反相高效液相色谱法测定肾复康胶囊中的野黄芩苷和芦丁

建立了肾复康胶囊中野黄芩苷和芦丁的反相高效液相色谱测定方法。以甲醇-水为提取溶剂,采用超声提取法对样品进行前处理。以0.02 mol/L磷酸二氢钾缓冲溶液(含1.0％（体积分数）冰醋酸)-甲醇（体积比为63∶37）为流动相,于330 nm波长下检测,肾复康提取液中野黄芩苷和芦丁可达基线分离,分析时间在20 min内。野黄芩苷和芦丁在10 ~300 mg/L内,其峰面积与浓度之间线性关系良好,目标物的加标回收率大于98％。该方法适用于肾复康胶囊及相关药材中野黄芩苷和芦丁黄酮类化合物的测定和质量控制。     

多波长线性回归紫外分光光度法同时测定复方阿斯匹林片中的三组分

用改进的多波长线性回归分光光度法同时测定了复方阿期匹林片中三组分的含量,模拟样品中阿斯匹林、非那西丁、咖啡因的平均回收率分别为１００．３１％、９９．８７％、１００．７７％,相对标准偏差分别为０．３５％、０．２５％、１．３７％（ｎ＝１０）。对四个批号实际样品的测定结果与标准方法一致,适物复方阿斯匹林片的常规分析。     

研究型仪器分析实验:改进QuEChERS法提取水产品中邻苯二甲酸酯类增塑剂

以近年来食品安全检测样品前处理研究为基础,探索了一个由科研成果“改进QuEChERS法提取测定水产品中邻苯二甲酸酯类增塑剂”设计转化而成的研究型仪器分析实验。以环境友好的改进型QuEChERS前处理技术,结合气相色谱-质谱法,成功检测了水产品中邻苯二甲酸酯(PAEs)。在教学实践中学生全程参与了实验项目的文献检索、实验设计及实验结果与讨论等工作,激发了学生的学习热情与学习主动性,同时也提高了学生的科研能力与论文写作能力。     

6-甲氧羰基-4,4'-二甲基-2,2'-联吡啶单核铜(Ⅰ)双膦发光配合物

合成并表征了2个新的基于6-甲氧羰基-4,4''-二甲基-2,2''-联吡啶的单核铜（Ⅰ）双膦配合物[Cu（mmbpy）（dppp）]ClO₄（1）和[Cu（mmbpy）（dppb）]ClO₄（2）。研究结果表明,铜（Ⅰ）配合物1和2均表现为扭曲变形的N₂P₂四面体几何构型,其P-Cu-P键角受辅助双膦配体控制。在常温下,这2个铜（Ⅰ）配合物在固态时均具有发光性质,并且相对于双膦配体亚甲基链的长度,P-Cu-P键角对其光物理性质的影响更为显著。在2,2''-联吡啶环上引入2个甲基取代基对改善铜（Ⅰ）配合物的发光性能也被证明是有效的。     

电控摩擦离合器的初步实验研究

以十二烷基磺酸钠水溶液作为润滑液,以石墨作为辅助电极,以氮化硅／黄铜摩擦片组成摩擦副,考察了自行研制的电控摩擦离合器试验台的工作特性及摩擦力矩对外加电场响应特性。结果表明,当外加电压从OV增加到20V时,电控摩擦离合器的摩擦力矩增大约2倍,摩擦力矩随外电压变化的响应时间约为3s。据此可以认为,电控摩擦技术可望应用于摩擦传动装置。     

圆管流动水击压力波测量及水力计算

为探索水击现象的物理过程和机理,研制了自循环定常流动管路瞬态特性计算机控制试验装置,并利用该装置进行圆管流动水击压力波实验测量。用12只扩散硅压力传感器测定圆管流动水击压力波瞬态分布及最大、最小压力值,由试验数据拟合出水击波波形,揭示了水击压力波传播方式、特性及衰减规律。通过分析随机捕捉测量技术方法,理论上推断出测量数据达到可信精度。在归纳分析试验数据基础上,得出最大压力随关阀时间的关系曲线,对圆管流动直接水击等概念进行了探讨,用数值分析方法拟合出水击最大压力水力计算修正方程式。     

SURFACE STRESS EFFECT IN MECHANICS OF NANOSTRUCTURED MATERIALS

This review article summarizes the advances in the surface stress effect in mechanics of nanostructured elements,including nanoparticles,nanowires,nanobeams,and nanofilms,and heterogeneous materials containing nanoscale inhomogeneities.It begins with the fundamental formulations of surface mechanics of solids,including the definition of surface stress as a surface excess quantity,the surface constitutive relations,and the surface equilibrium equations.Then,it depicts some theoretical and experimental studies of the mechanical properties of nanostructured elements,as well as the static and dynamic behaviour of cantilever sensors caused by the surface stress which is influenced by adsorption.Afterwards,the article gives a summary of the analytical elasto-static and dynamic solutions of a single as well as multiple inhomogeneities embedded in a matrix with the interface stress prevailing.The effect of surface elasticity on the diffraction of elastic waves is elucidated.Due to the difficulties in the analytical solution of inhomogeneities of complex shapes and configurations,finite element approaches have been developed for heterogeneous materials with the surface stress.Surface stress and surface energy are inherently related to crack propagation and the stress field in the vicinity of crack tips.The solutions of crack problems taking into account surface stress effects are also included.Predicting the effective elastic and plastic responses of heterogeneous materials while taking into account surface and interface stresses has received much attention.The advances in this topic are inevitably delineated.Mechanics of rough surfaces appears to deserve special attention due to its theoretical and practical implications.Some most recent work is reviewed.Finally,some challenges are pointed out.They include the characterization of surfaces and interfaces of real nanomaterials,experimental measurements and verification of mechanical parameters of complex surfaces,and the effects of the physical and chemical processes on the surface properties,etc.     

平面Laplace问题的等价间接变量边界积分方程

利用变分法证明平面调和函数的外问题的确切形式；在此基础上，建立外问题的具有间接变量的等价边界积分方程；传统的外问题及边界积分方程不具有普遍适用性，本文对此进行了详细的讨论．     

一类反应扩散方程正解的存在性

本文使用锥映象不动点指数方法,讨论了一类反应扩散方程正解的存在性.     

受迫二维广义KdV-Burgers方程的周期行波解

本文研究了受迫二维广义ＫｄＶ－Ｂｕｒｇｅｒｓ方程的周期行波解问题,讨论了解的有界性并给出了解的估计式,进而讨论了周期解的存在性及唯一性.