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991.
Hyperfine structure of a hydrogen-like atom due to orbit-orbit,spin-orbit,and spin-spin interactions
A nonrelativistic model of a hydrogen-like atom is considered. This model is used to calculate corrections to the energy spectrum of the atom. The analysis is based on a Hamiltonian that includes the intratomic fields generated by the electron and the nucleus. 相似文献
992.
A. V. Pastukhov V. A. Davankov E. V. Sidorova E. I. Shkol’nikov V. V. Volkov 《Russian Chemical Bulletin》2007,56(3):484-493
An automated procedure was developed for monitoring fast changes in the size of spherical samples of polymers during their
contact with a solvent or drying. The kinetics of bulk deformation in these processes was studied for a series of cross-linked
polymers, viz., gel-type and porous styrene—divinylbenzene copolymers and poly(divinylbenzenes), and hypercrosslinked polystyrenes. Gel,
macroporous, and hypercrosslinked polystyrenes are substantially different in the rate, mechanism, and degree of swelling,
which is associated with the principal differences in their physical structures. An unusual effect of a sharp decrease followed
by a temporary increase in the volume of porous polystyrene and poly(divinylbenzene) materials were observed during desorption
(evaporation) of organic solvents. Water desorption is accompanied by an excessive bulk compression of porous granules giving
rise to negative deformations, which gradually relax to the state equilibrium for the dry polymer. The results of dynamic
desorption porometry (for water desorption) are indicative of a bimodal size distribution of micropores in hypercrosslinked
polystyrene.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 467–476, March, 2007. 相似文献
993.
Pulsed laser deposition with a Nd:YAG laser was used to grow thin films from a pre-synthesized Ti3SiC2 MAX-phase formulated ablation target on oxidized Si(1 0 0) and MgO(1 0 0) substrates. The depositions were carried out in a substrate temperature range from 300 to 900 K, and the pressure in the deposition chamber ranged from vacuum (10−5 Pa) to 0.05 Pa Argon background pressure. The properties of the films have been investigated by Rutherford backscattering spectrometry for film thickness and stoichiometric composition and X-ray diffraction for the crystallinity of the films. The silicon content of the films varied with the energy density of the laser beam. To suppress especially the silicon re-sputtering from the substrate, the energy of the incoming particles must be below a threshold of 20 eV. Therefore, the energy density of the laser beam must not be too high. At constant deposition energy density the film thickness depends strongly on the background pressure. The X-ray diffraction measurements show patterns that are typical of amorphous films, i.e. no Ti3SiC2 related reflections were found. Only a very weak TiC(2 0 0) reflection was seen, indicating the presence of a small amount of crystalline TiC. 相似文献
994.
L. G. Smirnova Yu. B. Grunin S. V. Krasil'nikova M. A. Zaverkina D. R. Bakieva E. V. Smirnov 《Colloid Journal》2003,65(6):778-781
The pulsed NMR, isopiestic and pycnometric methods are applied to investigate the physicochemical properties of softwood [GOST (State Standard) 9571-89] and hardwood [GOST 28172-89] celluloses, as well as flax cellulose [GOST 10330-76, 9394-76], both in the initial state and subjected to chemical treatment. Possible changes occurring in the supramolecular structure of a polymer are analyzed. The structural and sorption characteristics of the investigated samples are calculated. Their water absorption capacities are determined. 相似文献
995.
Jean E. Taylor 《Discrete and Computational Geometry》1991,6(1):225-262
We bound the number of plane segments in a crystalline minimal surface S in terms of its Euler characteristic, the number
of line segments in its boundary, and a factor determined by the Wulff shapeW of its surface energy function. A major technique in the proofs is to quantize the Gauss map ofS based on the Gauss map ofW. One thereby bounds the number of positive-curvature corners and the interior complexity ofS.
The support of the National Science Foundation and the Air Force Office of Scientific Research and the hospitality of Stanford
University, where this paper was extensively rewritten, are gratefully acknowledged. 相似文献
996.
S. E. Weal 《The Journal of the Operational Research Society》1991,42(12):1047-1059
Much of the debate over OR education over the last ten years has been confined to the relevance of the content and style of programmes at the postgraduate level. This paper focuses on the undergraduate level and discusses the way in which practical elements have been successfully incorporated at this level in Australia. These elements include the use of case study material from the literature, case problem solving groups, industrial projects and 12 months paid employment through a co-operative education programme. The use of each of the above and the context with which they fit into the programme is covered as are the benefits and problems associated with the programme. 相似文献
997.
W. G. Habashi G. Baruzzi M. F. Peeters M. M. Hafez 《Numerical Methods for Partial Differential Equations》1991,7(2):193-207
Finite element solutions of the Euler and Navier-Stokes equations are presented, using a simple dissipation model. The discretization is based on the weak-Galerkin weighted residual method and equal interpolation functions for all the unknowns are permitted. The nonlinearity is iterated upon using a Newton method and at each iteration the linear algebraic system is solved by a direct solver with all unknowns fully coupled. Results are presented for two-dimensional transonic inviscid flows and two- and three-dimensional incompressible viscous flows. Convergence of the algorithm is shown to be quadratic, reaching machine accuracy in very few iterations. The inviscid results demonstrate the existence of nonunique numerical solutions to the steady Euler equations. 相似文献
998.
A. Yu. Kolesov E. F. Mishchenko N. Kh. Rozov 《Proceedings of the Steklov Institute of Mathematics》2007,256(1):206-222
The well-known sine-Gordon equation, supplemented with small damping and small quasiperiodic external force, is studied under the zero Dirichlet boundary conditions at the endpoints of a finite interval. The main assumption is that all frequencies of the external force are in 1:1 resonance with certain eigenfrequencies of the unperturbed equation; i.e., the socalled fundamental multifrequency resonance is observed. It is shown that in this case, by an appropriate choice of the parameters of the external force, one can make it so that the boundary value problem has a stable invariant torus of any finite dimension that bifurcates from zero on any preassigned finite set of spatial modes. It is also shown (by numerical analysis) that in a number of cases the above-mentioned torus coexists with a chaotic attractor. 相似文献
999.
E. V. Karnaukh 《Ukrainian Mathematical Journal》2007,59(4):620-632
We consider almost upper-semicontinuous processes defined on a finite Markov chain. The distributions of functionals associated
with the exit of these processes from a finite interval are studied. We also consider some modifications of these processes.
__________
Translated from Ukrains’kyi Matematychnyi Zhurnal, Vol. 59, No. 4, pp. 555–565, April, 2007. 相似文献
1000.
N. S. Zefirov N. V. Zyk E. K. Beloglazkina V. S. Tyurin 《Russian Chemical Bulletin》1995,44(2):315-317
Two systems for arene sulfenylation were investigated: arenesulfenamides in the presence of SO3 and sulfenylacetate complexes with AlBr3. A preference for the second reagent was demonstrated for sulfenylation of substrates bearing donor substituitents.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 324–326, February, 1995. 相似文献