Short-and long-range order effects on resonance energy transfer in crystals and glasses

Resonance energy transfer by the Förster-Dexter mechanism in a cubic crystal and in a rigid homogeneous medium is studied. The homogeneous medium is modeled using a hard-sphere fluid (HSF) radial distribution function. This distribution is more realistic than the commonly used uniform distribution with excluded volume (UDEV) function. For the dipole-dipole mechanism, both models yield essentially the same donor luminescence decay, except for small critical radii. For the exchange mechanism, however, the two models differ significantly. In particular, to fit a given experimental decay, the UDEV model requires both a larger effective Bohr radius and a larger rate constant at collisional distance than the HSF model.     

Self-broadening of space-time spectra of few-cycle pulses in dielectric media

The nonparaxial dynamics of spectra of pulses comprising a few cycles of a light field is analyzed in transparent nonlinear media with dispersion. It is shown that the inhomogeneous self-broadening of the time spectrum of a pulse proceeds more effectively into the blue region at all spatial frequencies. A decrease in the energy in the central part of the time spectrum is realized mainly at high spatial frequencies.     

Efficiency of shear surface wave transformation by the motion of the confining domain wall

The transformation of a shear surface magnetoelastic wave by the motion of the 180° confining domain wall in a ferromagnet is considered. Changes in the wave spectrum due to the motion of the wall are correlated with the variations of the energies of the elastic and magnetic subsystems. The efficiency of surface wave transformation by the domain wall motion is estimated in terms of energy. The frequency dependences of the mean energy density of the wave are found. It is shown that the energy density grows with wall velocity.     

Using the new in–in method for the synthesis of polyisoprene/polystyrene heteroarm star polymers

The basis of the two‐step in–in method is as follows: star polymers with poly(divinyl benzene) cores, synthesized by the arm‐first method, include many unreacted double bonds in their core, and these double bonds can be attacked by the carbanions of some monomers such as styrene and dienes. In this work, linear polyisoprene chains were used to attack the double bonds existing in the poly(divinyl benzene) cores of polystyrene star polymers, so that a heteroarm star polymer with polystyrene and polyisoprene arms was synthesized. It was later well characterized with size exclusion chromatography, light scattering, viscometry, UV spectroscopy, dynamic mechanical thermal analysis, and ¹H NMR. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 135–142, 2003     

Degradation of Metal 2-Acrylamido-2-methylpropanesulfonate-N-Vinylpyrrolidine Copolymers in Aqueous Solutions Containing Different Cations

The influence of single- and double-charged cations on degradation of metal 2-acrylamido-2-methylpropanesulfonate-N-vinylpyrrolidine copolymers in aqueous solutions in the presence of potassium peroxodisulfate, K₂S₂O₈, at 50 and 70°C was studied by viscosimetry.     

Preparation and Characteristics of a Cation Exchanger Based on Oxidized Anthracite

The features of anthracite oxidation as influenced by temperature and time were determined. Physicochemical and sorption characteristics of the resulting cation exchanger were studied.     

Crystallographic report: Crystal structure of 1‐bromo‐1′‐[(2S)‐N‐(1‐hydroxy‐3‐methylbutane‐2‐yl)]‐ferroceneamide

For the unsymmetrical title compound, 1‐bromo‐1′‐[(2S)‐N‐(1‐hydroxy‐3‐methylbutane‐2‐yl)]‐ferroceneamide, two independent molecules were found in the asymmetric unit. Copyright © 2003 John Wiley & Sons, Ltd.     

Energy and Acid-Base Characteristics of the Surface of Nitramine Fillers for Polymeric Composites

Single crystals of nitramine fillers for special-purpose polymeric composites are characterized by the surface energy and its constituents and also by the acidity of their surface.     

Thiol–norbornene materials: Approaches to develop high Tg thiol–ene polymers

The ability to prepare high T_g low shrinkage thiol–ene materials is attractive for applications such as coatings and dental restoratives. However, thiol and nonacrylated vinyl materials typically consist of a flexible backbone, limiting the utility of these polymers. Hence, it is of importance to synthesize and investigate thiol and vinyl materials of varying backbone chemistry and stiffness. Here, we investigate the effect of backbone chemistry and functionality of norbornene resins on polymerization kinetics and glass transition temperature (T_g) for several thiol–norbornene materials. Results indicate that T_gs as high as 94 °C are achievable in thiol–norbornene resins of appropriately controlled chemistry. Furthermore, both the backbone chemistry and the norbornene moiety are important factors in the development of high T_g materials. In particular, as much as a 70 °C increase in T_g was observed in a norbornene–thiol specimen when compared with a sample prepared using allyl ether monomer of analogous backbone chemistry. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5686–5696, 2007     

Fluid-fluid phase separation in colloid-polymer mixtures studied with small angle light scattering and light microscopy

Mixtures of colloidal silica spheres and polydimethylsiloxane in cyclohexane with a colloid-polymer size ratio of about one were found to phase separate into two fluid phases, one which is colloid-rich and one which is colloid-poor. In this work the phase separation kinetics of this fluid-fluid phase separation is studied for different compositions of the colloid-polymer mixtures, and at several degrees of supersaturation, with small angle light scattering and with light microscopy. The small angle light scattering curve exhibits a peak that grows in intensity and that shifts to smaller wave vector with time. The characteristic length scale that is obtained from the scattering peak is of the order of a few μm, in agreement with observations by light microscopy. The domain size increases with time as , which might be an indication of coarsening by diffusion and coalescence, like in the case of binary liquid mixtures and polymer blends. For sufficiently low degrees of supersaturation the angular scattering intensity curves satisfy dynamical scaling behavior.