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901.
There is a delicate balance for a low‐weight molecule to behave as a gelator or crystal. The synthesis of two novel amino acid‐based naphthalene‐dendrons, Nap ‐ G1 and Nap ‐ G2 is described. Both dendrons display polymorphic properties in organic solvents. Nap ‐ G1 developed a fibrous network with β‐sheet architecture in cyclohexane but exhibited a spherulitic network in mixed solvents (chloroform/petroleum ether 1:5, v/v). On the other hand, Nap ‐ G2 acted as an efficient organogelator in chloroform but formed crystalline fibers in relatively high polarity solvents (such as acetone and methanol). Combinations of characterizations have been employed to study the polymorphism.  相似文献   
902.
基于主成分的改进雷达图及其在综合评价中的应用   总被引:2,自引:0,他引:2  
本文从可视化角度出发,在总结传统可视化方法因优点与不足的基础上,将主成分分析、因子分析与雷达图结合,改进了传统的可视化方法。并将新的可视化方法引入到综合评价中,提出了一种基于雷达图面积的综合评价模型,实例验证该种方法切实有效。  相似文献   
903.
In order to investigate the calculation methods on crack resistance capacity of connection composed of cross shaped steel encased ultra high strength concrete (CSSEUHSC) columns and steel encased concrete (SEC) beams under cycle loads, six interior connection specimens were tested in the laboratory. A discussion on the crack resistance capacity was presented. Calculation methods of crack resistance capacity were deduced based on the experimental case and calculation results were in good agreement with the experimental results. The research results indicated that parameters of connection composed of CSSEUHSC columns and SEC beams with better crack resistance performance may be referred for engineering application.  相似文献   
904.
We consider the motion of an impurity in a Bose-Einstein condensate system at T = 0 K with the contact interaztions for boson-boson and boson-impurity. Under the forward-scattering approximation, we obtain a Fr6hlich-like Hamiltonian for this system, which means that a polaron can be formed. The effective mass, the phonon number and the energy to form a polaron are obtained. We also discuss the validity of the forwardscattering approximation for this system.  相似文献   
905.
在生产条件受控的状态下,先验分布与后验分布应服从同一分布,在假设该分布为正态分布的前提下,根据贝叶斯理论推导出均值、极差和标准差的迭代计算公式,并依此计算控制图的控制限,使有效的先验批检验信息得到充分运用,弥补传统控制图在小批量生产环境下样本信息不足的缺点。研究发现,基于贝叶斯原理的统计控制图控制限随着检验批次的逐渐增加,更接近控制界限的实际值,比传统控制图的控制效果更加可靠、有效。  相似文献   
906.
In this article, we continue our study of a system described by a class of initial boundary value problem (IBVP) of the Korteweg-de Vries (KdV) equation and the KdV Burgers (KdVB) equation posed on a finite interval with nonhomogeneous boundary conditions. While the system is known to be locally well-posed (Kramer et al. , [2010]; Rivas et al. in Math. Control Relat. Fields 1:61–81, [2011]) and its small amplitude solutions are known to exist globally, it is not clear whether its large amplitude solutions would blow up in finite time or not. This problem is addressed in this article from control theory point of view: look for some appropriate feedback control laws (with boundary value functions as control inputs) to ensure that the finite time blow-up phenomena would never occur. In this article, a simple, but nonlinear, feedback control law is proposed and the resulting closed-loop system is shown not only to be globally well-posed, but also to be locally exponentially stable for the KdV equation and globally exponentially stable for the KdVB equation.  相似文献   
907.
A new borate LiBa3(OH)[B9O16][B(OH)4], which combines the uniform porosity of open‐frameworks with the extraordinary NLO properties of borates, has been obtained under hydrothermal conditions by using mixed lithium and barium ions as templates. The framework displays an acs‐type net with large 21‐ring channels. The second harmonic generation (SHG) measurement shows that it is a type I phase‐matchable material with a strong SHG signal intensity about 3.1 times that of KDP (KH2PO4). UV/Vis–NIR diffuse reflectance analysis indicates that the compound has a wide transparency range with the short‐wavelength absorption edge below 200 nm. These characteristics reveal that the compound is a promising deep‐UV nonlinear optical material.  相似文献   
908.
Shen  Honglong  Yang  Xiaoqiang  Song  Juanjuan  Gao  Haiwen  Wu  Zongdeng  Yu  Jia  Lei  Wu  Yang  Jiazhi  He  Guangyu  Hao  Qingli 《Journal of Solid State Electrochemistry》2022,26(2):353-363
Journal of Solid State Electrochemistry - Long-cycle stability and high-energy density are big challenges for developing high-performance hybrid supercapacitor (HSC) electrode materials. In this...  相似文献   
909.
A novel fluorine-contained random copolymer (2,3,4,5,6-pentafluorostyrene)-r-poly(4-vinyl benzocyclobutene) (P(PFSt-r-4-VBCB)) was synthesized, and then spin-coated onto Si substrates followed by thermal cross-linking to produce the copolymer ultra-thin films. Although the surface modification with the P(PFSt-r-4-VBCB) film was simple and did not rely on special surface chemical reactions, the film could decrease the surface energy significantly, more importantly; the film demonstrated excellent stability and corrosion resistance. This random copolymer film could find broad applications in modifying various solid surfaces to enhance the properties such as corrosion resistance and solvent resistance.  相似文献   
910.
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