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141.
The problem of distribution of the electric field and electric current in a thin cylindrical metallic wire in the presence of the skin effect taking into account specular-diffuse reflection of electrons from the inner surface of the wire has been solved for the first time. The limiting cases have been considered. The obtained results have been discussed. 相似文献
142.
D. A. Rusakov A. A. Filaretov M. N. Bubentsova V. P. Danilov L. N. Komissarova 《Russian Journal of Inorganic Chemistry》2006,51(6):852-861
Gallium lithium hydroxyphosphate LiGa(OH)PO4 was prepared under mild hydrothermal conditions (T = 160°C, τ = 48 h) and characterized (IR spectroscopy, chemical and thermal analysis). LiGa(OH)PO4 was found to be structurally similar to the ambligonite family phases. The crystal structure was refined by the Rietveld method (space group $P\bar 1$ , Z = 2): a = 5.0853(1) Å, b = 5.2973(1) Å, c = 7.3006(1) Å, α = 67.830(1)°, β = 67.839(1)°, γ = 82.027(1)°, R p = 0.0519, R wp = 0.0765. A zero SHG signal confirmed a centrosymmetric structure of the compound. The structure is represented by a mixed {Ga(OH)[PO4]} 3∞ ? framework composed of the PO4 tetrahedra and GaO4(OH)2 octahedra. The framework contains hexagonal channels running in the [100] and [010] directions. The basic element of the framework is a linear chain of GaO4(OH)2 octahedra sharing trans OH vertices. The Li+ ions reside in the framework voids. 相似文献
143.
144.
A. G. Ibragimov L. O. Khafizova K. G. Satenov L. M. Khalilov L. G. Yakovleva S. V. Rusakov U. M. Dzhemilev 《Russian Chemical Bulletin》1999,48(8):1574-1580
The Cp2ZrCl2-catalyzed reaction of arylolefins (styrene,o- andp-methylstyrenes,trans-stilbene, 1,4-diphenyl-1,3-butadiene) with AlEt3 resulting in mono- and disubstituted alumacyclopentanes and substituted alumacyclopropanes was studied. The yield and ratio of cyclic organoaluminum compounds depend on the structure of the initial arylolefins and conditions of cycloalumination. 相似文献
145.
V. S. Rusakov V. S. Urusov R. V. Kovalchuk Yu. K. Kabalov S. V. Yudincev 《Hyperfine Interactions》2005,164(1-4):99-104
Mössbauer study of synthesized ferrite-garnet samples containing Zr, Th, Ce and Gd of the following composition: 1C – Ca2, 5 Ce0, 5 Zr2 Fe3 O12, 2C – Ca1, 5 GdCe0, 5 ZrFeFe3 O12, 1T – Ca2, 5 Th0, 5Zr2 Fe3 O12 and 2T – Ca1, 5 GdTh0, 5 ZrFeFe3 O12 are carried out. As a result of 57Fe Mössbauer study it is found that iron atoms in all investigated samples of garnets are in a trivalent state. The analysis of experimental Mössbauer spectra definitely specifies a various structural state of iron atoms in two investigated groups of samples: 1T, 1C and 2T, 2C. X-ray study have shown that 1T and 1C garnet samples crystallize in tetragonal space group I41/acd, but 2T and 2C samples crystallize in cubic space group Ia3d. 相似文献
146.
N. V. Anshukova A. I. Golovashkin L. I. Ivanova A. P. Rusakov 《Journal of Experimental and Theoretical Physics》2003,96(6):1045-1054
The effect of superstructural ordering in the oxygen sublattice (in addition to the influence of the antiferromagnetic interaction of copper ions) on the electron and phonon characteristics of oxide high-temperature superconductor (HTSC) systems has been studied. Taking into account this ordering effect, it is possible to explain a wide range of experimental data, including doping-induced changes in shape of the Fermi surface, features of the phonon spectra, the existence of stripes, the presence of a pseudogap and its coexistence with the superconducting gap, and some peculiarities in the phase diagrams of HTSCs. 相似文献
147.
Kinetics and thermodynamics of reversible disproportionation–comproportionation in redox triad oxoammonium cations – nitroxyl radicals – hydroxylamines
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Vasily D. Sen’ Ivan V. Tikhonov Leonid I. Borodin Evgeny M. Pliss Valery A. Golubev Mikhail A. Syroeshkin Alexander I. Rusakov 《Journal of Physical Organic Chemistry》2015,28(1):17-24
Kinetics and equilibrium of the acid‐catalyzed disproportionation of cyclic nitroxyl radicals R2NO? to oxoammonium cations R2NO+ and hydroxylamines R2NOH is defined by redox and acid–base properties of these compounds. In a recent work (J. Phys. Org. Chem. 2014, 27, 114‐120), we showed that the kinetic stability of R2NO? in acidic media depends on the basicity of the nitroxyl group. Here, we examined the kinetics of the reverse comproportionation reaction of R2NO+ and R2NOH to R2NO? and found that increasing in –I‐effects of substituents greatly reduces the overall equilibrium constant of the reaction K4. This occurs because of both the increase of acidity constants of hydroxyammonium cations K3H+ and the difference between the reduction potentials of oxoammonium cations ER2NO+/R2NO? and nitroxyl radicals ER2NO?/R2NOH. pH dependences of reduction potentials of nitroxyl radicals to hydroxylamines E1/3Σ and bond dissociation energies D(O–H) for hydroxylamines R2NOH in water were determined. For a wide variety of piperidine‐ and pyrrolidine‐1‐oxyls values of pK3H+ and ER2NO+/R2NO? correlate with each other, as well as with the equilibrium constants K4 and the inductive substituent constants σI. The correlations obtained allow prediction of the acid–base and redox characteristics of redox triads R2NO?–R2NO+–R2NOH. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
148.
L. N. Komissarova O. I. Solov’ev D. A. Rusakov M. A. Strelkov A. A. Filaretov 《Russian Journal of Inorganic Chemistry》2013,58(1):84-87
The phase formation in the subsolidus region of the Ag3PO4-ScPO4 quasi-binary system was studied by X-ray powder diffraction and differential thermal analyses throughout the range of concentration ratios of the initial components at an interval of 10 mol % within the temperature range 20–1000°C in air at atmospheric pressure. A T-x section was constructed. The formation of the binary phosphate Ag3Sc2(PO4)3 melting incongruently at 1300 ± 5°C was detected. The composition of an eutectic (with the melting point 900 ± 5°C) is between those of the compounds Ag3PO4 and Ag3Sc2(PO4)3. 相似文献
149.
Yu D. Perfiliev V. S. Rusakov L. A. Kulikov A. A. Kamnev K. Alkhatib 《Journal of Radioanalytical and Nuclear Chemistry》2005,266(3):557-560
Summary Resonant lines observed in source experiments are usually significantly broader thanthosein the corresponding absorber experiments.
In order to explain this phenomenon, the model of a trapped electron has been proposed. Auger electrons emitted, for instance,
after electron capture by 57Со or after the converted isomeric transition of119mSn, as well as secondary electrons, may be trapped in the vicinity of the nucleogenic ion. An asymmetric distribution of quadrupole
splittings in the resulting emission M?ssbauer spectra is thus a consequence of electron capture by lattice traps located
at different distances from the daughter ion. Estimates of quadrupole splitting values, which may be causedby trapped electrons
located at different distances from the nucleogenic atom, support the above mentioned model. 相似文献
150.
A. K. Zhubaev K. K. Kadyrzhanov V. S. Rusakov T. E. Turkebaev 《Hyperfine Interactions》2005,164(1-4):73-85
The paper reports on investigation of the laminar system ‘stainless steel 12Cr18Ni10Ti – Be’ at thermal treatment. There have
been determined sequences of phase transformations along with relative amount of iron-containing phases in the samples subjected
to thermal beryllization. It has been revealed that thermal beryllization of stainless steel thin foils results in γ→α transformation
and formation of the beryllides NiBe and FeBe2. It has also been revealed that direct γ→α- and reverse α→γ-transformations are accompanied by, correspondingly, formation
and decomposition of the beryllide NiBe. It is shown that distribution of the formed phases within sample bulk is defined
by local concentration of beryllium. Based on obtained experimental data there is proposed a physical model of phase transformations
in stainless steel at thermal beryllization. 相似文献