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31.
Nhat Anh Thi Thieu Minh Canh Vu Dae Hoon Kim Won Kook Choi Sung‐Ryong Kim 《先进技术聚合物》2020,31(10):2351-2359
The composites comprising vertically aligned network of copper nanowires (CuNWs) in the presence of cellulose nanofibers were fabricated by using the freeze‐templating method and the effect of aspect ratio (A/R) of CuNWs on the thermal conductivity of epoxy composites was investigated. The thermal conductivity of epoxy composites increased to 0.79 W m?1 K?1 at 1.12 vol% of high A/R CuNWs loading, corresponding to the thermal conductivity enhancement of 365% as compared to the pure epoxy. The thermal conductivity of vertically aligned higher A/R CuNWs/epoxy, which is 38.5% and 51.9% higher than those of the lower A/R CuNWs and the randomly aligned CuNWs, respectively. The application of the epoxy composites in heat dissipation was demonstrated by the temperature changes of composites on a hot plate with the increase of heating time. These results indicate that the thermally conductive composites in this study could be applied for thermal dissipating materials in electronic devices. 相似文献
32.
The gauge symmetry group of any slave boson representation allows to gauge away the phase of bosonic fields. One benefit of this radial field formulation is the elimination of spurious Bose condensations when saddle-point approximation is performed. Within the Kotliar–Ruckenstein representation, three of the four bosonic fields can be radial while the last one has to remain complex. In this work, the procedure to carry out the functional integration involving constrained fermionic fields, complex bosonic fields, and radial bosonic fields is presented. The correctness of the representation is verified by exactly evaluating the partition function and the Green's function of the Hubbard model in the atomic limit. 相似文献
33.
Martin Krtký Katarína Svr
kov Quynh Anh Vu rka tpnkov Jarmila Vinov 《Molecules (Basel, Switzerland)》2021,26(4)
Based on the broad spectrum of biological activity of hydrazide–hydrazones, trifluoromethyl compounds, and clinical usage of cholinesterase inhibitors, we investigated hydrazones obtained from 4-(trifluoromethyl)benzohydrazide and various benzaldehydes or aliphatic ketones as potential inhibitors of acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE). They were evaluated using Ellman’s spectrophotometric method. The hydrazide–hydrazones produced a dual inhibition of both cholinesterase enzymes with IC50 values of 46.8–137.7 µM and 19.1–881.1 µM for AChE and BuChE, respectively. The majority of the compounds were stronger inhibitors of AChE; four of them (2-bromobenzaldehyde, 3-(trifluoromethyl)benzaldehyde, cyclohexanone, and camphor-based 2o, 2p, 3c, and 3d, respectively) produced a balanced inhibition of the enzymes and only 2-chloro/trifluoromethyl benzylidene derivatives 2d and 2q were found to be more potent inhibitors of BuChE. 4-(Trifluoromethyl)-N’-[4-(trifluoromethyl)benzylidene]benzohydrazide 2l produced the strongest inhibition of AChE via mixed-type inhibition determined experimentally. Structure–activity relationships were identified. The compounds fit physicochemical space for targeting central nervous systems with no apparent cytotoxicity for eukaryotic cell line together. The study provides new insights into this CF3-hydrazide–hydrazone scaffold. 相似文献
34.
We present the first realisation of ferromagnetic Fe nanotips. Studies of the field emitted beams of electrons and metallic ions above and under the Curie temperature Tc were made. We have observed a reversible splitting of the electron beams when the temperature crossed through Tc and multiple spot patterns for the emitted metallic ion beams. These phenomena were not observed with Fe microtips or non-magnetic nanotips and thus were correlated to a strong magnetic interaction at the atomic scale apex of the nanotips. The Fe nanotips constitute an atomic scale beam-splitter. 相似文献
35.
Roussel and Rubio proved a lemma which is essential in the proof of the Strong Perfect Graph Theorem. We give a new short proof of the main case of this lemma. In this note, we also give a short proof of Hayward’s decomposition theorem for weakly chordal graphs, relying on a Roussel–Rubio-type lemma. We recall how Roussel–Rubio-type lemmas yield very short proofs of the existence of even pairs in weakly chordal graphs and Meyniel graphs. 相似文献
36.
S. Issing F. Fuchs C. Ziereis E. Batke A. Pimenov Y. Vu. Ivanov A. A. Mukhin J. Geurts 《The European Physical Journal B - Condensed Matter and Complex Systems》2010,73(3):353-360
A systematic and detailed study of Raman and infrared active lattice excitations in the orthorhombic multiferroic manganite
Eu1−xYxMnO3 (0 ≤ x ≤ 0.5) was carried out at room temperature. For the infrared active phonon modes the eigenfrequencies, damping constants
and oscillator strengths were analyzed by Fourier-Transform Infrared Spectroscopy in the far infrared frequency range. For
the Raman active phonons the same analysis for eigenfrequencies and damping constants was carried out using Raman spectroscopy
in the range from 200 cm−1 to 700 cm−1. Y doping leads to mode-dependent phonon frequency shifts up to 8%. These are interpreted in terms of the interplay between
the decrease of the reduced ion masses and the axis-dependent change of bond lengths. The latter leads to a bond softening
along the a-axis and a strengthening along the c-axis, for which the highest phonon frequency increase is observed. The application
of both Raman and Infrared Spectroscopy gives us sensitivity not only to symmetry properties via the selection rules but also
to the involvement of different ion types within the unit cell. It is clearly shown that the disorder induced effects are
of minor impact on the lattice properties and solely detected on the rare earth sites. The MnO6 octahedra remain unaffected and show the same behavior as in the stochiometric RMnO3 making Eu1−xYxMnO3 an excellent model system for a quasi-continuous fine-tuning of the lattice parameters relevant for the appearance of multiferroicity. 相似文献
37.
We show here that field emission (FE) can be used to directly observe the vibration resonances nu(R) of carbon nanotubes (CNTs) and that the tension created by the applied field allows the tuning of these resonances by up to a factor of 10. The resonances are observable by the changes they create in the FE pattern or the emitted FE current. The tuning is shown to be linear in voltage and to follow from the basic physics of stretched strings. The method allows one to study the mechanical properties of individual multiwall carbon nanotubes within an ensemble and follow their evolution as the CNTs are modified. The tuning and detection should be useful for nanometric resonant devices. 相似文献
38.
39.
A simple method of measuring the wavelength γ1 and the spectral line spacing Δγ of a multi-mode dye laser light by using the correlated speckle patterns produced at the far-field of a diffuser is proposed. Examples of the obtained values of γ1 and Δγ are 6.0 × 103 Å and 3.0 × 101 Å, respectively. 相似文献
40.
Molality as a unit of measure for expressing 1H MRS brain metabolite concentrations in vivo 总被引:1,自引:0,他引:1
Knight-Scott J Haley AP Rossmiller SR Farace E Mai VM Christopher JM Manning CA Simnad VI Siragy HM 《Magnetic resonance imaging》2003,21(7):787-797
Absolute concentrations of cerebral metabolite in in vivo 1H magnetic resonance spectroscopy studies (1H-MRS) are widely reported in molar units as moles per liter of tissue, or in molal units as moles per kilogram of tissue. Such measurements require external referencing or assumptions as to local water content. To reduce the scan time, avoid assumptions that may be invalid under specific pathologies, and provide a universally accessible referencing procedure, we suggest that metabolite concentrations from 1H-MRS measurements in vivo be reported in molal units as moles per kilogram of tissue water. Using internal water referencing, a two-compartment water model, a simulated brain spectrum for peak identification, and a spectroscopic bi-exponential spin-spin relaxation segmentation technique, we measured the absolute concentrations for the four common 1H brain metabolites: choline (Cho), myo-inositol (mIno), phosphocreatine + creatine (Cr), and N-acetyl-aspartate (NAA), in the hippocampal region (n = 26) and along the Sylvian fissure (n = 61) of 35 healthy adults. A stimulated echo localization method (20 ms echo time, 10 ms mixing time, 4 s repetition time) yielded metabolite concentrations, uncorrected for metabolite relaxation or contributions from macromolecule resonances, that were expectantly higher than with molar literature values. Along the Sylvian fissure the average concentrations (coefficient of variation (CV)) in mmoles/kg of tissue water were 17.6 (12%) for NAA, 14.2 (9%) for Cr, 3.6 (13%) for Cho, and 13.2 (15%) for mIno. Respective values for the hippocampal region were 15.7 (20%), 14.7 (16%), 4.6 (19%), and 17.7 (26%). The concentrations of the two regions were significantly different (p = 0.001) for NAA, mIno, and Cho, a trend in agreement with previous studies. All gray matter Sylvian fissure CV values, except for NAA, were also in agreement with previous 1H-MRS gray matter studies. The reduced precision of the NAA concentration was attributed to overlapping signal contributions from glutamate and glutamine (Glx), suggesting that a detailed Glx model is critical for accurate quantitation of the NAA 2.02 ppm resonance. The reduced precision of the measurements in the hippocampal region was attributed to poor spectral resolution. 相似文献