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111.
Supercritical fluid extraction of oxindole alkaloids from Uncaria Tormentosa is described. The extraction was performed with supercritical carbon dioxide alone and with supercritical carbon dioxide modified with 10% metanol, and the extracts were analyzed by GC/MS and HPLC/MS. 相似文献
112.
Internal conversion coefficients for inner shells of atomic ions of Sn are calculated for various degrees of ionization and compared with neutral atom predictions. The relativistic version of an analytic perturbation theory is used to include screening effects. 相似文献
113.
An exact analytic evaluation of the Kramers-Heisenberg matrix elements for Rayleigh scattering fromn=3 states of hydrogenlike atoms is performed in the nonrelativistic dipole approximation, using the Green's function method. The results are given separately for each subshell. The possibility of 3s?3d transitions is also considered. The dependence on the photon energy is contained in six invariant amplitudes. The formulas needed for the evaluation of the various cross sections are presented. The numerical results are contained in tables from which partial and total cross sections can be easily built, covering the energy range from zero up to 20 times theK threshold energy. In the vicinity of Balmerα frequency the cross section is large and comparable with that for excitedn=2 states, confirming an earlier hypothesis of Röhr. At other energies the cross sections forn=2 andn=3 states are comparable, too. The results should be useful in plasma diagnostics. 相似文献
114.
The reaction of o-hydroxybenzylideneamine and malonyl dichloride produces coumarin-3-carboxanilide. 相似文献
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Alenka Možir Matija Strlič Tanja Trafela Irena Kralj Cigić Jana Kolar Viorica Deselnicu Gerrit de Bruin 《Applied Physics A: Materials Science & Processing》2011,104(1):211-217
Historic parchment is an extremely complex material, not only due to the various methods of production used and various past environmental histories of objects, but also due to its inhomogeneous structure. Many traditional methods of characterisation are empirical, but useful since they have gained recognition by the end-users. In this paper, we investigated the shrinkage temperature of collagen and the influence of lipids contained in parchment on the measurements. While the content of lipids does not seem to significantly affect shrinkage temperature measurements themselves, it strongly affects the decrease of shrinkage temperature of collagen during degradation, and thus its thermomechanical properties. This confirms the high importance of lipid peroxidation during degradation of parchment. 相似文献
119.
Rodica Buhaceanu Ioan Sarghie Adriana Barsanescu Viorica Dulman Ioan Bunia 《Central European Journal of Chemistry》2009,7(4):827-835
The sorption capacity of three weak base ion exchangers based on acrylic copolymers functionalized with ethylenediamine, triethylenetetramine
and N, N- dimethylamino propylamine for Ag(I) ions was evaluated. Adsorption experiments were carried out by batch method.
The effect of pH, crosslinking degree of copolymers, amount of sorbent, initial ion concentration, contact time and temperature
was studied. The parameters which characterize the retention process were estimated using Langmuir and Freundlich isotherm
models, the best fitting being for the first model. Kinetic data were fitted to pseudo-first order, pseudo-second order and
intraparticle diffusion models. Experimental data were in good agreement with the pseudo second order.
相似文献
120.
On-line microwave-induced helium plasma atomic emission detection for capillary zone electrophoresis
We report a feasibility study on using a microwave-induced helium plasma atomic emission detector (MIP-AED) as an on-line detector in capillary zone electrophoresis (CZE). To couple CZE to MIP-AED, we used an ion exchange membrane capillary to connect the separation capillary to the interfacing capillary. The outlet end of the interfacing capillary was placed directly in the discharge tube of the MIP-AED system. The electroosmotic flow generated in the separation capillary carried the analytes and the electrolyte buffer solution through the interfacing capillary into the MIP-AED discharge tube where the analytes were detected. The performance of the CZE/MIP-AED system was evaluated with trimethyltin chloride, dimethyltin dichloride, n-propanol, and 2-butanone. The preliminary results indicate that the MIP-AED can be used in CZE to provide element-specific detection for target analytes. 相似文献