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P. G. J. van Dongen F. Gebhard D. Vollhardt 《Zeitschrift für Physik B Condensed Matter》1989,76(2):199-210
We present a general formalism for the diagrammatic calculation of correlation functions for Hubbard-type models in terms of projected wave functions. It is shown that in the limit of high spatial dimensionsd only diagrams with bubble-structure remain. This causes correlation functions to have an overall RPA-type form ind. Exact evaluations are performed for the Gutzwiller wave function. Nearest neighbor correlations are shown to be proportional to their value in the non-interacting case, i.e. are renormalized. However, their absolute value is only of order 1/d. Hence this wave function does not describe spin correlations adequately in high dimensions. The asymptotic behavior of the spin-correlation function is extracted and is found to have a scaling form similar tod=1. Assuming this form to hold in all dimensions we show that the Brinkman-Rice transition only occurs ind=. Finite orders of perturbation theory in 1/d around this singular point are not sufficient to remove the transition. 相似文献
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Miljanić OS Han S Holmes D Schaller GR Vollhardt KP 《Chemical communications (Cambridge, England)》2005,(20):2606-2608
The first cases of hindered rotation around the triple bond in simple diphenylacetylenes were observed, including that in chiral 2,2'-bis(trimethylsilyl)-6,6'-bis(dimethylthexylsilyl)diphenylacetylene. 相似文献
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The CpCo(CO)2-catalyzed cyclization of 1-trimethylsilyl-1, 5-hexadiyne (4) with propargyltetrahy-dropyranylether (5 leads to the formation of both possible regioisomers of the benzocyclobutene product: 3-trimethylsilyl-4-tetrahydropyranyloxymethylbenzocyclobutene (6) and the corresponding 5-tetrahydropyranyloxymethyl-isomer 7. On the other hand, cyclization of the same diyne with 3-(trimethylsilyloxy) propyne (10) gave only the 3,4-disubstituted product as the free alcohol 11. Compound 6 was iododesilylated, the ether hydrolyzed, and the alcohol tosylated to give 4-iodo-5-tosyloxymethylbenzocyclobutene 13, also obtainable more directly from 11 by treatment with ICI and tosylation. Iodide 13 could be reacted with n-butyllithium to give a variety of products incorporating the n-butylgroup and derived from crosscoupling of the carbon skeleton of starting material. The title compound 1 may be an intermediate en route to the observed products, but was not detected. Several thermal elimination routes to 1 from appropriately 4,5-substituted benzocyclobutenes were unsuccessful. Flash vacuum thermolysis of 11 furnished the silyloxyderivative 21 through elimination of methane. 相似文献