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61.
Carlos Kleber Z. Andrade Ricardo Alexandre F. Matos Viviane B. Oliveira Jussara A. Durães Maria J. A. Sales 《Journal of Thermal Analysis and Calorimetry》2010,99(2):539-543
Thermal properties of new ionic liquids (ILs) were investigated by thermogravimetry (TG/DTG) and differential scanning calorimetry
(DSC). Chlorides, tetrafluoroborates and hexafluorophosphates of (−)mentholpyrrolidinium and (−)-mentholimidazolium cations
revealed good thermal stability at air atmosphere. Morphological characteristics of poly(methyl methacrylate) (PMMA) matrices
doped with 10% of these ILs were also investigated by DRX and water absorption test. Into the matrix, they exhibited a very
satisfactory pattern concerning the polymer thermal stabilization. DSC results show that some of these ILs also present plasticizer
features since they can lower the polymer glass transition temperature (T
g) up to 317.15 K. 相似文献
62.
The copper(II)-gadolinium(III) and copper(II)-terbium(III) complexes studied in this report derive from disymmetric trianionic ligands abbreviated H3Li (i = 4-6). These ligands are obtained through reaction of different aldehydes with "half-units" having an amide function, the latter resulting from the monocondensation of different diamines with phenyl 2-hydroxy-3-methoxybenzoate. Upon deprotonation, the Li ligands (i = 4-10) possess an inner N2O2 coordination site with one amido, one imine, and two phenoxo functions, an outer O2O2 or O2O coordination site, and an amido oxygen atom positioned out of these two sites. The trianionic character of such ligands yields original anionic complexes in the presence of copper(II) or nickel(II) ions, with a 1/1 L/M stoichiometry. The crystal and molecular structures of four complexes, two 3d (1, 5) and two 3d-4f (12, 13) complexes, have been determined. Complex 1 crystallizes in the monoclinic space group C2/c: a = 27.528(2) A, b = 7.0944(7) A, c = 22.914(2) A, beta = 92.130(6) degrees , V = 4471.9(7) A(3), Z = 8 for C(21.5)H(27)CuKN(2)O(6.5). Complex 5 crystallizes in the monoclinic space group P2(1)/n (No. 14): a = 11.0760(9) A, b = 21.454(2) A, c = 15.336(1) A, beta = 101.474(1) degrees , V = 3571.5(5) A(3), Z = 4. Complex 12 crystallizes in the triclinic space group P (No. 2): a = 8.682(2) A, b = 11.848(2) A, c = 11.928(2) A, alpha = 81.77(3) degrees , beta = 89.17(3) degrees , gamma = 85.49(3) degrees , V = 1210.6(4) A(3), Z = 2 for C20H22CuN5O11Tb. Complex 13 belongs to the monoclinic space group C2/c: a = 25.475(5)A, b = 12.934(3)A, c = 15.023(3) A, beta = 91.06(3) degrees , V = 4949.02A3, Z = 8 for C21H25CuN4O12Tb. The structural determinations confirm that the dinuclear entities involved in 12 and 13 are disposed in a head-to-tail arrangement to give tetranuclear complexes in which the copper and lanthanide ions are positioned at the vertexes of a rectangle. In the [Cu-Gd]2 species, there are two different ferromagnetic Cu-Gd interactions. The stronger one is supported by the double phenoxo bridge (CuO2Gd) while the weaker one corresponds to the single amido bridge (Cu-N-C-O-Gd). Replacement of gadolinium ions with anisotropic terbium ions yields tetranuclear entities showing slow relaxation of magnetization and magnetization hysteresis. Detailed relaxation and hysteresis loop studies establish single-molecule magnet (SMM) behavior which is influenced by weak intermolecular interactions. 相似文献
63.
Gani T. Stamov 《Journal of Applied Mathematics and Computing》2008,27(1-2):243-255
By means of piecewise continuous functions Lyapunov’s functions we give new sufficient conditions for the global exponential stability of the unique positive almost periodic solutions of an non autonomous N-dimensional impulsive Lotka-Volterra diffusive competitive system with dispersion and fixed moments of impulsive perturbations. 相似文献
64.
2-D nanoscale LC combined with a triple quadrupole-linear ion trap mass spectrometer was applied to the analysis of a complex peptide mixture. A 2-D dual nanoscale LC-MS/MS system was compared to a conventional one. Peptides were separated with a strong cation exchange (SCX) microcolumn in the first dimension and two C18 nanocolumns were used as second dimension. MS experiments were performed using information-dependent data acquisition, where two precursor ions were selected from an enhanced MS (EMS) or an enhanced multicharged ion (EMC) as survey scan. The major benefit of EMC instead of EMS was a two-fold reduction of the data file and a 15% increase of characterized proteins. The advantage of the 2-D dual nanoscale LC-MS/MS system versus the conventional 2-D nanoscale LC-MS/MS system was reflected in the significant increase of peptides which were successfully identified within the same time frame. The first factor contributing to this increase was that the mass spectrometer was collecting twice the number of relevant MS/MS data. The second factor is the use of twice the number of SCX salt fractions in the first dimension, allowing a better sample fractionation, thereby reducing the number of peptides transferred to the second chromatographic dimension per salt fraction. 相似文献
65.
N-methyl acetanilides alkaline hydrolysis mechanism has been studied by means of solvent effect (DMSO and 2H2O) and of structure-reactivity correlation (log kobs = f(pKB aniline)). Our results are consistent with HO? rate determining attack only for p-nitro anilide and with a rate determining water assisted decomposition of the tetrahedral intermediate for X p-CH3O, H, p-Cl, m-Cl. 相似文献
66.
Viviane Cristina Gumiero Pedro Alves da Rocha Filho 《Journal of Dispersion Science and Technology》2013,34(11):1569-1573
Babassu is considered one of the greatest native resources in the world and its oil is used in body and hair formulations. The aim of this study was to evaluate the short-term stability in oil-in-water (O/W) nanoemulsions containing babassu oil prepared by emulsification phase inversion submitted to the centrifugation, thermal stress, and heating/cooling cycle tests. The formulations showed no change compared to the droplet size, polydispersity index, pH, and electrical conductivity values after thermal stress and heating/cooling cycle tests. Based on these results, the nanoemulsions obtained can be considered as promising disperse systems for pharmaceutical and cosmetic applications. 相似文献
67.
The present paper deals with the investigation of the stability of the zero solution of impulsive functional differential equations. By means of piecewise continuous functions coupled with the Razumikhin technique sufficient conditions for stability, uniform stability and asymptotic stability of the zero solution of such equations are found. 相似文献
68.
Viviane Pilla Leandro P. Alves Egberto Munin Marcos T.T. Pacheco 《Optics Communications》2007,280(1):225-229
The radiative quantum efficiencies η of the CdSe/ZnS core-shell nanoparticles embedded into polymethyl methacrylate (PMMA) and suspended in three different solvents: chloroform (CHCl3), toluene (C6H5CH3) and tetrahydrofuran (C4H8O) were measured using thermal lens (TL) technique. The mode-mismatched pump-probe TL measurements were accomplished in function of the CdSe/ZnS quantum-dot concentration (12-60 mg/ml) at λe = 594 nm (pump) and λp = 632.8 nm (probe). The values obtained for η were higher for CdSe/ZnS nanoparticles suspended in tetrahydrofuran and chloroform, as compared to the values for toluene. Thermal diffusivity (D) and the absolute nonradiative quantum efficiency (φ) were determined. 相似文献
69.
Genevive Delmas Viviane Daviet Danielle Filiatrault 《Journal of Polymer Science.Polymer Physics》1976,14(9):1629-1639
Intrinsic viscosities have been measured at 25° on five ethylene–propylene copolymer samples ranging in composition from 33 to 75 mole-% ethylene. The solvents used were n-C8 and n-C16 linear alkanes and two branched alkanes, 2,2,4-trimethylpentane and 2,2,4,4,6,8,8-heptamethylnonane (br-C16). This choice was based on the supposition that the branched solvent would prefer the propylene segments and the linear solvent the ethylene segments, due to similarity in shape and possibly in orientational order. It was found that [η]n ? [η]br ≡ Δ[η] is indeed negative for propylene-rich copolymers, zero for a 56% ethylene copolymer, and positive for ethylene-rich copolymers. The Stockmayer–Fixman relation was used to obtain from Δ[η] a molecular-weight independent function of composition. The quantities (Δ[η]/[η])(1 + aM?1/2) and Δ[η]/M are linear with the mole percent ethylene in the range investigated with 200 ≤ a ≤ 2000. The possibility of using these results for composition determination in ethylene–propylene copolymers is discussed. Intrinsic viscosities in the same solvents are reported for two samples of a terpolymer with ethylidene norbornene. 相似文献
70.
Existence of almost periodic solutions for strong stable impulsive differential equations 总被引:1,自引:0,他引:1
Conditions for strong stability and the existence of almostperiodic solutions of systems of impulsive differential equationswith impulsive effect at fixed moments are obtained. The investigationsare carried out by means of piecewise continuous functions whichare analogues of Lyapunov functions. 相似文献