(Fe0.1Co0.55Ni0.35)78Si8B14金属玻璃的晶化过程及压力的影响(Ⅰ)——晶化时的相析出过程

用X射线衍射法研究了(Fe_0.1Co_0.55Ni_0.35)₇₈Si₈B₁₄金属玻璃在常压下及20kbar高压下晶化过程中的析出相及析出过程。结果表明在上述压力下晶化过程都分成两个阶段,分别对应于初级晶化和共晶晶化。在常压下,初级晶化时析出fcc-Co晶体,而共晶晶化对应着Ni₃₁Si₁₂和(FeCoNi)₃(SiB)相的析出。随着回火温度的增高或时间的延长,(FeCoNi)₃(SiB)相逐渐转变为(FeCoNi)₂₃B₆相。20kbar高压下的晶化析出过程与常压下不同的是:提高了晶化温度,在共晶晶化阶段出现了Co₂B相。此外,压力还阻止(FeCoNi)₂₃B₆相的形成。从热力学和动力学的角度讨论了压力对金属玻璃晶化过程的影响。 关键词：     

光解水α-Fe2O3电极表面的研究

本文利用Ar⁺轰击正分的α-Fe₂O₃表面,证明了轰击后的表面呈类FeO性质,存在Fe⁺⁺。提出了由于表面Fe⁺⁺的3d电子的催化作用,Fe⁺⁺能把吸附在它上面的H₂O先分解成OH-和H⁺,因而有助于提高光解水的效率的看法。用UPS和XPS等技术证实了类FeO表面吸附水后存在OH^-,确认Fe^{++关键词：}     

Study of Intramolecular Cyclization of N-styryl-oxo-cinnamides (Ⅱ)

lnthepreviouspaper',wereportedtheintramolecularcyclizationsofamide4anditscis-eneisomerinanattempttosynthesizehomoclausenamideandzetaclausenamide2.Inordertostudytherelationshipbetweenthestereochemistryandtheilltramolecularcyclizationofthisseriesofcompounds,theamides5(cis-oxirane,trans-ene)and8(cis-oxirane,cis-ene)wereprepared,andtheirintramolecularcyclizationswerereportedinthispaper.Theamide5withm.p.152.O-l54.O"CwasobtainedfromDarzen'scondensationofcompound3withPhCHOinMeOHatl5-2OoCwithMeO…     

HILBERTIAN INVARIANCE PRINCIPLE FOR EMPIRICAL PROCESS ASSOCIATED WITH A MARKOV PROCESS

The authors establish the Hilbertian invariance principle for the empirical process of a stationary Markov process, by extending the forward-backward martingale decomposition of Lyons-Meyer-Zheng to the Hilbert space valued additive functionals associated with general non-reversible Markov processes.     

LiNbO3:Fe晶体中调制双光束耦合衍射效率的测定

通过对LiNbO₃:Fe晶体中双光束耦合中的任一束光强进行低频调制,其衍射效率比无调制时提高两倍多(由30％提高到76％)。用运动光栅理论解释了这一实验结果。 关键词：     

KNbO3：Fe晶体的时间微分效应及图像追踪

本文观察到了KNbO_3:Fe晶体的时间微分效应,并用这个微分效应进行了图像追踪的演示,为KNbO_3:Fe晶体在光折变器件领域的应用进行了有益的探索。     

The Expansion Method of Mixed Basis Vectors of Lower-energy States and Harmonic Oscillators in Calculation of Bound States of Few-Body Systems

In this paper,the harmonic oscillator approach to the bound states of few-body ststems is developed and the lower-energy states are introduced as basis vectors and mixed with a part of harmonic oscillator vectors to calculate the binding energy.The lower energy levels of 3-α system and ⁹Be are presented and compared with experiments or other calculations.The results are satisfactory.     

The Kondo Problem as the Quantum Sine-Gordon Model

The ground-state properties of the Kondo Hamiltonian is analyzed in detail and we find the problem to be exactly equivalent to a modified quantum sine-Gordon model. Paralleling to the renormalization-group theory of the sine-Gordon model, we easily derive the correct next-to-leading order flow equations and obtain a universal quantity in a linear combination of the coefficients of the higher-order terms.     

“虚墙”法及其在交通噪声计算中的应用

本文提出“虚墙”法作为众所周知的虚声源法的对偶,并将它应用于车行隧道和城市街道等混响声场的交通噪声计算。根据这个概念,由单车种等间距分布的车流所产生的声场可等效于位于—对假想的刚硬墙壁之间的单一车辆所产生的声场。这对虚墙与隧道或街道的边界形成一个围闭空间,使得经典室内声压级计算公式可以应用于计算交通噪声混响声压级。本文还给出两个应用实例与实测数据相比较。     

GM(1,1)改进模型及其应用

根据 GM( 1 ,1 )灰色模型的指数特性 ,通过在区间上求积分给出了关于背景值的一个比较确切的计算公式 ,讨论了由此建立的 GM( 1 ,1 )改进模型的适用范围和预测精度 .结果表明改进模型比原 GM( 1 ,1 )模型适用性要强、模拟和预测精度要高 ,不仅适用于低增长序列、也适用于高增长序列 ,不仅适用于短期预测 ,同样也适用于中、长期预测