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991.
Adel Attia Markéta Zukalová Jiří Rathouský Arnošt Zukal Ladislav Kavan 《Journal of Solid State Electrochemistry》2005,9(3):138-145
A mesoporous electrode material whose structure is composed of anatase nanocrystals stabilized by alumina is reported. Powder X-ray diffraction shows the anatase phase only, but micro-Raman spectroscopy shows that the materials have a core-shell morphology with grains of bulk anatase covered by a thin rutile layer on the surface. This structure is unique when compared to analogous materials stabilized by zirconia (PNNL-1). Nitrogen adsorption isotherms demonstrate a monotonous increase in surface area and mesopore volume with increasing Al content. Thin film electrodes from these materials were characterized by lithium insertion electrochemistry. Cyclic voltammograms exhibit significant differences in Li accommodation in Al-free and Al-stabilized materials. 相似文献
992.
[Reaction: see text] Transformation of enantiopure diastereoisomers (2R,1'S)- and (2S,1'S)-2-(1-aminoalkyl)epoxides into the corresponding 4-(1-aminoalkyl)-1,3-dioxolanes is achieved by reaction with different ketones in the presence of BF3.Et2O. The conversion takes place in very high yields, total selectivity, and without epimerization. A mechanism to explain this transformation is proposed. The obtained 1,3-dioxolanes can be deprotected, and (2R,3S)- and (2S,3S)-3-aminoalkano-1,2-diols were isolated. 相似文献
993.
Wen J. Mei Ying X. Liu Jie Liu Jun Li Kang C. Zheng Liang N. Ji 《Transition Metal Chemistry》2005,30(1):82-88
Two mixed porphyrin–polypyridyl RuII complexes [Ru(bpy)2(MPyTPP)Cl]Cl (1) and [Ru(phen)2(MPyTPP)Cl]Cl (
2
) (bpy=2,2-bipyridine; phen=1,10-phenanthroline; MPyTPP=5-monopyridyl-10,15,20–triphenylporphyrin) have been synthesized and characterized by elementary analysis, e.s.–m.s., cyclic voltammetry and u.v.–vis. spectroscopy. The DNA-binding properties of these complexes were investigated by electronic spectra, c.d. spectra and viscosity experiments. The results suggested that both complexes (1) and (2) bind to DNA in an outside binding mode. At the same time, theoretical calculations applying the ab initio and the density functional theory (DFT) methods were also performed, and the results showed that there is no good planarity on the main ligand MPyTPP of these complexes, and there are rather great distortion angles (dihedral angles ca. 72°) between the porphrin ring and each of the 10-, 15-, 20-phenyl groups. This may be the reason why the complexes bind to DNA in an outside mode, instead of an intercalative mode. 相似文献
994.
The polarographic behaviour of 2-nitronaphthalene was investigated by DC tast polarography (DCTP) and differential pulse polarography (DPP), both at a dropping mercury electrode, and differential pulse voltammetry and adsorptive stripping voltammetry, both at a hanging mercury drop electrode. Optimum conditions have been found for the determination of 2-nitronaphthalene by the given methods in the concentration ranges of 2×10–6–1×10–4, 2×10–7–1×10–4, 1×10–8–1×10–4 and 2×10–9–1×10–8 M, respectively. Practical applicability of these techniques was demonstrated by the determination of 2-nitronaphthalene in drinking and river water after its preliminary separation and preconcentration using liquid–liquid and solid-phase extraction with limits of determination of 3×10–10 M (drinking water) and 3×10–9 M (river water). 相似文献
995.
996.
Shujiang Tu Fang Fang Songlei Zhu Tuanjie Li Xiaojing Zhang Qiya Zhuang Shuijun Ji Yong Zhang 《Journal of heterocyclic chemistry》2005,42(1):29-32
The synthesis of bifunctional pyridine and quinolione derivatives were investigated using terephthalic and isophthalic aldehydes as a precursor. The reaction proceeds under microwave irradiation with good yield (70–92%) and short reaction time (7–9 min.). We provide a rapid and efficient method of synthesizing a range of bifunctional monocyclic and bicyclic products related to 1,4‐dihydropyridines (1,4‐DHPs). 相似文献
997.
Different cellular accumulations with distinct fluorescence properties of BMVC in cancer cells from normal cells allow us to establish a simple and economic method for the diagnosis of cancer cells. With using a light emitting diode to excite the BMVC molecule, microarray fluorescence analysis of a cell‐based glass chip provides an easy method towards the detection of a limited number of cancer cells. 相似文献
998.
Ming Xu Yong Ji Jing‐Lin Zuo Yi‐Zhi Li Xiao‐Zeng You 《Journal of heterocyclic chemistry》2005,42(5):847-850
Two new unsymmetrical tetrathiafulvalene (TTF) derivatives, 2,3‐bis(cyanoethylthio)‐6,7‐(methyl‐ethylenedithio)tetrathiafulvalene ( 6a ) and 2,3‐bis(cyanoethylthio)‐6,7‐(cyclopentodithio)tetrathiafulvalene ( 6b ), have been prepared and characterized by NMR, MS, IR and Elemental analyses. The molecular structures have been determined by X‐ray crystallography. Their redox properties have been investigated by cyclic voltammetry in dichloromethane solution and each compound shows two reversible single‐electron redox couples. 相似文献
999.
Minimate EDXRF谱仪在水泥工业分析中的应用 总被引:2,自引:0,他引:2
Minimate EDXRF谱仪是由低功率X射线管、封闭式正比计数管和2048道分析器组成,可分析原子序数11以上的元素(其中钠和镁需通氦气).作者用该仪器分析了粉末状水泥中MgO、Al_2O_3、SiO_2、SO_3、K_2O、CaO和Fe_2O_3等组成,并对水泥生料的取样误差作了估计.结果表明,该仪器可满足水泥制品的控制分析. 相似文献
1000.
收集了工业上用于重油加氢脱硫的 Ni M o/γ Al2 O3 失活催化剂, 用超声波萃取, 超临界流体萃取( S F E)等方法对其进行了处理, 用热重( T G)、差热分析( D T A)、程序升温氧化质谱( T P O M S)、扫描电镜能谱仪( S E M E D S)、 X 射线衍射仪( X R D)、程序升温还原( T P R)等方法对处理前后的催化剂进行了表征, 探讨了导致催化剂失活的主要原因. 结果表明, 积炭, 金属沉积是催化剂失活的主要原因, 经去除沉积的金属和烧炭后, 失活重油加氢催化剂的活性状态可得到恢复, 同时失活催化剂从工业反应器中的卸出方式也会对催化剂的性质产生影响. 相似文献