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排序方式: 共有56条查询结果,搜索用时 46 毫秒
41.
Mihucz VG Tatár E Virág I Cseh E Fodor F Záray G 《Analytical and bioanalytical chemistry》2005,383(3):461-466
Flow injection analysis (FIA) and high-performance liquid chromatography double-focusing sector field inductively coupled
plasma mass spectrometry (HPLC-DF-ICP-MS) were used for total arsenic determination and arsenic speciation of xylem sap of
cucumber plants (Cucumis sativus L.) grown in hydroponics containing 2 μmol dm−3 arsenate or arsenite, respectively. Arsenite [As(III)], arsenate [As(V)] and dimethylarsinic acid (DMA) were identified in
the sap of the plants. Arsenite was the predominant arsenic species in the xylem saps regardless of the type of arsenic treatment,
and the following concentration order was determined: As(III) > As(V) > DMA. The amount of total As, calculated taking into
consideration the mass of xylem sap collected, was almost equal for both treatments. Arsenite was taken up more easily by
cucumber than arsenate. Partial oxidation of arsenite to arsenate (<10% in 48 h) was observed in the case of arsenite-containing
nutrient solutions, which may explain the detection of arsenate in the saps of plants treated with arsenite. 相似文献
42.
Rita?Patakfalvi Zsanett?Virányi Imre?DékányEmail author 《Colloid and polymer science》2004,283(3):299-305
Silver nanoparticles were prepared in aqueous AgNO3 solution by using hydroquinone and sodium citrate as reducing agents with neutral polymers poly(vinylpyrrolidone) and poly(vinyl alcohol) as stabilizers. The rate of particle formation was determined with a diode array UV-Vis spectrophotometer. The effects of the polymer concentration on the reaction rate, the size, and the size distribution of the particles formed were studied by transmission electron microscopy. Both the reaction rate and the size of silver nanoparticles decreased with increasing polymer concentration in the range 0.07–0.50 w/v%. 相似文献
43.
The development and characterization of a highly sensitive enzyme immobilized carbon based electrode for the determination of subnanomolar concentrations of hydrogen peroxide in aqueous samples is described. The biosensor consists of horseradish peroxidase (HRP) immobilized in solid carbon paste along with a suitable redox mediator. The latter allows the acceleration of the electroreduction of HRP in the presence of hydrogen peroxide. Several phenothiazines as mediators are investigated in a comparative manner and with respect to dimethylferrocene using cyclic voltammetry and amperometry. Insolubilization of the HRP in the solid carbon paste is achieved by cross-linking the enzyme with glutaraldehyde and bovine serum albumin. Several experimental parameters such as pH, mediator and enzyme content are considered. The hydrogen peroxide determination is better carried out in 0.1 M acetate buffer, pH 4.5, by amperometry at an applied potential of 0.0 V versus Ag/AgCl, 3 M NaCl concentration and by using the phenothiazine base as redox mediator. The biosensor response is linear over the concentration range 2 nM-10 microM with a detection limit of 1 nM. The linear range of the hydrogen peroxide response without a mediator in the biosensor is found between 2 and 40 microM. The biosensor can be used for more than 180 measurements. Additional modification of the electrode by incorporation of Nafion SAC-13 microparticles in the solid carbon paste allows detection of concentrations of hydrogen peroxide as low as 0.1 nM. 相似文献
44.
B. Virág 《Geometric And Functional Analysis》2000,10(6):1588-1605
This paper studies anchored expansion, a non-uniform version of the strong isoperimetric inequality. We show that every graph
with i-anchored expansion contains a subgraph with isoperimetric (Cheeger) constant at least i. We prove a conjecture by Benjamini, Lyons and Schramm (1999) that in such graphs the random walk escapes with a positive
lim inf speed. We also show that anchored expansion implies a heat-kernel decay bound of order exp(—cn
1/3).
Submitted: September 1999, Revision: January 2000. 相似文献
45.
Flow, Turbulence and Combustion - Data-driven Reynolds-averaged Navier–Stokes (RANS) turbulence closures are increasing seen as a viable alternative to general-purpose RANS closures, when LES... 相似文献
46.
Fe-doped TiO2, Ti1–xFexO2 (x = 0.00, 0.02, 0.04, 0.06, 0.08, and 0.10), photocatalysts have been successfully synthesized via citric acid–assisted autocombustion method. The synthesized photocatalysts were characterized using different characterization techniques, such as X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), Fourier transform infrared (FT-IR), transmission electron microscopy (TEM), energy dispersive x-ray spectroscopy (EDX), and x-ray photoelectron spectroscopy (XPS). The XRD diffraction patterns revealed that synthesized photocatalysts have the anatase phase of TiO2. The DRS analysis indicates a slight increment in absorbance in the visible light region by the Fe doping in TiO2. The FT-IR spectra reveal the various stretching and bending vibrational bands of the Ti–O lattice. The XPS spectra confirm the presence of elements titanium, oxygen, and iron in the synthesized samples and determine binding energy of elements. TEM analysis shows the shape of the synthesized photocatalyst, and it was used to calculate the average particle sizes of undoped and Fe-doped TiO2 (Ti0.96Fe0.04O2) photocatalysts using a histogram. The photocatalytic activities of synthesized photocatalysts were determined by photodegradation of dye (Direct Blue 199), contaminating carpet industry wastewater in the photochemical reactor and open pan reactor. The maximum photodegradation activity was shown by the Ti0.96Fe0.04O2 photocatalyst among all the synthesized undoped and Fe-doped photocatalysts. The synthesized photocatalyst (Ti0.96Fe0.04O2) had better photocatalytic activity when compared to both, undoped TiO2 and Aeroxide (Degussa) P-25. The used Fe-doped TiO2 photocatalyst (Ti0.96Fe0.04O2) was regenerated five times and investigated for its photocatalytic activity. 相似文献
47.
Kuzmann E. Virág I. Pöppl L. Havancsák K. Klencsár Z. Novochatskii I. A. Garg V. K. de Oliveira A. C. Vértes A. 《Hyperfine Interactions》2002,139(1-4):561-568
Rapidly quenched Fe–Cr–P–C amorphous alloys irradiated with 209 MeV energy 84Kr ions were investigated by Mössbauer spectroscopy, X-ray diffraction, and differential scanning calorimetry measurements. Significant changes were found between Mössbauer spectra of the irradiated and non-irradiated amorphous alloys. The changes were analysed by the hyperfine field distribution method, too. The crystallisation temperature as well as the phase composition at a certain stage of crystallisation were found to be different in the non-irradiated and irradiated samples. These results reflect the changes in the short-range ordering due to the irradiation with energetic heavy ions. 相似文献
48.
49.
Ionization probabilities of the LI and LIII subshells have been calculated for 82Pb by the impact of protons with in the frame work of binary encounter approximation (BEA) theory. The results obtained have been compared with the probabilities based on semi-classical approximation (SCA) theory. 相似文献
50.