Uniform attractor for nonautonomous incompressible non-Newtonian fluid with a new class of external forces

This paper is joint with [27]. The authors prove in this article the existence and reveal its structure of uniform attractor for a two-dimensional nonautonomous incompressible non-Newtonian fluid with a new class of external forces.     

5-(5-氯-2-吡啶偶氮)-2,4-二氨基甲苯分光光度法测定微量钌(Ⅲ)

研究了 5- ( 5-氯 - 2 -吡啶偶氮 ) - 2 .4-二氨基甲苯 ( 5- Cl- PADAT)与钌 ( )的显色反应。在 p H4.0～ 6.5HAc- Na Ac缓冲溶液中 ,在加热的条件下 ,5- Cl-PADAT与 Ru( )形成稳定的配合物 ,加入无机酸 ( HCl,HCl O4 ,H2 SO4 ,H3 PO4 )酸化后 ,其最大吸收波长位于 50 5nm处 ,表观摩尔吸光系数为 8.5×1 0 4 L· mol-1· cm-1,钌浓度在 0～ 6μg/ 1 0 m L范围内服从比耳定律 ,Ru( )与 5- Cl- PADAT配合物的摩尔比为 1∶ 2。以 EDTA为掩蔽剂 ,方法具有良好的选择性 ,已应用于合成样中钌的测定。     

Highly Efficient Oxidative Bromination of Alkanes with the HBr-H2O2 System in the Presence of Catalyst

Various cycloalkanes and straight‐chain alkanes were efficiently brominated with an aqueous HBr‐H₂O₂ system. This oxidative brominating process was promoted by catalysis and irradiation with light. The cycloalkanes were converted to the corresponding bromo‐cycloalkanes in moderate yields and the straight‐chain alkanes produced dominantly secondary bromides. This simple but effective bromination method of alkanes is characterized by high atom efficiency, inexpensive reagents and the absence of organic waste, which make it a good alternative to the existing method for C? H activation through bromination.     

Fluorescent Biological Label for Recognizing Human Ovarian Tumor Cells Based on Fluorescent Nanoparticles

In this paper, we report a method for recognizing human ovarian tumor(HOT) cells using fluorescent biological label based on core-shell nanoparticles. The luminescent nanoparticles were synthesized with a water-in-oil(W/O)micromulsion technique. The fluorescent silica core-shell nanoparticles modified with anti-HER2 antibody using bifunctional cross-linker glutaraldedhyde targeted the corresponding tumor antigen in the cell surface of the SKOV3 ovarian cancer cells. The specific immunoreactivity of antibody-nanoparticles with cells was characterized by laser scanning microscopy (LSM) and scanning electron microscope (SEM). The results showed that the method offered potential advantages of sensitivity and simplicity due to high binding efficiency between nanoparticles and cells and provided an alternative method for the detection of HOT.     

The Effect of the Chain Length on MMA Free Radicl Polymerization

It has been known that the propagation rate coefficient (kp) will change with monomer conversion, Friss, Hamielec et al.1-5 have proposed many formulas about kp to fit this change. In order to obtain the relation between Arrhenius parameters and monomer conversion, a group of kp values at the same monomer conversion must be measured. We adopted a new method through analysis of kp values measured by usual experimental techniques for this purpose. Firstly, we chose a value of monomer convers…     

Chiral Separation of N-Benzoyl Phenylalanine Methyl Ester by Nonaqueous Capillary Electrophoresis

Theseparationofopticalisomersisarapidlygrowingareaincapillaryelectrophoresis(CE),andmostchiralseparationbyCEhavebeenperformedinaqueousbackgroundelectrolyte.Organicsolventssuchasmethanolandacetonitrilehavebeenappliedasbuffermodifiersatconcentrationtypicallynothigherthan40%inordertoincreasehydrophobicanalytesolubilityandtoimproveselectivity,resolution,ortoaltertheelectroosmoticflow(EOF)andelectrophoreticmobilityofanalyte.Buttherehavebeenonlyafewreportsonthechiralseparationusingpurenonaqueousme…     

Solvent Effects on Aza‐anionic Cycloaromatization of 2‐(2‐Substituted‐ethynyl)benzonitriles

The methanolysis of 2‐(2‐aryl ethynyl)benzonitriles is accelerated when the polar aprotic solvents are added, which could enhance the 6‐endo pathway and give isoquinolones, though the 5‐exo pathway is occupied mostly. The yields of products would also be in creased.     

Tb(III) Speciation in Human Blood Plasma by Computer Simulation

With the wide application of rare earth fertilizer and medicines1, more and more rare earths enter into environment, and also into human body via food chain. Now it is very urgent to study the biological effect of rare earths on human health and environment. After entering into human body by whatever route, lanthanide ions are transported to secondary deposition sites mainly via the plasma in the blood stream. So it is very important to study lanthanides speciation in human blood plasma. Becau…