Storage yard operations in container terminals: Literature overview,trends, and research directions

Inbound and outbound containers are temporarily stored in the storage yard at container terminals. A combination of container demand increase and storage yard capacity scarcity create complex operational challenges for storage yard managers. This paper presents an in-depth overview of storage yard operations, including the material handling equipment used, and highlights current industry trends and developments. A classification scheme for storage yard operations is proposed and used to classify scientific journal papers published between 2004 and 2012. The paper also discusses and challenges the current operational paradigms on storage yard operations. Lastly, the paper identifies new avenues for academic research based on current trends and developments in the container terminal industry.     

Transport operations in container terminals: Literature overview,trends, research directions and classification scheme

Internal transport operations connect the seaside, yard side, and landside processes at container terminals. This paper presents an in-depth overview of transport operations and the material handling equipment used, highlights current industry trends and developments, and proposes a new classification scheme for transport operations and scientific journal papers published up to 2012. The paper also discusses and challenges current operational paradigms of transport operations. Lastly, the paper identifies new avenues for academic research based on current trends and developments in the container terminal industry.     

Concerted and stepwise proton-coupled electron transfers in aquo/hydroxo complex couples in water: oxidative electrochemistry of [Os(II)(bpy)(2)(py)(OH(2))](2+)

Successive oxidation of transition metal(II) aqua complexes (M(II)OH(2) to M(III)OH) is a domain in which proton-coupled electron transfer reactions are extremely common. The mechanism of these PCET reactions-concerted or stepwise-is an important issue in the understanding and design of natural or artificial systems catalyzing the formation of dioxygen by four-electron oxidation of water. Concerted proton-coupled electron transfer from an aqua metal(II) to a hydroxo metal(III) complex requires the close proximity of a proton-accepting group with a pK value between those of the aqua complexes. Otherwise, stepwise electron-proton or proton-electron pathways involving high-energy intermediates are followed. Concerted proton-electron pathways involving water as proton-acceptor or proton-donor group are inefficient. Cyclic voltammetry of the title complex in buffered aqueous solution and re-examination of previous results for the same complex attached to an electrode surface are used to establish these conclusions, which provide a starting point on the route to higher degrees of oxidation, such as those involved in the catalysis of water oxidation.     

Lost-sales inventory systems with a service level criterion

Competitive retail environments are characterized by service levels and lost sales in case of excess demand. We contribute to research on lost-sales models with a service level criterion in multiple ways. First, we study the optimal replenishment policy for this type of inventory system as well as base-stock policies and (R, s, S) policies. Furthermore, we derive lower and upper bounds on the order-up-to level, and we propose efficient approximation procedures to determine the order-up-to level. The procedures find values of the inventory control variables that are close to the best (R, s, S) policy and comply to the service level restriction for most of the instances, with an average cost increase of 2.3% and 1.2% for the case without and with fixed order costs, respectively.     

In Situ Spectroscopy of Calcium Fluoride Anchored Metal–Organic Framework Thin Films during Gas Sorption

Surface-mounted metal–organic frameworks (SURMOFs) show promising behavior for a manifold of applications. As MOF thin films are often unsuitable for conventional characterization techniques, understanding their advantageous properties over their bulk counterparts presents a great analytical challenge. In this work, we demonstrate that MOFs can be grown on calcium fluoride (CaF₂) windows after proper functionalization. As CaF₂ is optically (in the IR and UV/Vis range of the spectrum) transparent, this makes it possible to study SURMOFs using conventional spectroscopic tools typically used during catalysis or gas sorption. Hence, we have measured HKUST-1 during the adsorption of CO and NO. We show that no copper oxide impurities are observed and also confirm that SURMOFs grown by a layer-by-layer (LbL) approach possess Cu⁺ species in paddlewheel confirmation, but 1.9 times less than in bulk HKUST-1. The developed methodology paves the way for studying the interaction of any adsorbed gases with thin films, not limited to MOFs, low temperatures, or these specific probe molecules, pushing the boundaries of our current understanding of functional porous materials.     

The numerical integration of relative equilibrium solutions. The nonlinear Schrodinger equation

We analyse different error propagation mechanisms for conservativeand nonconservative time-integrators of nonlinear Schrödingerequations. We use a geometric approach based on interpretingwaves as relative equilibria.     

Time-restricted batching models and solution approaches for integrated forward and return product flow handling in warehouses

With the rise of Internet sales, retailers witness increases in returned products, generally because website pictures and specifications tend to be insufficient for customers to determine the right size, colour or suitability of a product. Efficient processing of the return flow can improve inventory management and increase the utilisation of warehouse capacities. Moreover, short response times to customer orders and on-time delivery are critical and shape warehouse operations. To address the problem of integrated order and return job batching, this article proposes two optimisation models with constraints on the delivery time. We propose different objectives in offline and online contexts which require unique solution approaches. Time constraints also need to be taken into account to exploit the different characteristics of order and return jobs, as well as to incorporate response time-oriented objectives. Computational examples confirm the effectiveness of included returns and the impact of consumer-oriented objectives. Finally, a comparison of the proposed solution approaches with batching procedures used by a library warehouse indicates significant savings in travel distance through integrated order and return job processing.     

Phase stability of colloidal spheres mixed with supramolecular rod-like polymers

Mixtures of colloids and supramolecular polymers exhibit stimuli-responsive phase behavior. In previous work (Peters and Tuinier, Physica A 510, 233 [2018]) the polymers were treated as fully flexible chains, while in experimental systems supramolecular polymers may have a certain degree of stiffness. Here we predict that for stiff rod-like supramolecular polymers phase separation can occur at much lower polymer concentrations than for flexible supramolecular polymers. Additionally, it is demonstrated that colloid–polymer interactions can significantly influence the equilibrium polymer size distribution, however this does not strongly affect the phase behavior of the mixture. At the low polymer concentrations at which the system already gets unstable, the effect of excluded volume interactions between polymers chains themselves is small. Finally, for an experimental system it is predicted that a variety of re-entrant phase transitions may be observed within a realistic temperature range as illustrated by a specific example.     

Integral resource capacity planning for inpatient care services based on bed census predictions by hour

The design and operations of inpatient care facilities are typically largely historically shaped. A better match with the changing environment is often possible, and even inevitable due to the pressure on hospital budgets. Effectively organizing inpatient care requires simultaneous consideration of several interrelated planning issues. Also, coordination with upstream departments like the operating theatre and the emergency department is much-needed. We present a generic analytical approach to predict bed census on nursing wards by hour, as a function of the Master Surgical Schedule and arrival patterns of emergency patients. Along these predictions, insight is gained on the impact of strategic (ie, case mix, care unit size, care unit partitioning), tactical (ie, allocation of operating room time, misplacement rules), and operational decisions (ie, time of admission/discharge). The method is used in the Academic Medical Center Amsterdam as a decision-support tool in a complete redesign of the inpatient care operations.