Tensor products of n-complete algebras

If A and B are n- and m-representation finite k-algebras, then their tensor product $\mathrm{\Lambda }=A{?}_{k}B$ is not in general $(n+m)$-representation finite. However, we prove that if A and B are acyclic and satisfy the weaker assumption of n- and m-completeness, then Λ is $(n+m)$-complete. This mirrors the fact that taking higher Auslander algebra does not preserve d-representation finiteness in general, but it does preserve d-completeness. As a corollary, we get the necessary condition for Λ to be $(n+m)$-representation finite which was found by Herschend and Iyama by using a certain twisted fractionally Calabi–Yau property.     

Effect of charge distribution on the translocation of an inhomogeneously charged polymer through a nanopore

We investigate the voltage-driven translocation of an inhomogeneously charged polymer through a nanopore by utilizing discrete and continuous stochastic models. As a simplified illustration of the effect of charge distribution on translocation, we consider the translocation of a polymer with a single charged site in the presence and absence of interactions between the charge and the pore. We find that the position of the charge that minimizes the translocation time in the absence of pore-polymer interactions is determined by the entropic cost of translocation, with the optimum charge position being at the midpoint of the chain for a rodlike polymer and close to the leading chain end for an ideal chain. The presence of attractive and repulsive pore-charge interactions yields a shift in the optimum charge position toward the trailing end and the leading end of the chain, respectively. Moreover, our results show that strong attractive or repulsive interactions between the charge and the pore lengthen the translocation time relative to translocation through an inert pore. We generalize our results to accommodate the presence of multiple charged sites on the polymer. Our results provide insight into the effect of charge inhomogeneity on protein translocation through biological membranes.     

Fluctuation-induced interactions between dielectrics in general geometries

We study thermal Casimir and quantum nonretarded Lifshitz interactions between dielectrics in general geometries. We map the calculation of the classical partition function onto a determinant, which we discretize and evaluate with the help of Cholesky factorization. The quantum partition function is treated by path integral quantization of a set of interacting dipoles and reduces to a product of determinants. We compare the approximations of pairwise additivity and proximity force with our numerical methods. We propose a "factorization approximation" that gives rather good numerical results in the geometries that we study.     

Isotropic-nematic phase transition of single-walled carbon nanotubes in strong acids

We present the first quantitative assessment of the maximum amount of nanotubes that can exist in the isotropic phase () of single-walled carbon nanotubes (SWNTs) in Br?nsted-Lowry acids. We employ a centrifugation technique in conjunction with UV-vis-nIR spectroscopy to quantify , which is also the critical concentration of the isotropic-nematic transition of SWNTs in strong acids. Centrifugation of biphasic dispersions of SWNTs, that is, acid dispersions consisting of an isotropic phase in equilibrium with an ordered nematic liquid crystalline phase, results in a clear phase separation, where the isotropic phase is supernatant. Dilution of the isotropic phase with a known amount of acid followed by UV-vis-nIR absorbance measurements yields , that is, the maximum concentration of SWNTs that can exist in the isotropic phase in a given acid for a given SWNTs' length distribution. At low SWNT concentration (below 200 ppm) in superacids, light absorbance in the range from 400 to 1400 nm scales linearly with concentration. This Beer's law behavior yields calibration curves for measuring SWNTs' concentration in acids. We find that the critical concentration of the isotropic-nematic transition increases with acid strength in accordance with the previously proposed sidewall protonation mechanism for dispersing SWNTs in acids.     

Mapping a homopolymer onto a model fluid

We describe a linear homopolymer using a grand canonical ensemble formalism, a statistical representation that is very convenient for formal manipulations. We investigate the properties of a system where only next neighbor interactions and an external, confining, field are present and then show how a general pair interaction can be introduced perturbatively, making use of a Mayer expansion. Through a diagrammatic analysis, we shall show how constitutive equations derived for the polymeric system are equivalent to the Ornstein-Zernike and Percus-Yevick equations for a simple fluid and find the implications of such a mapping for the simple situation of Van der Waals mean field model for the fluid.     

The Fermi–Pasta–Ulam Problem and Its Underlying Integrable Dynamics: An Approach Through Lyapunov Exponents

FPU models, in dimension one, are perturbations either of the linear model or of the Toda model; perturbations of the linear model include the usual \(\beta \)-model, perturbations of Toda include the usual \(\alpha +\beta \) model. In this paper we explore and compare two families, or hierarchies, of FPU models, closer and closer to either the linear or the Toda model, by computing numerically, for each model, the maximal Lyapunov exponent \(\chi \). More precisely, we consider statistically typical trajectories and study the asymptotics of \(\chi \) for large N (the number of particles) and small \(\varepsilon \) (the specific energy E / N), and find, for all models, asymptotic power laws \(\chi \simeq C\varepsilon ^a\), C and a depending on the model. The asymptotics turns out to be, in general, rather slow, and producing accurate results requires a great computational effort. We also revisit and extend the analytic computation of \(\chi \) introduced by Casetti, Livi and Pettini, originally formulated for the \(\beta \)-model. With great evidence the theory extends successfully to all models of the linear hierarchy, but not to models close to Toda.     

Elementary scales and the lack of Fourier paradox for Fourier fluids

Focusing on the Fourier fluids in the liquid state, which are characterized by linear thermal constitutive equation and low compressibility, this short note proposes a discrete approach based on the elementary scales, which allows removing the so-called Fourier paradox in classical continuum thermomechanics. As a corollary, the adopted line of reasoning allows highlighting some features on the elementary scales.

     

Incorporation of a lipophilic series,as coenzyme Q Homologs,din phospholipid vesicles

The incorporation of Coenzyme Q† homologs into phospholipid vesicles to achieve a concentration close to the quinone content of mitochondria has been studied with different methods. The results obtained can be summarized as follows: (a) stirring does not lead to comparable incorporation of the various CoQs tested; (b) ultrasonic irradiation results in a homogeneous incorporation both of the naturally occurring homologs of Coenzyme Q (polyisoprenoid chainlength ranging from ten to six units) and of the nonphysiological shorter chain homologs; (c) ethanol injection, which is a simple, rapid, and inexpensive technique, gives results comparable to those obtained by ultrasonication.