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21.
Ruta Lazauskaite Maryte Daskeviciene Vytautas Getautis Juozas V. Grazulevicius 《Monatshefte für Chemie / Chemical Monthly》2009,140(5):565-571
Abstract Photoinitiated cationic polymerizations of various epoxy monomers bearing a carbazole moiety, 9-[3-(allyloxy)-2-(oxiran-2-ylmethoxy)propyl]-9H-carbazole, 9-[3-methoxy-2-(oxiran-2-ylmethoxy)propyl]-9H-carbazole, 9-[2-(oxiran-2-ylmethoxy)ethyl]-9H-carbazole, as well as a composition of 3,6-dibromo-9-(oxiran-2-ylmethyl)-9H-carbazole with 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexane carboxylate were investigated in bulk using triphenyl carbenium
salts having anions such as BF4
−, SnCl5
−, and SbCl6
−. Dark polymerizations of the carbazolyl monomers in the presence of the initiators are studied. These photoinduced polymerization
reactions give oligomers of degree of polymerization 4-22. The effect of the anion of the photoinitiator and polymerization
time on the polymerization reaction is discussed.
Graphical abstract
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22.
The H-bonded complexes of pyridine N-oxide (PyO) with H(2)O, acetic, cyanoacetic, propiolic, tribromoacetic, trichloroacetic, trifluoroacetic, hydrochloric, and methanesulfonic acids have been studied by FTIR and NMR spectroscopy, X-ray diffraction, and quantum chemical DFT calculations. Correlations between vibrational frequencies of the NO stretching and PyO ring modes and geometric parameters of the H-bond have been established. FTIR experiments show and DFT calculations confirm that definite discontinuity is present in the vicinity of the midpoint in the proton transfer pathway. The established correlations significantly aid in the understanding of fine effects such as the isotope (deuteration) effect, crystal-to-solution transition, or criticality of aqueous solutions induced by ionic pairs. Geometric isotope effect in the ionic H-bond aggregate of PyO·H(D)Cl was found to be extraordinary large. Measured FTIR, CP/MAS, and high-resolution (13)C NMR spectra indicate that H-bond in the PyO·HCl complex in polar solvent can potentially be more ionic than in the crystal. Vibrational modes of ionic pairs originating via proton transfer in H-bond complexes can provide new information concerning the interionic interaction and its role in the phase separation and mezo-structuring processes. The results are compared to the relevant data for PyO·HCl complex in argon matrix. 相似文献
23.
Minvydas Ragulskis Rimas Maskeliunas Liutauras Ragulskis Vytautas Turla 《Optics and Lasers in Engineering》2005,43(9):3640
Geometric moiré fringe formation method is a classical well-established experimental technique with numerous practical applications. This paper proposes the application of time-average geometric moiré analysis for the determination of dynamic displacements of the lithographic press rubber roller. This optical measurement technique is a natural extension of double-exposure geometric moiré for the identification of dynamic displacements of vibrating elastic structures. Experimental investigations prove the validity and effective practical applicability of the method. 相似文献
24.
B. Barvainiene A. Stanisauskaite V. Getautis 《Chemistry of Heterocyclic Compounds》2007,43(6):718-721
The synthesis of N-(2,3-epoxypropyl)diphenylamine is reported. It was found that thermal opening of the oxirane ring of N-(2,3-epoxypropyl)diphenylamine
occurred both at the secondary and the tertiary carbon atoms but the basic reaction product is 3-hydroxy-1-phenyl-1,2,3,4-tetrahydroquinoline.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 852–855, June, 2007. 相似文献
25.
Jolanta Stumbraite Maryte Daskeviciene Rimgaile Degutyte Vygintas Jankauskas Vytautas Getautis 《Monatshefte für Chemie / Chemical Monthly》2007,138(12):1243-1248
Summary. Novel glass-forming 2-(1-phenyl-1,2,3,4-tetrahydroquinoline-6-ylmethylene)-1,3-indandione derivatives were synthesized and
their thermal properties were studied. The results of a preliminary investigation of the photoelectric properties of amorphous
films of the title compounds are briefly reported. The ionization potential of these molecular glasses is ca. 5.6 eV and the hole drift mobility exceeds 10−8 cm2 V−1 s−1 at strong electric fields. 相似文献
26.
Vytautas Getautis Maryte Daskeviciene Tadas Malinauskas Vygintas Jankauskas 《Monatshefte für Chemie / Chemical Monthly》2007,138(4):277-283
Summary. Synthesis of a new monomer and polymer containing both ferrocene and hydrazone moieties are reported. The obtained materials
were examined by various techniques including differential scanning calorimetry, UV, IR, NMR spectroscopy, and time of flight
method. These materials may be of particular interest for the development of future electrophotographic photoreceptors as
electron photoemission spectra of the layers showed ionization potentials of 5.35–5.41 eV. The hole drift mobility values
in compositions of the designed structures with bisphenol Z polycarbonate exceeded 10−8 cm2/Vs at strong electric fields. 相似文献
27.
Getautis V Daskeviciene M Malinauskas T Stanisauskaite A Stumbraite J 《Molecules (Basel, Switzerland)》2006,11(1):64-71
A series of mono and di-N-2,3-epoxypropyl N-phenylhydrazones have been prepared on a large scale by reaction of the corresponding N-phenylhydrazones of 9-ethyl-3-carbazolecarbaldehyde, 9-ethyl-3,6-carbazoledicarbaldehyde, 4-dimethyl-amino-, 4-diethylamino-, 4-benzylethylamino-, 4-(diphenylamino)-, 4-(4,4-4'-dimethyl-diphenylamino)-, 4-(4-formyldiphenylamino)- and 4-(4-formyl-4'-methyldiphenyl-amino)benzaldehyde with epichlorohydrin in the presence of KOH and anhydrous Na(2)SO(4). 相似文献
28.
Balevicius V Aidas K Tamuliene J Fuess H 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(5):835-839
Moderately narrow 1H NMR signals were observed in the solid-phase obtained from pyridine-N-oxide (PyO)...HCl solutions in acetonitrile/H2O after heterogeneous phase separation. High-resolution 1H NMR spectra are compared with those of crystalline PyO...HCl and PyO...DCl. It is concluded that partially resolved peaks in 1H NMR spectra of solids are related with heterogeneity of the spin system and the presence of different mobile H-bond clusters containing PyO, HCl, DCl and water molecules. Some part of non-bonded water or HCl molecules is captured in the cavities of crystalline samples. The attribution of the 1H NMR signals was based on the density functional theory calculation of proton magnetic screening tensor of the most expected H-bond structures in the 6-311G** basis taking into account the solvent effect by the polarized continuum model. 相似文献
29.
Dovil Malkait Birut Grybait Rita Vaickelionien Giedrius Vaickelionis Birut Sapijanskait-Banevi
Povilas Kavaliauskas Vytautas Mickevi
ius 《Molecules (Basel, Switzerland)》2022,27(1)
Rapidly growing antimicrobial resistance among clinically important bacterial and fungal pathogens accounts for high morbidity and mortality worldwide. Therefore, it is critical to look for new small molecules targeting multidrug-resistant pathogens. Herein, in this paper we report a synthesis, ADME properties, and in vitro antimicrobial activity characterization of novel thiazole derivatives bearing β-amino acid, azole, and aromatic moieties. The in silico ADME characterization revealed that compounds 1–9 meet at least 2 Lipinski drug-like properties while cytotoxicity studies demonstrated low cytotoxicity to Vero cells. Further in vitro antimicrobial activity characterization showed the selective and potent bactericidal activity of 2a–c against Gram-positive pathogens (MIC 1–64 µg/mL) with profound activity against S. aureus (MIC 1–2 µg/mL) harboring genetically defined resistance mechanisms. Furthermore, the compounds 2a–c exhibited antifungal activity against azole resistant A. fumigatus, while only 2b and 5a showed antifungal activity against multidrug resistant yeasts including Candida auris. Collectively, these results demonstrate that thiazole derivatives 2a–c and 5a could be further explored as a promising scaffold for future development of antifungal and antibacterial agents targeting highly resistant pathogenic microorganisms. 相似文献
30.
Vilijandas Bagdonavičius Algimantas Bikelis Vytautas Kazakevičius Mikhail Nikulin 《Comptes Rendus Mathematique》2006,342(1):63-68
A joint model for linear degradation and competing failure data with partial renewals is proposed. Non-parametric estimation procedures for failure intensities and failure probabilities as functions of degradation level are given. Asymptotic properties of the estimators are investigated. To cite this article: V. Bagdonavi?ius et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献