Tuning Pore Size in Square‐Lattice Coordination Networks for Size‐Selective Sieving of CO2

Porous materials capable of selectively capturing CO₂ from flue‐gases or natural gas are of interest in terms of rising atmospheric CO₂ levels and methane purification. Size‐exclusive sieving of CO₂ over CH₄ and N₂ has rarely been achieved. Herein we show that a crystal engineering approach to tuning of pore‐size in a coordination network, [Cu(quinoline‐5‐carboxyate)₂]_n ( Qc‐5‐Cu ) ena+bles ultra‐high selectivity for CO₂ over N₂ (S_CN≈40 000) and CH₄ (S_CM≈3300). Qc‐5‐Cu‐sql‐β , a narrow pore polymorph of the square lattice ( sql ) coordination network Qc‐5‐Cu‐sql‐α, adsorbs CO₂ while excluding both CH₄ and N₂. Experimental measurements and molecular modeling validate and explain the performance. Qc‐5‐Cu‐sql‐β is stable to moisture and its separation performance is unaffected by humidity.     

Study of the Au/SiO<Subscript>2</Subscript> + Co(65 at %)/GaAs heterostructure interfaces by the polarized neutron reflectometry method

Using the polarized neutron reflectometry method, we studied Au/SiO₂ + Co(60 at %)/GaAs granular films, which display a giant injection magnetoresistance effect in a narrow temperature range close to T = 300 K. We revealed the existence of a layer having particular magnetic properties at the boundary of a film with a semiconductor GaAs substrate. Experiments carried out at temperatures T = 300 K and T = 100 K showed an insignificant difference in the magnetic profile of the heterostructure.     

Formation of surface gradient structural-phase states under electron-beam treatment of stainless steel

The structural-phase states of steel 08X18H10T (0.08% C, 18% Cr, 10% Ni, 1% Ti) subjected to pulse electron beam treatment in the regime of surface layer melting is investigated using the methods of optical and electron microscopy. The regularities of variations in the phase composition and the state of the defect substructure moving away from the irradiation surface up to a 200-μm depth are revealed.     

Homological equations for tensor fields and periodic averaging

Homological equations of tensor type associated to periodic flows on a manifold are studied. The Cushman intrinsic formula [4] is generalized to the case of multivector fields and differential forms. Some applications to normal forms and the averaging method for perturbed Hamiltonian systems on slow-fast phase spaces are given.     

Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

Two isostructural metal–organic materials, Tripp-1-M (Tripp = 2,4,6-tris(4-pyridyl)pyridine; M = Co, Ni), that exhibit binodal 3,6-connected pyr network topology have been prepared and characterized. Tripp-1-M are based upon a novel M₇F₁₂²⁺ cluster that possesses 12 connection points but, because of double cross-linking by 3-connected Tripp ligands, it functions as a 6-connected supermolecular building block (SBB).     

Errors as Multistable Response Options

Five simulations mimicked benchmark phenomena of intact and dyslexic word naming. Initially, an iterative map was tuned to simulate the frequency × consistency interaction in skilled naming. Subsequently, two model parameters were changed, in turn, to produce the regularization error of surface dyslexia (PINT pronounced to rhyme with /mint/), absent pseudoword (BINT) naming of phonological dyslexia (words are named correctly; pseudowords are not), the semantic error of deep dyslexia (BUSH named as /tree/), and a dissociation in picture naming of spoken versus written responses (the spoken response to a picture of a bush is /tree/, but the written response is BUSH). All errors, except absent pseudoword naming, were simulated as transcritical bifurcations.     

Positron as a probe of cation vacancies in X-irradiated NaBr crystals

The temperature dependence of the ionic conductivity shows an increase of the free-cation vacancies concentration in X-irradiated NaBr single crystal. The 2γ angular correlation measurements confirm that positron bound state are formed preferably near the cation vacancies.