orientable surfaces, up to homology isomorphism, is the infinite loop space of a Thom spectrum built from the canonical bundle over the Grassmannians of 2-planes in ℝ ⁿ⁺². In particular, we show that the stable rational cohomology is a polynomial algebra on generators in degrees 4i – this is the non-oriented analogue of the Mumford conjecture.     

Amorphisation of GaN during processing with rare earth ion beams

GaN epilayers grown by metal organic chemical vapor deposition (MOCVD) were implanted with Tm and Eu ions with different energies and fluences and at different temperatures in order to optimize the implantation conditions. The recovery of the implantation damage was studied using both rapid thermal annealing and furnace annealing with nitrogen overpressure of 4×10⁵ Pa. Rutherford backscattering spectrometry in the channeling mode (RBS/C) was used to monitor the evolution of damage introduction and recovery in the Ga-sublattice and transmission electron microscopy (TEM) was carried out for further structural analysis. The RBS/C spectra as well as TEM images show two different damage regions, one at the surface arising from an amorphous surface layer and another one deeper in the crystal coinciding with the end of range of the implanted ions. For implantation with 150 keV at room temperature, even for fluences as low as 3×10¹⁴ at/cm², a thin amorphous surface layer, which becomes thicker with increasing implantation fluence, was observed by TEM. High temperature annealing of these highly damaged layers often results in loss of the amorphous layer and accumulation of the implanted species at the surface rather than a regrowth of the crystal. It was possible to prevent the formation of an amorphous layer by implanting at 500 C. In those samples a large part of the lattice damage was removed during annealing at 1000 C and the recovery of the lattice is similar for both applied annealing methods.     

Kondo effect of molecular complexes at surfaces: ligand control of the local spin coupling

The spin state of single magnetic atoms and molecules at surfaces is of fundamental interest and may play an important role in future atomic-scale technologies. We demonstrate the ability to tune the coupling between the spin of individual cobalt adatoms with their surroundings by controlled attachment of molecular ligands. The strength of the coupling is determined via the Kondo resonance by low-temperature scanning tunneling spectroscopy. Spatial Kondo resonance mapping is introduced as a novel imaging tool to localize spin centers in magnetic molecules with atomic precision.     

Measurement of the decay amplitudes of B0 --> J/psiK*0 and B(s)(0) --> J/psistraight phi decays

An angular analysis of B0-->J/psiK(*0) and B(0)(s)-->J/psistraight phi has been used to determine the decay amplitudes with parity-even longitudinal ( A0) and transverse ( A( parallel)) polarization and parity-odd transverse ( A( perpendicular)) polarization. The measurements are based on 190 B0 and 40 B(0)(s) candidates obtained from 89 pb(-1) of &pmacr;p collisions at the Fermilab Tevatron. The longitudinal decay amplitude dominates with |A0|(2) = 0.59+/-0. 06+/-0.01 for B0 and |A0|(2) = 0.61+/-0.14+/-0.02 for B(0)(s) decays. The parity-odd amplitude is found to be small with |A( perpendicular)|(2) = 0.13(+0.12)(-0.09)+/-0.06 for B0 and |A( perpendicular)|(2) = 0.23+/-0.19+/-0.04 for B(0)(s) decays.     

Measurement of b-quark fragmentation fractions in p&pmacr; collisions at sqrt

We have studied the production of B hadrons in 1.8-TeV pp[over ˉ] collisions. We present measurements of the fragmentation fractions, f_{u}, f_{d}, f_{s}, and f_{baryon}, of produced b quarks that yield B^{+}, B^{0}, B_{s}^{0}, and Λ[over ˉ]_{b}^{0} hadrons. Reconstruction of five electron-charm final states yields f_{s}/( f_{u}+f_{d})=0.213±0.068 and f_{baryon}/( f_{u}+f_{d})=0.118±0.042, assuming f_{u}=f_{d}. If all B hadrons produced in pp[over ˉ] collisions cascade to one of these four hadrons, we determine f_{u}=f_{d}=0.375±0.023, f_{s}=0.160±0.044, and f_{baryon}=0.090±0.029. If we do not assume f_{u}=f_{d}, we find f_{d}/f_{u}=0.84±0.16.