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81.
In this study, the reaction of semiconductor microrods of phase I copper 7,7,8,8-tetracyanoquinodimethane (CuTCNQ) with KAuBr(4) in acetonitrile is reported. It was found that the reaction is redox in nature and proceeds via a galvanic replacement mechanism in which the surface of CuTCNQ is replaced with metallic gold nanoparticles. Given the slight solubility of CuTCNQ in acetonitrile, two competing reactions, namely CuTCNQ dissolution and the redox reaction with KAuBr(4), were found to operate in parallel. An increase in the surface coverage of CuTCNQ microrods with gold nanoparticles occurred with an increased KAuBr(4) concentration in acetonitrile, which also inhibited CuTCNQ dissolution. The reaction progress with time was monitored using UV-visible, FT-IR, and Raman spectroscopy as well as XRD and EDX analysis, and SEM imaging. The CuTCNQ/Au nanocomposites were investigated for their photocatalytic properties, wherein the destruction of Congo red, an organic dye, by simulated solar light was found dependent on the surface coverage of gold nanoparticles on the CuTCNQ microrods. This method of decorating CuTCNQ may open the possibility of modifying this and other metal-TCNQ charge transfer complexes with a host of other metals which may have significant applications. 相似文献
82.
Vipul P. Rane Kiran R. Patil Jaiprakash N. Sangshetti Devanand B. Shinde 《Chromatographia》2008,67(9-10):777-781
A simple, rapid, and robust chiral HPLC method has been developed and validated for separation of the enantiomers of epinephrine, l-1-(3,4-dihydroxyphenyl)-2-(methylamino)ethanol, an antihypertensive drug, in the bulk drug. The enantiomers were resolved on an amylose-based stationary phase with n-hexane–2-propanol–methanol–trifluoroacetic acid–diethylamine 90:05:05:0.2:0.2 (v/v) as mobile phase at a flow rate of 1.0 mL min?1. In the optimized method resolution between the enantiomers was not less than 3.0. The trifluoroacetic acid and diethylamine in the mobile phase were important for enhancing chromatographic efficiency and hence the resolution of the enantiomers. The method was extensively validated and proved to be robust. The calibration plot for the d enantiomer was highly linear over the concentration range 100–2,000 μg mL?1. The limits of detection and quantification for the d enantiomer were 0.15 and 0.45 μg mL?1, respectively. Recovery of the d enantiomer from bulk drug samples of epinephrine ranged between 99.5 and 101.5%. Epinephrine sample solution was stable for up to 48 h. The method was suitable for accurate quantitative determination of the d enantiomer in the bulk drug substance 相似文献
83.
Soni SK Selvakannan PR Bhargava SK Bansal V 《Langmuir : the ACS journal of surfaces and colloids》2012,28(28):10389-10397
We report the biomacromolecular self-assembly of histidine acid phosphatase (HAP), an enzyme of significant biomedical and industrial importance, in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF(4)]). The spontaneous self-assembly of HAP enzyme in [BMIM][BF(4)] results in the formation of HAP nanocapsules. The HAP enzyme molecules were found to retain their enzymatic activity after the self-assembly process, which enabled us to utilize self-assembled HAP capsules as self-catalyzing templates for the synthesis of a range of hollow metal nanoparticles (Au, Ag, Pd, and Ni) without employing any additional reducing agent. The hollow metal nanospheres with HAP encapsulated within their cavity were found to retain enzymatic activity for at least up to four cycles, as demonstrated in the case of Au-coated HAP capsules as the model system. 相似文献
84.
Bansal V Poddar P Ahmad A Sastry M 《Journal of the American Chemical Society》2006,128(36):11958-11963
The syntheses of inorganic materials by biological systems is characterized by processes that occur close to ambient temperatures, pressures, and neutral pH, as is exemplified by biosilicification and biomineralization processes in nature. Conversely, laboratory-based syntheses of oxide materials often require extremes of temperature and pressure. We have shown here the extracellular, room-temperature biosynthesis of 4-5 nm ternary oxide nanoparticles such as barium titanate (BT) using a fungus-mediated approach. The tetragonality as well as a lowered Curie transition temperature in sub-10 nm particles was established, and the ferroelectricity in these particles was shown using Kelvin probe microscopy. 相似文献
85.
Sanjay Bhajanker Vipul Srivastava Sankar P. Sanyal 《Physica B: Condensed Matter》2012,407(13):2376-2381
The high pressure structural, elastic and thermal properties of holmium pnictides HoX (X=N, P, As and Bi) were investigated theoretically by using an inter-ionic potential theory with modified ionic charge parameter. We have predicted a structural phase transition from NaCl (B1) to CsCl (B2)-type structure at pressure of 139 GPa for HoN, 52 GPa for HoP, 44 GPa for HoAs and 26 GPa for HoBi. Other properties, such as lattice constant, bulk modulus, cohesive energy, second and third-order elastic constants were calculated and compared with the available experimental and theoretical data. In order to gain further information the brittle behaviour of these compounds was observed. Some other properties like Shear modulus (G), Young's modulus (E), Poisson's ratio (ν), anisotropy factor (A), sound velocities, Debye temperature (θD) were calculated. The variation of elastic constants (C11 and C44) and Debye temperature (θD) with pressure was also presented. 相似文献
86.
We present a design of a dual-core leaky waveguide that can be used as an integrated-optic polarizer. The proposed polarizer works on the principle of mode filtering. The structure is characterized by two cores, namely core-1 and core-2 and a high index layer in the upper-most region, such a structure supports leaky modes. The leakage losses of the modes have been calculated by using the transfer matrix method (TMM). Single polarization operation is ensured by high differential leakage loss between fundamental TE and TM modes. We show TE-pass operation with 0.5 dB/mm loss in TE0 mode and 13 dB/mm loss in TM0 mode, and TM-pass operation with 0.36 dB/mm loss in TM0 mode and 7.45 dB/mm loss in TE0 mode. Besides single-polarization operation, single-mode operation of the structure is ensured by high leakage loss of all the other higher-order modes. 相似文献
87.