全文获取类型
收费全文 | 138篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 99篇 |
晶体学 | 3篇 |
力学 | 3篇 |
数学 | 6篇 |
物理学 | 32篇 |
出版年
2024年 | 2篇 |
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2015年 | 1篇 |
2014年 | 5篇 |
2013年 | 8篇 |
2012年 | 20篇 |
2011年 | 11篇 |
2010年 | 11篇 |
2009年 | 4篇 |
2008年 | 8篇 |
2007年 | 5篇 |
2006年 | 5篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有143条查询结果,搜索用时 31 毫秒
101.
Ghulam NabiChuanbao Cao Waheed S. KhanSajad Hussain Zahid UsmanMuhammad Safdar Sajjad Hussain ShahNoor Abass Din Khattak 《Applied Surface Science》2011,257(23):10289-10293
Dandelion-like gallium nitride (GaN) microstructures were successfully synthesized via Ni catalyst assisted chemical vapor deposition method at 1200 °C under NH3 atmosphere by pre-treating precursors with aqueous ammonia. The as-synthesized product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). X-ray diffraction analysis revealed that as-synthesized dandelion-like GaN was pure and has hexagonal wurtzite structure. SEM results showed that the size of the dandelion-like GaN structure was in the range of 30-60 μm. Dandelion-like GaN microstructures exhibited reasonable field emission properties with the turn-on field of 9.65 V μm−1 (0.01 mA cm−2) and threshold field of 11.35 V μm−1 (1 mA cm−2) which is sufficient for applications of electron emission devices, field emission displays and vacuum micro electronic devices. Optical properties were studied at room temperature by using fluorescence spectrophotometer. Photoluminescence (PL) measurements of dandelion-like GaN showed a strong near-band-edge emission at 370.2 nm (3.35 eV) with blue band emission at 450.4 nm (2.75 eV) and 465.2 nm (2.66 eV) but with out yellow band emission. The room-temperature photoluminescence properties showed that it has also potential application in light-emitting devices. The tentative growth mechanism for the growth of dandelion-like GaN was also described. 相似文献
102.
S. Waheed N. Siddique J. H. Zaidi 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(3):765-771
A proficiency test (PT) exercise was offered by the International Atomic Energy Agency (IAEA) for major, minor and trace elements
in Chinese ceramic reference material (IAEA-CU-2006-06). Neutron activation analysis (NAA) laboratory at PINSTECH, Pakistan
participated in the exercise and submitted the results for 28 elements. The aim of participation was to develop a suitable
methodology for accurate measurement of as many elements as possible in ceramic material using a low power reactor (PARR-2)
as this would help future investigation in a project on the authenticity of art objects, for provenance, conservation and
management of ancient cultural heritage of the country. After receiving the final report of the PT exercise, a critical review
of our data and final scoring of each element is made to check the suitability of our methodology and reliability of the acquired
data. Most of the reported results passed different statistical evaluation criterion such as relative bias, z-score and u-scores and ratio of our results and IAEA target values. One element (Yb) falls in the unacceptable range of relative bias
and z-scores. Hf and Tb showed slightly high z-scores within the questionable range. Ho, Mo and Sn were determined during this study but their results were not submitted
to the IAEA. The confidence of accuracy observed for most of the elements in ceramic material has made it mandatory to report
their results as information values. 相似文献
103.
In the continual search of new therapeutics, many possible drug candidates are excluded, because they are found to negatively affect mitochondrial function. We have developed an approach for directly, electrochemically assaying mitochondrial metabolic activity as a function of metabolic substrate to determine drug toxicity. By wiring mouse mitochondria to a carbon electrode surface, electrons can be intercepted before they reach Complex IV, the terminal step of electron transport chain. The electrons are rerouted, to a separate electrode of the electrochemical cell, the cathode. This allows for the direct measurement of electrical current and potential of the mitochondria during their oxidation of substrates such as pyruvate and fatty acids when there are different concentrations of drug present. This analytical technique has been shown to reliably assay several classical mitochondrial toxins and exhibits potential for the further development of a drug candidate screening technique, as well as other applications where the quantitative study of mitochondrial dysfunction is important. 相似文献
104.
A crystal growth rate equation, parameterized from molecular dynamics simulations of n‐alkanes, is compared to recent experiments on growth rates for polyethylene at high undercooling. The analysis reveals that the growth rate of alkanes and polyethylene can both be described by the same relationship. The appropriate relaxation time is used to describe the kinetic barrier to crystallization. For chains shorter than the entanglement length, this is the Rouse time. For chains longer than the entanglement molecular weight, kinetic limitations are modeled by the local relaxation of an entangled segment at the interface. This model supports a different mechanism for fast crystal growth at high undercooling than that usually inferred from slow growth data near the melting temperature. Use of the crystal growth rate model is illustrated for polyethylene crystallizing under conditions of slow cooling and fast cooling. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2468–2473, 2005 相似文献
105.
JinRong Wang Akbar Zada Hira Waheed 《Mathematical Methods in the Applied Sciences》2019,42(18):6706-6732
In this article, we study the existence and uniqueness of solution for a coupled system of nonlinear implicit fractional anti‐periodic boundary value problem. Further, we investigate different kinds of stability such as Ulam‐Hyers stability, generalized Ulam‐Hyers stability, Ulam‐Hyers‐Rassias stability, and generalized Ulam‐Hyers‐Rassias stability. We develop conditions for existence and uniqueness by using the classical fixed point theorem. Also, two examples are provided to illustrate the obtained results. 相似文献
106.
S. Waheed S. Rahman N. Siddique Y. Faiz 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(2):1453-1461
Eleven chelated calcium supplements intended for human consumption and produced by national and multinational companies have been studied for their mineral contents. Instrumental neutron activation analysis technique was used to quantify 12 elements (As, Br, Ce, Co, Cr, Fe, K, Na, Sb, Sn, Sr and Zn) while atomic absorption spectrometry technique quantified Cd, Cu and Ni. Three different irradiation protocols were adopted using a 27 kW tank-in-pool type miniature neutron source reactor. Most of the elements were present as minor or trace constituents except for Na that was quantified as major element in CaS-1 (3.73 %), CaS-2 (1.45 %), CaS-4 (1.56 %), CaS-5 (2.31 %), CaS-6 (1.84 %), CaS-7 (1.22), CaS-8 (1.73), CaS-9 (1.94), CaS-10 (2.07) and CaS-11 (2.48). However supplement CaS-3 with Ca source of calcium acetate contained only 53 μg/g of Na and the highest amount of Fe while As, Br, Cd and Sb were not detected in this sample. Percentage daily intakes with respect to their recommended dietary reference intake s and provisional tolerable daily intakes of essential and toxic elements showed that these elements contribute to a very low percentage of the recommended/tolerable levels for most of the supplements studied. Nevertheless the findings depict that it is very important for pharmaceutical and neutraceutical firms to completely identify these elements in the supplements and include their potency on the labels before being released to the consumers. 相似文献
107.
S. Waheed Y. Faiz S. Rahman N. Siddique 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(1):143-150
Geophagy of multani mitti (MM) clay is very common in central Pakistan especially amongst women. It was therefore mandatory to establish baseline levels of toxic elements in this clay for its safe dietary consumption by consumers of different genders, age groups and physical states. Instrumental neutron activation analysis and atomic absorption spectrometry techniques were used to determine the nutritional safety of MM clay for oral intake. All quantified toxic elements were detected at trace levels with composition in the descending order; Pb > Br > As > Sb > Hg > Cd. Comparison of these elements in MM clay with other clays shows that As, Cd, and Pb, are lowest in MM clay while its Br and Hg contents are high. Highest weekly dietary intakes of As, Br, Cd, Hg, and Sb were found to be 18, 0.05, 1.6, 9.2 and 1.1 % of the respective recommended provisional tolerable weekly intakes. The findings of this study show that As, Br, Cd, Hg and Sb in MM clay are well below the tolerance levels. However its Pb concentration is very high and may pose health concerns. The data presented in this study can be used as national base level guideline for geophagy of MM clay by men, women (normal, pregnant and lactating) and children. 相似文献
108.
The creation of iron-copper (Fe-Cu) alloys has practical application in improving the surface heat conduction and corrosion resistance of, for example, conformal cooling channels in steel moulds, but is difficult to achieve because the elements have got low inter-solubility and are prone to solidification cracking. Previous work by these authors has reported a method to produce a graded iron-nickel-copper coating in a single-step by direct diode laser deposition (DLD) of nickel wire and copper powder as a combined feedstock. This work investigates whether dual powder feeds can be used in that process to afford greater geometric flexibility and compares attributes of the ‘nickel wire and copper powder’ and ‘nickel powder and copper powder’ processes for deposition on a H13 tool steel substrate.In wire-powder deposition, a higher temperature developed in the melt pool causing a clad with a smooth gradient structure. The nickel powder in powder-powder deposition did not impart much heat into the melt pool so the melt pool solidified with sharp composition boundaries due to single metal melting in some parts. In wire-powder experiments, a graded structure was obtained by varying the flow rates of wire and powder. However, a graded structure was not realised in powder-powder experiments by varying either the feed or the directions. Reasons for the differences and flow patterns in the melt pools and their effect on final part properties of parts produced are discussed. 相似文献
109.
Amran Waheed Shahid Mahmud Muhammad Saleem Tayyaba Ahmad 《Journal of Saudi Chemical Society》2009,13(3):269-272
The constituents of total lipids and neutral lipid classes, i.e., hydrocarbons, wax esters, sterol esters, triacylglycerols, free fatty acids, 1,3-diacylglycerols, 1,2-diacylglycerols, free sterols, alcohols, and monoacylglycerols of three species of Citrus namely Citrus sinensis, Citrus paradisi, Citrus aurantium were investigated by thin layer and gas chromatography. Palmitic, oleic and linoleic acids were the major components in all the lipids and lipid classes studied. 相似文献
110.
Hitesh Chopra Protity Shuvra Dey Debashrita Das Tanima Bhattacharya Muddaser Shah Sidra Mubin Samka Peregrine Maishu Rokeya Akter Md. Habibur Rahman Chenmala Karthika Waheed Murad Naeem Qusty Safaa Qusti Eida M. Alshammari Gaber El-Saber Batiha Farag M. A. Altalbawy Mona I. M. Albooq Badrieah M. Alamri 《Molecules (Basel, Switzerland)》2021,26(16)