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31.
We observed for the first time a strong angle-independent modification of spontaneous emission spectra from laser dyes in photonic crystals, made of inverse opals in titania. Comparison with spectra from such crystals with much smaller lattice spacing, for which emission is in the long wavelength limit, reveals inhibition of emission up to a factor approximately 5 over a large bandwidth of 13% of the first order Bragg resonance frequency. The center frequency and bandwidth of the inhibition agree with calculated total density of states, while the measured inhibition of vacuum fluctuations is much larger. Because of the specific location of the dye molecules, we likely probe the strongly modulated local photonic density of states. 相似文献
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Directional fluorescence spectra of laser dye in opal and inverse opal photonic crystals 总被引:1,自引:0,他引:1
We have investigated the fluorescence from R6G dye molecules embedded in fcc photonic crystals with a large range of lattice parameters. Both polystyrene opals and alumina inverse opals are studied, allowing us to compare direct and inverted structures. We observe clear stop bands in the fluorescence spectra, whose center positions, widths, and depths are analyzed and compared to stop bands from reflectivity measurements. In the frequency range of first-order stop gaps, the measured stop band centers and widths agree well with theoretical predictions. The depths are interpreted in terms of the mean free path (disorder) and the Bragg attenuation length (order). We observe intriguing enhanced emission at the blue side of the stop bands, which is attributed to the escape of diffuse light from the photonic crystal (related to both order and disorder). We perform the first experiments in the range of second-order stop gaps, which is the regime where the photonic band gap is anticipated. We observe complex multiple-Bragg features that correlate favorably with reflectivity peaks. 相似文献
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Relationships between exposure to noise [metric: day-evening-night levels (DENL)] from stationary sources (shunting yards, a seasonal industry, and other industries) and annoyance are presented. Curves are presented for expected annoyance score, the percentage "highly annoyed" (%HA, cutoff at 72 on a scale from 0 to 100), the percentage "annoyed" (%A, cutoff at 50 on a scale from 0 to 100), and the percentage "(at least) a little annoyed" (%LA, cutoff at 28 on a scale from 0 to 100). The estimates of the parameters of the relations are based on the data from a field study (N=1875) at 11 locations (2 shunting yards, 1 seasonal industry, 8 other industries) in the Netherlands. With the same (yearly) DENL, the seasonal industry causes less annoyance than the other industries, while the other industries cause less annoyance than the shunting yards. It appears that annoyance caused by vibrations from shunting yards and annoyance caused by noise from through trains are (partly) responsible for the relatively high annoyance from shunting yards. The relatively low annoyance from the seasonal industry presumably is related to the presence of a relatively quiet period. Results for the two shunting yards and the seasonal industry are based on fewer data than the other industrial sources, and are indicative. The same patterns of influence of age and noise sensitivity that are generally found are also found in this study. For comparison, results regarding transportation sources are also given, including previously unpublished results for expected annoyance. 相似文献
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Chatzidimitriou-Dreismann CA Vos M Kleiner C Abdul-Redah T 《Physical review letters》2003,91(5):057403
We present, for the first time, a direct comparison between electron (ECS) and neutron (NCS) Compton scattering results from protons of a solid polymer. The momentum distributions of hydrogen obtained from ECS and NCS are in excellent agreement. In both experiments, a strong "anomalous" shortfall in the scattering intensity of protons [first detected in liquid water with NCS [Phys. Rev. Lett. 79, 2839 (1997)]]] is found ranging from about 20% up to 50%, depending on the momentum transfer applied. The characteristic times of electron- and neutron-proton collisions lie in the subfemtosecond range. The presented ECS and NCS results provide further direct evidence for this striking effect, which has been ascribed to attosecond quantum entanglement of the protons. 相似文献
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The synthesis, spectroscopic, electrochemical and photophysical characterization of a series of dinuclear ruthenium(II) complexes of the type [(bpy)2Ru(NnN)2RuCl(bpy)2](PF6)3, where NnN = 4,4′‐bipyridyl (N0N), 1,2‐bis(4‐pyridyl)ethylene (NEN), 1,2‐bis(4‐pyridyl)ethane (N2N), and 4,4′‐trimethylenedipyridine (N3N) are reported. The photophysical and electrochemical properties are discussed with particular emphasis on the ability of the bridging ligands to support intercomponent interaction. 相似文献