排序方式: 共有52条查询结果,搜索用时 31 毫秒
21.
Vineet Sharma Vinita Sharma Rakesh Bohra John E. Drake Michael B. Hursthouse Mark E. Light Ann L. Bingham 《Transition Metal Chemistry》2007,32(4):442-448
New heteroleptic oxovanadium(V) chloro oximato complexes of the type [VO{Cl}3-n
{ON=C(CH3)(Ar)}
n
] (where Ar = C4H3O-2, C4H3S-2, C5H4N-2 and n = 1 or 2) have been synthesized in excellent yields by the reaction of VOCl3 with the sodium salts of corresponding internally functionallized oximes in refluxing anhydrous benzene. The complexes are
characterized by elemental analyses and spectroscopic techniques (FT-IR, 1H-, 13C{1H}- and 51V-NMR). FAB mass spectral analysis of one of the derivatives, [VOCl{ON=C(CH3)C4H3S}2] indicates the monomeric nature of the complex. 51V-NMR spectral studies of these complexes suggest tetra-coordination around the vanadium atom in solution. However, the single
crystal X-ray diffraction study of a redistribution product [VOCl{ON=C(CH3)(C4H3S-2)}2] · CH3OH obtained on recrystallization of [VOCl2{ON=C(CH3)(C4H3S-2)}] from a methanol-hexane mixture shows the vanadium(V) atom is hepta-coordinated with distorted pentagonal bipyramidal
geometry. The oxo-atom occupies the axial position while the weakly coordinated CH3OH group is trans to the V=O atom. The two oximato ligands in the approximate pentagonal plane are bonded to the central vanadium atom in dihapto
(η2-N, O) manner with the formation of three-membered rings. The V–Cl bond occupies the fifth position in the approximate plane. 相似文献
22.
Pinaki S. Bhadury Vinita Dubey Sapna Singh Chhaya Saxena 《Journal of fluorine chemistry》2005,126(8):1252-1256
A simpler technique for the synthesis of 2,2-bis(4-allyoxyphenyl)hexafluoropropane has been achieved from 4,4′-(hexafluoroisopropylidene)diphenol for obtaining 2,2-bis(3-allyl-4-hydroxyphenyl)hexafluoropropane. This monomer and its corresponding hybrid organic/inorganic siloxane polymer are successfully used as a coating material for the detection of toxic chemical warfare agents. 相似文献
23.
Mixed metal oxides of tin with strontium (xSnO2.SrO) in different molar ratio {where x?=?1 (1), 2 (2), 4(3); SnO2 doped with Sr+2(4), SnO2 doped with Sr+2 and co-doped with F?(5)} have been prepared by sol–gel technology in basic medium using SnCl2.2H2O as precursor in isopropanol as solvent. Structural analysis by XRD patterns have shown formation of particles at nanoscale and phase separation of SnO2 in tetragonal rutile framework in these mixed metal oxides. This fact was further supported by TEM. SEM images of all these samples have shown formation of various geometrical patterns ranging from spherical particles to nanorods. In the IR spectra of all these oxides, Sr–O absorption bands were present only in sample (1). UV–Vis spectroscopy has shown reduction in optical band gap in mixed metal oxides and the lowest value of band gap was observed for sample (3). Photoluminescence spectra of all these derivatives are found to be almost similar again indicated retention of tetragonal rutile SnO2 framework. I–V curves of all these oxides are non-linear and lowest resistance was observed for sample (3). This fact was further supported by impedance measurements. 相似文献
24.
25.
Michael J. Minkler Jr Jung Min Kim Vinita V. Shinde Bryan S. Beckingham 《Magnetic resonance in chemistry : MRC》2020,58(12):1168-1176
Low-cost, high-accuracy characterization of polymeric materials is critical for satisfying societal demand for high-quality materials with ultra-specific requirements. Low-field nuclear magnetic resonance (NMR) spectroscopy presents an opportunity to replace costlier or destructive methods while utilizing nondeuterated solvents. Many factors play key roles in the ability of low-field NMR spectroscopy to accurately analyze polymer systems. Sample characteristics such as polymer concentration, composition, and molecular weight all directly affect the capability of low-field spectrometers to accurately determine polymer microstructure compositions. In addition to inherent sample properties affecting instrumental accuracy, many choices concerning instrumental parameters (including number of scans, relaxation delay, spectral width, and points per scan) must be made that impact the quality of the resulting NMR spectra. In this work, we benchmark the capability of a 60-MHz low-field NMR spectrometer for analyzing polymer materials using mixed microstructure polyisoprenes as a model polymer system of interest. The aforementioned critical sample and instrumental variables are varied, and we report on the ability to quantitatively characterize polyisoprene microstructure to within 1–2% of a higher field NMR spectrometer (400 MHz). We anticipate our findings to be generally applicable to other low-field spectrometers of similar field strength and other polymer systems. 相似文献
26.
In this article, similarity reductions of the (2 1)-dimensional Bogoyavlenskii-Schieff equation of higher order have been done by Lie group method. We have determine the geometric vector field, infinitesimal generators, symmetric groups, and commutator table of Lie algebra with the help of Lie symmetry analysis. The new close form solutions and similarity solutions of the (2 1)-dimensional Bogoyavlenskii-Schieff equation of higher order have been determined from the reduction equations. Also, the conservation laws have been derived by invoking the new conservation theorem proposed by Ibragimov. 相似文献
27.
Bernard AS Giroud C Ching HY Meunier A Ambike V Amatore C Collignon MG Lemaître F Policar C 《Dalton transactions (Cambridge, England : 2003)》2012,41(21):6399-6403
SOD-mimics are small complexes that reproduce the activity of superoxide dismutases, natural proteins that catalytically dismutate the superoxide anion. Activated macrophages, which produce ROS and RNS fluxes, constitute a relevant model to challenge antioxidant activity in a cellular context and were used to test a Mn-complex which was shown to efficiently alter the flow of O(2)(-), ONOO(-) and H(2)O(2). 相似文献
28.
A facile synthesis of S-(2-thioxo-1,3-dithiolan-4-yl)methyl dialkylcarbamothioates (3) and S-thiiran-2-ylmethyl dialkylcarbamothioate (5) has been reported by the reaction of 5-(chloromethyl)-1,3-oxathiolane-2-thione (1) with sodium dialkylcarbamodithioate (2) and dialkylamine (4), respectively, through intermolecular O-S rearrangement in water. A plausible mechanism of formation of the title compounds has also been proposed. 相似文献
29.
Patel Puja Nadar Manimaran Vinita Umapathy Devan Antony Joseph Velangani Pappu Srinivasan Rathinam Yuvakkumar Pitchan Arul Prakash Ponnuchamy Kumar 《应用有机金属化学》2020,34(9):e5740
In recent years, capping molecules onto the surface of nanomaterials has become an interesting field of research. This idea facilitates the biological applications of nanomaterials with a modified surface. Keeping this in mind, the present study addresses the development of polymeric platinum nanoparticles using polyvinyl pyrrolidone (PVP). High-throughput characterization indicates that polymeric platinum nanoparticles have an excellent surface morphology and good dispersity in aqueous solution. More specifically, high resolution-transmission electron microscopy studies showed that the polymeric platinum nanoparticles were spherical and measured 2–10 nm. Furthermore, the polymeric platinum nanoparticles were evaluated for anticancer properties against human MCF-7 breast cancer cell lines. The results show that polymeric platinum nanoparticles inhibited the growth of cancer cells in a dose-dependent manner with a half-maximum inhibitory concentration of 96.36 μg ml−1. In addition, fluorescence-based staining methods confirmed an inquest in the pattern of cell death inferring late apoptotic bodies, nuclear fragmentation, mitochondrial membrane potential and generation of reactive oxygen species. The overall findings suggest that the polymeric platinum nanoparticles confer anticancer activity and may be suitable chemotherapeutic agents in the future. Finally, the results from this study can be extended to other types of cancer as well. 相似文献
30.