Modification of surface properties of electrospun polyamide nanofibers by means of a perfluorinated acridine

Polyamide 6 (PA6) nanofibers were prepared from formic acid solutions by using electrospinning technique. The fibers were smooth, defects free and with diameters smaller than 200 nm. Small amounts of a perfluorinated acridine were added as dopant to the feed solution to modify the wettability of the fibers. The effect of doping on the contact angle values is well apparent. The contact angle values go from 50° of pure PA6 to 120° when 6% of acridine is added. A comparison between fibers and films of pure and doped polyamide 6 was carried out in order to determine the effect of morphology on wettability. Thermal annealing near the T_g of the polymer promoted the segregation of the molecules to the surface, reaching contact angles of 131° with smaller amounts (4%) of acridine. The surface segregation was also promoted by time aging.     

Influence of the vertical profile of Saharan dust on the visible direct radiative forcing

The vertical profile of Saharan dust in the atmosphere is generally characterized by a large aerosol concentration in the mid troposphere, differently from the climatological distribution of other types of particles, that show a peak at the surface and a rapid decrease with height. Saharan dust is also characterized by particles of relatively large size of irregular shape, and variable values of the single scattering albedo (the ratio between radiation scattering and extinction). The dust's peculiar vertical distribution is expected to produce an effect on the calculation of the direct aerosol radiative forcing at the surface and at the top of the atmosphere. This effect is investigated by comparing estimates of aerosol direct visible radiative forcing at the surface and at the top of the atmosphere for dust vertical profiles measured in the Mediterranean, and for the climatological profile. The radiative forcing is estimated by means of an accurate radiative transfer model, and for the ocean surface. The sensitivity of the results on the solar zenith angle, aerosol optical depth, and aerosol absorption is also investigated. The aerosol radiative forcing at the surface shows a very small dependency on the aerosol vertical profile. At the top of the atmosphere, the radiative forcing is weakly dependent on the vertical profile (up to 10% variation on the daily average forcing) for low absorbing particles; conversely, it shows a strong dependency (the daily radiative forcing may vary up to 100%) for absorbing particles. The top of the atmosphere visible radiative forcing efficiency produced by dust having single scattering albedo <0.7 is higher by 4 W m⁻² when the observed vertical profile instead of the standard profile is used in the calculations (i.e. it produces a lower cooling). For values of the single scattering albedo around 0.67, the sign of the forcing depends on the vertical profile. The influence of the vertical distribution on the radiative forcing is largest at small values of the solar zenith angle, and at short wavelengths.     

A genetic algorithm for a global optimization problem arising in the detection of gravitational waves

The detection of gravitational waves is a long-awaited event in modern physics and, to achieve this challenging goal, detectors with high sensitivity are being used or are under development. In order to extract gravitational signals emitted by coalescing binary systems of compact objects (neutron stars and/or black holes), from noisy data obtained by interferometric detectors, the matched filter technique is generally used. Its computational kernel is a box-constrained global optimization problem with many local solutions and a highly nonlinear and expensive objective function, whose derivatives are not available. To tackle this problem, we designed a real-coded genetic algorithm that exploits characteristic features of the problem itself; special attention was devoted to the choice of the initial population and of the recombination operator. Computational experiments showed that our algorithm is able to compute a reasonably accurate solution of the optimization problem, requiring a much smaller number of function evaluations than the grid search, which is generally used to solve this problem. Furthermore, the genetic algorithm largely outperforms other global optimization algorithms on significant instances of the problem.     

羊八井50m~2RPC地毯性能研究YBJ-ARGO合作组(英文)

利用羊八井５０ｍ２ＲＰＣ地毯（ＹＢＪ－ＡＲＧＯ实验原型）的测试数据对其性能进行了分析研究,包括原初粒子方位角分布、天顶角分布、地毯的角分辨、探测时间系统误差对方位角分布的正弦调制、探测时间系统误差的离线修正、几何不对称的小型地毯探测器上原初粒子到达方向重建误差造成的方位角分布的不均匀性等．     

A note on Ramsey numbers

Upper bounds are found for the Ramsey function. We prove $\text{R(3, x) <}\text{cx}{}^2\text{ln}\text{x}$ and, for each k ? 3, $\text{R(k, x) <}\text{c}{}_{\mathrm{k}}\text{x}{}^{\mathrm{k\; ?\; 1}}\text{(}\text{ln}\text{x)}{}^{\mathrm{k\; ?\; 2}}$ asymptotically in x.     

High-spin isomers in Rn in the region of triple neutron core-excitations

The level scheme of ²¹²Rn has been extended to spins of ∼38?$\sim 38?$ and excitation energies of about 13 MeV using the ²⁰⁴Hg(¹³C, 5n)²¹²Rn reaction and γ-ray spectroscopy. Time correlated techniques have been used to obtain sensitivity to weak transitions and channel selectivity. The excitation energy of the 22⁺ core-excited isomer has been established at 6174 keV. Two isomers with τ=25(2) ns$\tau =25(2)\text{ns}$ and τ=12(2) ns$\tau =12(2)\text{ns}$ are identified at 12211 and 12548 keV, respectively. These are the highest-spin nuclear isomers now known, and are attributed to configurations involving triple neutron core-excitations coupled to the aligned valence protons. Semi-empirical shell-model calculations can account for most states observed, but with significant energy discrepancies for some configurations.     

Memory effects in quantum channel discrimination

We consider quantum-memory assisted protocols for discriminating quantum channels. We show that for optimal discrimination of memory channels, memory assisted protocols are needed. This leads to a new notion of distance for channels with memory, based on the general theory of quantum testers. For discrimination and estimation of sets of independent unitary channels, we prove optimality of parallel protocols among all possible architectures.     

A semi-analytical finite element formulation for modeling stress wave propagation in axisymmetric damped waveguides

A semi-analytical finite element (SAFE) method is presented for analyzing the wave propagation in viscoelastic axisymmetric waveguides. The approach extends a recent study presented by the authors, in which the general SAFE method was extended to account for material damping. The formulation presented in this paper uses the cylindrical coordinates to reduce the finite element discretization over the waveguide cross-section to a mono-dimensional mesh. The algorithm is validated by comparing the dispersion results with viscoelastic cases for which a Superposition of Partial Bulk Waves solution is known. The formulation accurately predicts dispersion properties and does not show any missing root. Applications to viscoelastic axisymmetric waveguides with varying mechanical and geometrical properties are presented.     

Organic contamination in clams,Venerupis aurea laeta and Cerastoderma edule glaucum,from Sicily (Italy)

Two species of edible clams Venerupis aurea laeta and Cerastoderma edule glaucum from Ganzirri Lake (Sicily, Italy) were investigated to determine OCP and PCB residues by GC-MS. Thirty-five samples were examined for two years in order to perform: a) their actual contamination; b) the daily dietary exposure of seafood consumers to the pollutants in question. In all the clams analysed in this study, PCB and OCP (4,4′-DDE) residues are always below the limits fixed by law. It seems that there is some seasonality of concentrations observed. In fact the more high concentrations of residues are detected in the hot months, for both species and years. Given the consumption of clams and the values obtained in this study for the two species analysed, it is possible estimate that the average daily dietary intake of NDL-PCB and of 4,4′-DDE for adults is really low.     

Exploring the Phase-Selective,Green, Hydrothermal Synthesis of Upconverting Doped Sodium Yttrium Fluoride: Effects of Temperature,Time, and Precursors

The aim of this work was i) to develop a hydrothermal, low-temperature synthesis protocol affording the upconverting hexagonal phase NaYF₄ with suitable dopants while adhering to the “green chemistry” standards and ii) to explore the effect that different parameters have on the products. In optimizing the synthesis protocol, short reaction times and low temperatures (below 150 °C) were considered. Yb³⁺ and Er³⁺ ions were chosen as dopants for the NaYF₄ material. Within the context of the second goal, parameters including nature of the precursors, treatment temperature, and treatment time were investigated to afford a pure hexagonal crystalline phase, both in the doped and undoped materials. To fully explore the synthesis results, the prepared materials were characterized from a structural (XRD), compositional (XPS, ICP-MS), and morphological (SEM) point of view. The upconverting properties of the compounds were confirmed by photoluminescence measurements.