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排序方式: 共有93条查询结果,搜索用时 196 毫秒
61.
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de Farias RF de Souza JM de Melo JV Airoldi C 《Journal of colloid and interface science》2000,227(1):147-151
Polyaniline deposited on As(2)O(3) surface resulted in a new material, which was characterized by infrared spectoscopy, thermogravimetry, differential scanning calorimetry, scanning electron microscopy, X-ray diffraction, and cyclic voltammetry. The mass percentage of polymer deposited on oxide surface is approximately 13%. The scanning electron microscopy images as well as the X-ray diffraction patterns provided conclusive evidence that the oxide surface is coated by the polymer. The cyclic voltammograms of the polyaniline adsorbed on As(2)O(3) surface showed that the adsorbate exerts remarkable effects on redox processes on this oxide. The pure oxide exhibited two oxidation/reduction peaks at 0.25/-0.06 and 0.47/-0.25 V attributed tentatively to the processes As(2)O(3)(s)+6H(+)+6e(-)=2As(s)+3H(2)O and As(s)+3H(+)+3e(-)=AsH(3)(g), respectively. The polyaniline-coated sample exhibited a better-defined voltammogram in which the first oxidation peak of the oxide had its intensity increased about four times. Copyright 2000 Academic Press. 相似文献
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Alves GA Amato S Anjos JC Appel JA Bracker SB Cremaldi LM Darling CL Dixon RL Errede D Fenker HC Gay C Green DR Jedicke R Kaplan D Karchin PE Kwan S Leedom I Lueking LH Luste GJ Mantsch PM de Mello Neto JR Metheny J Milburn RH de Miranda JM da Motta Filho H Napier A d'Olivera AB Rafatian A dos Reis AC Reucroft S Ross WR Santoro AF Sheaff M Souza MH Spalding WJ Stoughton C Streetman ME Summers DJ Takach SF Wu Z 《Physical review letters》1992,69(22):3147-3150
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Donglong Fu Dr. Joel E. Schmidt Dr. Paul Pletcher Pelin Karakiliç Xinwei Ye Carolien M. Vis Prof. Dr. Pieter C. A. Bruijnincx Dr. Matthias Filez Laurens D. B. Mandemaker Prof. Dr. Louis Winnubst Prof. Dr. Ir. Bert M. Weckhuysen 《Angewandte Chemie (International ed. in English)》2018,57(38):12458-12462
Facile fabrication of well‐intergrown, oriented zeolite membranes with tunable chemical properties on commercially proven substrates is crucial to broadening their applications for separation and catalysis. Rationally determined electrostatic adsorption can enable the direct attachment of a b‐oriented silicalite‐1 monolayer on a commercial porous ceramic substrate. Homoepitaxially oriented, well‐intergrown zeolite ZSM‐5 membranes with a tunable composition of Si/Al=25–∞ were obtained by secondary growth of the monolayer. Intercrystallite defects can be eliminated by using Na+ as the mineralizer to promote lateral crystal growth and suppress surface nucleation in the direction of the straight channels, as evidenced by atomic force microscopy measurements. Water permeation testing shows tunable wettability from hydrophobic to highly hydrophilic, giving the potential for a wide range of applications. 相似文献
67.
Several diselenides were tested for catalytic activity in Baeyer-Villiger reactions with 60% aqueous hydrogen peroxide. Bis[3,5-bis(trifluoromethyl)phenyl] diselenide forms the corresponding 3,5-bis(trifluoromethyl)benzene seleninic acid in situ, which is a highly reactive and selective catalyst for the oxidation of carbonyl compounds in 1,1,1,3,3,3-hexafluoro-2-propanol, 2,2,2-trifluoroethanol, or dichloromethane. 相似文献
68.
Aitala EM Amato S Anjos JC Appel JA Ashery D Banerjee S Bediaga I Blaylock G Bracker SB Burchat PR Burnstein RA Carter T Carvalho HS Costa I Cremaldi LM Darling C Denisenko K Fernandez A Gagnon P Gerzon S Gobel C Gounder K Granite D Halling AM Herrera G Hurvits G James C Kasper PA Kondakis N Kwan S Langs DC Leslie J Lichtenstadt J Lundberg B Manacero A MayTal-Beck S Meadows B de Mello Neto JR Milburn RH de Miranda JM Napier A Nguyen A d'Oliveira AB O'Shaughnessy K Peng KC Perera LP Purohit MV 《Physical review letters》1996,76(3):364-367
69.
The classical 0–1 knapsack problem is considered with two objectives. Two methods of the two–phases type are developed to generate the set of efficient solutions. In the first phase, the set of supported efficient solutions is determined by optimizing a parameterized single-objective knapsack problem. Two versions are proposed for a second phase, determining the non-supported efficient solutions: both versions are Branch and Bound approaches, but one is breadth first, while the other is depth first. Extensive numerical experiments have been realized to compare the results of both methods. 相似文献
70.
JM Pakarinen H Moisio S Holopainen P Vainiotalo 《Rapid communications in mass spectrometry : RCM》1999,13(14):1485-1490
2-Methoxyethanol chemical ionization of amines, carboxylic acids and amino acids has been found to produce numerous adduct ions. The most intense adduct ions for amines are [M + H](+) and [M + 77](+), for carboxylic acids [M + 27](+), [M + 59](+) and [M + 77](+), and for amino acids [M + H](+), [M + 13](+), [M + 27](+) and [M + 77](+). Either the adduct ion [M + H](+) or [M + 77](+) was the most abundant ion found for amino acids. The proton affinities of amino acids are noticed to control the formation of the [M + H](+) and [M + 77](+) ions. The relative abundance of [M + 13](+) and [M + 27](+) ions varied for different amino acids being most intense for phenylalanine and aspartic acid. Copyright 1999 John Wiley & Sons, Ltd. 相似文献