InP(001)-(2 x 1) surface: a hydrogen stabilized structure

The InP(001)(2 x 1) surface has been reported to consist of a semiconducting monolayer of buckled phosphorus dimers. This apparent violation of the electron counting principle was explained by effects of strong electron correlation. Combining first-principles calculations with reflectance anisotropy spectroscopy and LEED experiments, we find that the (2 x 1) reconstruction is not at all a clean surface: it is induced by hydrogen adsorbed in an alternating sequence on the buckled P dimers. Thus, the microscopic structure of the InP growth plane relevant to standard gas phase epitaxy conditions is resolved and shown to obey the electron counting rule.     

Analysis of relative isotopologue abundances for quantitative profiling of complex protein mixtures labelled with the acrylamide/D3-acrylamide alkylation tag system

The new method of analysis of relative isotopologue abundances (ARIA) applied here is based on the evaluation of total isotope patterns of tryptic protein fragments measured by matrix-assisted laser desorption/ionisation time-of-flight mass spectrometry (MALDI-TOFMS) to calculate the mixing ratios of composites consisting of stable isotope labelled and isotopically natural (unlabelled) proteins, as described in an accompanying paper in this issue. Recently, Sechi (Rapid Commun. Mass Spectrom. 2002; 16: 1416-1424) and Gehanne et al. (Rapid Commun. Mass Spectrom. 2002; 16: 1692-1698) introduced the use of differential quantitative mass analysis by MALDI-TOFMS using mixtures of standard proteins alkylated prior to two-dimensional polyacrylamide gel electrophoresis (2D-PAGE) with either acrylamide (AA) or deuterium-labelled [2,3,3'-D(3)]-acrylamide (D3AA). In the present study we validate the AA/D3AA system, firstly by measuring the yield of proteins alkylated with AA, and secondly by using differential radioactive labels ((125)I and (131)I) to quantitatively establish that non-comigration in 2D-PAGE is negligible. ARIA is then applied to quantitatively estimate the relative proportions of peptides labelled with AA or D3AA in the validated system, using typical silver-stained 2D-PAGE protein spots from 2D gels loaded with 150 microg of total liver protein. The precision and limitations of ARIA quantification of peptides differentially alkylated with isotopomeric reagents are discussed.     

Modular diphosphine ligands based on bisphenol A backbones

A straightforward two-step synthesis is used to obtain new phosphorus-containing ligands based on readily available bisphenol A type backbones. Five diphosphine ligands have been prepared in good yields. An X-ray crystallographic study is presented for ligand 5. Preliminary results on rhodium-catalyzed hydroformylation exemplify the use of these ligands for homogeneous catalysis.     

A non-trivial Fréchet quotient of the space of real analytic functions

We prove that the space of real analytic functions ${\cal A}(\Omega)$ on an arbitrary open set $\Omega \subseteq \mathbb{R}^d$ has a Fréchet infinite dimensional quotient space with a continuous norm. Received: 4 February 2002     

Heavy quark production in heavy ion colliders

We describe updated calculations of $Q\bar Q$ production in pp and π ^- p interactions. We compare these results to total cross section data and discuss how the baseline cross sections extrapolate to heavy ion collider energies. We touch upon the differences between leading and next-to-leading order heavy quark production. Finally, we discuss the implications of our calculations for quarkonium production. Our discussion here focuses on bottom quarks.     

Two-photon annihilation into baryon-antibaryon pairs

We study the handbag contribution to two-photon annihilation into baryon-antibaryon pairs at large energy and momentum transfer. We derive factorization of the process amplitude into a hard subprocess and form factors describing the soft transition, assuming that the process is dominated by configurations where the (anti)quark approximately carries the full momentum of the (anti)baryon. The form factors represent moments of time-like generalized parton distributions, so-called distribution amplitudes. A characteristic feature of the handbag mechanism is the absence of isospin-two components in the final state, which in combination with flavor symmetry provides relations among the form factors for the members of the lowest-lying baryon octet. Assuming dominance of the handbag contribution, we can describe current experimental data with form factors of plausible size, and predict the cross sections of presently unmeasured channels. Received: 3 July 2002 / Revised version: 7 October 2002 / Published online: 20 November 2002 RID="a" ID="a" e-mail: mdiehl@physik.rwth-aachen.de RID="b" ID="b" e-mail: kroll@physik.uni-wuppertal.de RID="c" ID="c" e-mail: cvogt@nordita.dk     

All-optical sampling with a monolithically integrated Mach-Zehnder interferometer gate

An all-optical sampler consisting of a polarization-independent monolithic Mach-Zehnder interferometer with integrated semiconductor optical amplifiers and a temporal resolution of 1 ps is presented. As an example, a simple 320-Gbit/s pattern has been successfully sampled, demonstrating the functionality of this scheme for high-bit-rate waveform characterizations in light-wave systems.     

Dynamics of individual atomic kinks during crystal dissolution

The dynamics of kink motion via atom removal/deposition as a fundamental step in dissolution/crystallization of solids have become directly accessible by a novel scanning tunneling microscopy technique. Results obtained for the electrochemical dissolution of Cu(100) in HCl solution show pronounced local dissolution/redeposition fluctuations at the individual kinks even at the onset of Cu dissolution with average kink propagation and reaction rates in the range 10(3) and 10(5) atoms s(-1), respectively. These experiments allow one to directly measure the central kinetic properties of this electrochemical reaction.