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881.
882.
Dirk H. Rischke Yariş Pürsün Joachim A. Maruhn Horst Stöcker Walter Greiner 《Acta Physica Hungarica A》1995,1(3-4):309-322
It is shown that in ideal relativistic hydrodynamics a phase transition from hadron to quark and gluon degrees of freedom in the nuclear matter equation of state leads to a minimum in the excitation function of the transverse collective flow. 相似文献
883.
D. Lenssen H. L. Bay St. Mesters C. Dieker D. Guggi R. Carius S. Mantl 《Journal of luminescence》1998,80(1-4):461-465
Recent band structure calculations indicate that ruthenium silicide (Ru2Si3) is semiconducting with a direct band gap. Electrical measurements lead to a band gap around 0.8 eV which is technologically important for fiber communications. This makes Ru2Si3 a promising candidate for silicon based optical devices, namely LEDs. We present first results on the epitaxial growth of ruthenium silicide films on Si(1 0 0) and Si(1 1 1) fabricated by the template method, a special molecular beam epitaxy technique. Orientational relationships on Si(1 1 1) have been determined. We characterized the films by Rutherford Backscattering and Channeling, X-ray diffraction and transmission electron microscopy. 相似文献
884.
Germanium(II)‐, Zinn(II)‐ und Blei(II)‐Derivate des polycyclischen Alumosiloxans [Ph2SiO]8[Al(O)OH]4
Michael Veith Hinka Hreleva Matthias Gasthauer Andreas Rammo Volker Huch 《无机化学与普通化学杂志》2006,632(6):985-991
Germanium(II)‐, Tin(II)‐ and Lead(II)‐Derivatives of the polycyclic Alumosiloxane [Ph2SiO]8[Al(O)OH]4 Five new derivatives of the polycyclic alumosiloxane [Ph2SiO]8[Al(O)OH]4 have been synthesized by replacement of the protic hydrogen atoms on the hydroxy‐groups attached to the aluminium atoms by the divalent group 14 elements germanium, tin and lead. The compounds can be divided in those with one metal atom per alumosiloxane moiety, [Ph2SiO]8[Al(O)OH]2[AlO2]M (M=Ge, Sn), and those with complete substitution of the protic hydrogen atoms by metal atoms like [Ph2SiO]8[AlO2]4M2 (M= Sn, Pb). Always one element of the series Ge, Sn, Pb is missing in the two types of compounds. Crystal structure analyses of [Ph2SiO]8[Al(O)OH]2[AlO2]2M · 2 C4H8O2 (M= Ge ( 1 ), Sn ( 2a )), [Ph2SiO]8[Al(O)OH]2[AlO2]2Sn · 2 THF ( 2b ) and [Ph2SiO]8[AlO2]4M2 (M= Sn ( 3 ), Pb ( 4 )) have been performed elucidating either polycyclic basket‐type ( 1 , 2a , 2b ) or closed polyhedral structures ( 3 , 4 ). 相似文献
885.
886.
N.
zkan A. St. J. Murphy R. N. Boyd A. L. Cole M. Famiano R. T. Güray M. Howard L.
ahin J. J. ZachR. deHaan J. Grres M. C. WiescherM. S. IslamT. Rauscher 《Nuclear Physics A》2002,710(3-4)
Total cross section measurements for the 102Pd(p, γ)103Ag and 116Sn(p, γ)117Sb reactions have been performed in the proton energy range 2.6 to 4.25 MeV, and for the 112Sn(α, γ)116Te reaction over the alpha beam energy range 7.0 to 10.5 MeV. An activation technique was used in which gamma rays from decays of the reaction products were detected off-line by two hyper-pure germanium detectors in a low background environment. Where possible, reaction rates are derived and the results compared to those of calculations generated by the NON-SMOKER and the MOST statistical model codes so as to judge their applicability for describing the cross sections needed for network calculations of nucleosynthesis in explosive astrophysical environments via the γ- and rp-processes. 相似文献
887.
Electrothermal atomic absorption spectrometry is applied to investigate the release of the selenium and tin atoms from pyrocoated
graphite support. The Coats and Redfern and Sturgeon approaches are used for estimation of the apparent activation energies
of atom release. The addition of tungsten and palladium modifiers leads to enhancement of the activation energies and changes
the kind of the vaporizing species for analytes. 相似文献
888.
Stéphane R Louboutin 《Comptes Rendus Mathematique》2002,334(8):625-628
We prove that for any even primitive Dirichlet character χ of odd conductor qχ>1 we have where κ:=2+γ?log(π/4)=2.81878…. To cite this article: S.R. Louboutin, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 625–628. 相似文献
889.
Elke Baum Patrik Dahlke Volker Kaiser Michel Molinier Roland E. Schmidt Jürgen Pebler Werner Massa Dietrich Babel 《无机化学与普通化学杂志》2006,632(14):2244-2250
890.
Lydie Viau Itamar Malkowsky Karine Costuas Stéphanie Boulin Lo?c Toupet Eléna Ishow Keitaro Nakatani Olivier Maury Hubert Le Bozec 《Chemphyschem》2006,7(3):644-657
Two 2,2'-bipyridines, substituted at the 4,4'-positions by p-dialkylaminophenylazostyryl moieties p-R2N-C6H4-N=N-C6H4-CH=CH-[6 a, R2N=nBu2N; 6 b, R2N=(nBu)(C4H8OTHP)N; 6 c, R2N=(nBu)(C4H8OH)N], were successfully synthesized by using Wadworth-Emmons reactions. The X-ray structure of 6 a has been determined. Esterification of 6 c with 2-bromoisobutyroylbromide afforded 6 d. This ligand was used as an initiator for the living radical polymerization of methylmethacrylate (MMA) and gave rise to macroligand 6 e. Thin films of good optical quality were obtained by the spin-coating technique. Photoisomerization experiments were carried out on 6 a in solution and on 6 e in both solution and film, and the kinetics of photochemical (E/Z) and thermal (Z/E) isomerization were investigated. They were found to show Z-E back isomerization typical of aminoazobenzene-type rather than of push-pull-type molecules. Density functional theoretical (TD-DFT) calculations were performed on model compound 6 a' (R2N=Me2N) to understand the structural and electronic transitions of the corresponding E-E, E-Z and Z-Z isomers. It was found that the E-E isomer is almost planar as observed experimentally by X-ray diffraction, whereas the Z-Z isomer, which is 35.4 kcal mol(-1) less stable than the E-E isomer, is nonplanar. The theoretical studies also reveal that several transitions of pi-pi*, n-pi* and charge-transfer (CT) types, are involved in the long-wavelength transition of 6 a (E-E). The same observations can be made for the (Z-Z) isomer, and the TD-DFT simulated spectrum fits quite nicely to the experimental, reproducing and explaining the apparition of a blue-shifted charge-transfer band at 390 nm. 相似文献