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41.
42.
Tei L Bencini A Blake AJ Lippolis V Perra A Valtancoli B Wilson C Schröder M 《Dalton transactions (Cambridge, England : 2003)》2004,(13):1934-1944
The binding properties of 1,4,7-triazacyclononane ([9]aneN3) to metal cations can be adapted through sequential functionalisation of the secondary amines with aminoethyl or aminopropyl pendant arms to generate ligands with increasing numbers of donor atoms. The new amino functionalised pendant arm derivative of 1,4,7-triazacyclononane ([9]aneN3), L1, has been synthesised and its salt [H2L1]Cl2 characterised by X-ray diffraction. The protonation constants of the ligands L1-L4 having one, two or three aminoethyl or three aminopropyl pendant arms, respectively, on the [9]aneN3 framework, and the thermodynamic stabilities of their mononuclear complexes with CuII and ZnII have been investigated by potentiometric measurements in aqueous solutions. In order to discern the protonation sites of ligands L1-L4, 1H NMR spectroscopic studies were performed in D2O as a function of pH. While the stability constants of the CuII complexes increase on going from L1 to L2 and then decrease on going from L2 to L3 and L4, those for ZnII complexes increase from L1 to L3 and then decrease for L4. The X-ray crystal structures of the complexes [Cu(L1)(Br)]Br, [Zn(L1)(NO3)]NO3, [Cu(L2)](ClO4)2, [Ni(L2)(MeCN)](BF4)2, [Zn(L4)](BF4)2.MeCN and [Mn(L4)](NO3)2.1/2H2O have been determined. In both [Cu(L1)(Br)]Br and [Zn(L1)(NO3)]NO3 the metal ion is five co-ordinate and bound by four N-donors of the macrocyclic ligand and by one of the two counter-anions. The crystal structures of [Cu(L2)](ClO4)2 and [Ni(L2)(MeCN)](BF4)2 show the metal centre in slightly distorted square-based pyramidal and octahedral geometry, respectively, with a MeCN molecule completing the co-ordination sphere around NiII in the latter. In both [Zn(L4)](BF4)2.MeCN and [Mn(L4)](NO3)2.1/2H2O the metal ion is bound by all six N-donors of the macrocyclic ligand in a distorted octahedral geometry. Interestingly, and in agreement with the solution studies and with the marked preference of CuII to assume a square-based pyramidal geometry with these types of ligands, the reaction of L4 with one equivalent of Cu(BF4)2.4H2O in MeOH at room temperature yields a square-based pyramidal five co-ordinate CuII complex [Cu(L6)](BF4)2 where one of the three propylamino pendant arms of the starting ligand has been cleaved to give L6. 相似文献
43.
44.
Vito Vitrih 《Annali dell'Universita di Ferrara》2008,54(2):349-359
In this paper, four-pencil lattices on tetrahedral partitions are studied. The explicit representation of a lattice, based
upon barycentric coordinates, enables us to extend the lattice from a single tetrahedron to a tetrahedral partition. It is
shown that the number of degrees of freedom is equal to the number of vertices of the tetrahedral partition. The proof is
based on a lattice split approach.
相似文献
45.
Raymond P. Vito 《International Journal of Non》1974,9(5):325-330
This is a study on the stability of movement of a particle subject to displacement on a plane and linked to two supports fixed by identical non-linear springs. It is demonstrated that even a slight “softening” non-linearity completely modifies the characteristics of the stability of the system. 相似文献
46.
47.
Serena Fiorito Francesco Epifano Francesca Preziuso Vito Alessandro Taddeo Claudio Santi Salvatore Genovese 《Tetrahedron letters》2017,58(4):371-374
The chromane core is widely represented in nature being part of a wide array of secondary metabolites of plant, fungal, and bacterial origin. In this paper an improved method for the chemical synthesis of differently substituted chromanes is described. Substituted 2H-1-benzopyrans have been synthesized in good to excellent yields (52–81%) by treatment of 3,3-dimethylallyl and propenylbenzene ethers of differently substituted phenols with phenylselenyl chloride. 相似文献
48.
Leydi Erika Sarmiento Mildred Rodríguez Lorenzo Echevarria Vito Lubes 《Journal of solution chemistry》2010,39(10):1484-1491
The complex species formed between vanadium(III) and 1,10-phenanthroline (phen), 2,2′-bipyridine (bipy), and 8-hydroxyquinoline
(8hq) were studied in aqueous solution by means of electromotive forces measurements, emf(H), at 25 °C with 3.0 mol⋅dm−3 KCl as the ionic medium. The potentiometric data were analyzed using the least-squares computational program LETAGROP, taking
into account the hydrolytic vanadium(III) species formed in solution. Analysis of the vanadium(III)–phen system data shows
the formation of [VHL]4+, [V(OH)L]2+, [V2OL2]4+ and [V2OL4]4+ complexes. In the vanadium(III)–bipy system the [VHL]4+, [V(OH)L]2+, [V2OL2]4+ and [V2OL4]4+ complexes were observed, and in the vanadium(III)–8hq system the complexes [V(OH)L]+, [V(OH)2L], [VL2]+ and [VL3] were detected. 相似文献
49.
Pedro R. Aranda Susana Moyano Luis D. Martinez Irma E. De Vito 《Analytical and bioanalytical chemistry》2010,398(2):1043-1048
A new, simple, and selective method for preconcentration and determination of Cr(VI) in aqueous samples. After adsorption
in “batch mode” on Aliquat 336-AC, determinations were made directly on the solid by X-ray fluorescence spectrometry, which
had the advantage of not requiring the step of elution of the chromium retained. The enrichment factor was calculated considering
that the tablets obtained from 10 mL solution of Cr(VI) (1000 μg L-1) had a final thickness of 0.64 mm and a diameter of 16.7 mm; the volume deposited on the pellet was 0.14 cm3. The preconcentration factor obtained was 71-fold, which was highly satisfactory for chromium trace analysis by XRF. Finally,
the method was successfully applied to the determination of Cr(VI) in drinking water samples. 相似文献
50.
Anacardium occidentale belongs to the family Anacardiaceae and is principally grown in tropical America (Mexico, Peru, Brazil, etc.) and India. Cashew nuts contain low amounts of hydroxy alkyl phenols that come from an oily liquid present in their shell and that is known as cashew-nut shell liquid. This paper reports the alkyl phenols composition of cold pressed raw and roasted cashew nut oil. First of all, cashew nut shell liquid was used for a basic fractionation of the alkyl phenol classes by preparative TLC and definitively identified by GC-MS and GC-FID. Anacardic acids were the major alkylphenols contained in both oils followed by cardol, cardanol and 2-methylcardol compounds, respectively. Raw and roasted oils did not show different compositions except for cardanols. The oil produced from roasted cashew nut reported a higher concentration of cardanols. Furthermore, tocopherols and other minor polar compounds were determined by HPLC-FLD and HPLC-DAD-MS, respectively. Tocopherol content varied in a range of 171.48-29.56mg/100g from raw to roasted cashew nut oil, being β-tocopherol the one which presented a higher decrease (93.68%). Also minor polar compounds in cashew oil decreased after roasting from 346.52 to 262.83mg/kg. 相似文献