邻苯二甲酸二丁酯对雌二醇与血清组分结合的影响

利用紫外分光光度法测定了邻苯二甲酸二丁酯 (DBP)、雌二醇 (E2 )与血清组分 3种物质间两两结合的二元体系和三元体系结合常数。结果表明 ,DBP、血清组分和 E2 三者之间能两两结合 ,其中以 E2 与血清组分的结合能力最强。当三者处于同一体系中 ,随着 DBP浓度的增加 ,E2 与血清组分 - DBP二元体系间的结合常数也逐渐增加 ,其最大值高出正常 E2 与血清组分结合常数 (7.5 4× 10 4mol-1· L )近一个数量级。这表明 ,DBP的存在可能不会与 E2 对血清组分进行竞争结合 ,但由于本身的结合特点 ,会减少血液中游离E2 的含量 ,从而影响细胞内雌激素的平衡     

Speciation Analysis of Inorganic Tin (Sn(II)/Sn(IV)) by Graphite Furnace Atomic Absorption Spectrometry Following Ion-Exchange Separation

A new method based on anion exchange resin separation and graphite furnace atomic absorption spectrometry (GFAAS) detection is proposed for the determination of inorganic tin species. The result showed that Sn(IV) was quantitatively retained on the resin when [HCl] = 9.0 mol · L⁻¹, but Sn(II) could not be adsorbed on the resin under the same condition. Thus, a separation of Sn(II) and Sn(IV) has been realized. When the concentration of NaOH solution was between 2.0–7.0 mol · L⁻¹, Sn(IV) that adsorbed on the resin could be eluated from the resin completely. Meanwhile, under the atmosphere and the nitrogen states, the translation between Sn(II) and Sn(IV) was investigated. Under the optimal conditions, the detection limit of Sn(IV) is 0.40 μg · L⁻¹ with RSD of 2.3% (n = 5, c = 2.0 μg · L⁻¹). The proposed method was applied to the speciation analysis of tin in different water samples and the recovery of total Sn was in the range of 98.7–101.7%. In order to verify the accuracy of the method, a certified reference water sample was analyzed and the results obtained were in good agreement with the certified value.     

VALENCE AND EMISSION OF SAMARIUM IONS IN KMF(M:Mg、Ca)

The SmF_(2.01)was synthesized by reducing SmF_3 in H_2 stream.As it was doped inKM_gF_3 and KCaF_3.there was emission of Sm~(2+) in KMgF_3 but no emission of Sm~(2+) inKCaF_3 was observed.     

Fourier regularization for a backward heat equation

In this paper a simple and convenient new regularization method for solving backward heat equation—Fourier regularization method is given. Meanwhile, some quite sharp error estimates between the approximate solution and exact solution are provided. A numerical example also shows that the method works effectively.     

基于分形维数的液体爆炸分散中界面破碎形态研究

通过对爆炸抛撒图象的处理,得到液体界面的曲线.采用盒维数的计算方式,计算界面曲线的分形维数.通过对各时刻液体界面分形维数的变化研究,分析爆炸抛撒近场阶段的变化过程,同时观察到蘑菇状尖顶的出现与破碎,以及空化区域的形成和消失现象。     

Crystallographic report: Bis(norfloxacin)dilead(II) tetranitrate, [Pb2(H‐Norf)2(ONO2)4]

The centrosymmetric binuclear structure of [Pb₂(H‐Norf)₂(ONO₂)₄]shows the geometry around each lead(II) atom to be distorted trigonal bipyramidal with Pb–O distances ranging from 2.357(3) to 2.769(4) Å. Copyright © 2003 John Wiley & Sons, Ltd.     

产品销售相关环境下的提成率研究

以往多产品销售的最优提成率研究多基于多产品销售相互独立的假设之上。本文将一种多产品销售的合同模型拓展到产品销售相互影响的环境中,对不同的销售相关性情况下销售提成率的设置进行了分析,推出了不同情况下各产品提成率之间的关系特点和指导性结论。最后研究了当厂商兼顾短期利润和长期利润时对主副产品销售提成率的影响,提出了根据产品所处生命周期的不同阶段,用价值权重向量来动态调整、优化负责销售主、副产品的销售人员薪酬合同参数设计的方法。     

良序套张量积的代数中的强不可约算子

设Ｈ为复的可分无限维Ｈｉｌｂｅｒｔ空间，称有界线性算子Ｔ为强不可约的，如果与Ｔ可交换的幂等算子只有０和Ｉ．王宗尧、蒋春澜、纪有清等人证明了在任何一个套的套代数中都存在大量的强不可约算子，并且找到了它们的酉轨道闭包．本文考虑有限个套的张量积的代数中强不可约算子的存在性问题。证明了：对复平面上任何一个连通完备集σ、总存在一个对角算子Ｎ和它的一个范数可以任意小的紧摄动Ｔ＝Ｘ＋Ｋ，使得Ｔ是一个强不可约算子、Ｔ在有限个良序套的张量积的代数中，并且σ（Ｔ）＝σｌｒｅ（Ｔ）＝σ（Ｎ）＝σｌｒｅ（Ｎ）＝σ进一步，文章还对具有单点谱的算子和良序套与正交补为良序套的张量积的代数进行了讨论，得到了一些结果．     

新型AFM探针的制备及应用

采用熔拉 -腐蚀复合方法 ,将普通单模石英光纤制成直锥形光纤探针。利用自制工具将探针打弯 ,制成悬臂式光纤探针 ,在AFM上取得了较理想的测试结果。将自制光纤探针和商用硅材料探针获得的两种扫描图像进行了对比 ,分析了悬臂式光纤探针的特点