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141.
The reaction of [RuHCl(CO)(PPh3)3] with 4-phenylpyrimidine gave a new ruthenium(II) complex, namely [RuHCl(CO)(PPh3)2(pyrim-4-Ph)]. The complex has been studied by IR and UV?Cvis spectroscopy and by X-ray crystallography. The molecular orbitals of the complex have been calculated by density functional theory. The spin-allowed singlet?Csinglet electronic transitions of the complex have been calculated by time-dependent DFT, and the UV?Cvis spectrum of the compound has been discussed on this basis. The emission properties of the complex were also studied. 相似文献
142.
Non-uniform distribution of moisture contents inside of the porous materials during drying results in compressional stresses inside of the material and tensional ones close to the surface. The tensional stresses together with brittleness of dry material are the reasons of fracturing of the material. The proposed model consists of two parts. The mass transfer is described by simple diffusion equation. The mechanical behaviour of the material is modelled with the network model in which the material is modelled as the set of small particles interconnected elastically via springs. The spring constants and strengths depend on Young modulus and the material tensional strength. The dependences of these material parameters on the moisture content are determined. Then two 2D initial-boundary problems are solved. The results show possible way of cracks initiation and generation by drying. 相似文献
143.
This paper presents a special use of the linear poroelasticity theory to describe tidally induced groundwater oscillations. Two models of oscillation inducing mechanism make use of this theory to predict groundwater level fluctuations. The numerical solutions of both models are presented and compared with well water level measurement obtained in Police Basin, north-east Bohemia. 相似文献
144.
Quentin Araud Pascal Finaud‐Guyot Vincent Guinot Robert Mosé José Vazquez 《国际流体数值方法杂志》2012,70(12):1590-1604
Discontinuous Galerkin (DG) methods have shown promising results for solving the two‐dimensional shallow water equations. In this paper, the classical Runge–Kutta (RK) time discretisation is replaced by the eigenvector‐based reconstruction (EVR) that allows the second‐order time accuracy to be achieved within a single time‐stepping procedure. Moreover, the EVRDG approach yields stable solutions near drying and wetting fronts, whereas the classical RKDG approach yields instabilities. The proposed EVRDG technique is compared with the original RKDG approach on various test cases with analytical solutions. The EVRDG solutions are shown to be as accurate as those obtained with the RKDG scheme. Besides, the EVRDG scheme is 1.6 times faster than the RKDG method. Simulating dambreaks involving dry beds confirms that EVRDG scheme gives correct solutions, whereas the RKDG method yields instabilities. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
145.
Jakob Woisetschl?ger Adam D. Wexler Gert Holler Mathias Eisenhut Karl Gatterer Elmar C. Fuchs 《Experiments in fluids》2012,52(1):193-205
When a high-voltage direct-current is applied to two beakers filled with polar liquid dielectrica like water or methanol, a horizontal bridge forms between the two beakers. By repeating a version of Pellat’s experiment, it is shown that a horizontal bridge is stable by the action of electrohydrodynamic pressure. Thus, the static and dynamic properties of the phenomenon called a ‘floating water bridge’ can be explained by the gradient of Maxwell pressure, replenishing the liquid within the bridge against any drainage mechanism. It is also shown that a number of liquids can form stable and long horizontal bridges. The stability of such a connection, and the asymmetry in mass flow through such bridges caused by the formation of ion clouds in the vicinity of the electrodes, is also discussed by two further experiments. 相似文献
146.
Collective behaviours can be observed in both natural and man-made systems composed of a large number of elemental subsystems. Typically, each elemental subsystem has its own dynamics but, whenever interaction between individuals occurs, the individual behaviours tend to be relaxed, and collective behaviours emerge. In this paper, the collective behaviour of a large-scale system composed of several coupled elemental particles is analysed. The dynamics of the particles are governed by the same type of equations but having different parameter values and initial conditions. Coupling between particles is based on statistical feedback, which means that each particle is affected by the average behaviour of its neighbours. It is shown that the global system may unveil several types of collective behaviours, corresponding to partial synchronisation, characterised by the existence of several clusters of synchronised subsystems, and global synchronisation between particles, where all the elemental particles synchronise completely. 相似文献
147.
A model of spring-block on a moving plate with a nonlinear periodic substrate potential whose shape can be varied continuously as a function of a shape parameter is investigated. The dynamical study of the system for different values of the shape parameter involves the analysis of phase space, the construction of bifurcation diagrams, and the computation of the largest Lyapunov exponent. A smart damper associated with drag coefficient is proposed to reduce stick-slip and chaotic motions. The domain of validity of the control method is derived. 相似文献
148.
Lionel Mathelin Olivier P. Le Ma?tre 《Theoretical and Computational Fluid Dynamics》2012,26(5):415-434
This paper describes a rigorous a posteriori error analysis for the stochastic solution of non-linear uncertain chemical models. The dual-based a posteriori stochastic error analysis extends the methodology developed in the deterministic finite elements context to stochastic discretization frameworks. It requires the resolution of two additional (dual) problems to yield the local error estimate. The stochastic error estimate can then be used to adapt the stochastic discretization. Different anisotropic refinement strategies are proposed, leading to a cost-efficient tool suitable for multi-dimensional problems of moderate stochastic dimension. The adaptive strategies allow both for refinement and coarsening of the stochastic discretization, as needed to satisfy a prescribed error tolerance. The adaptive strategies were successfully tested on a model for the hydrogen oxidation in supercritical conditions having 8 random parameters. The proposed methodologies are however general enough to be also applicable for a wide class of models such as uncertain fluid flows. 相似文献
149.
The present study deals with the formulation of minimal loading conditions for microscale applications in numerical two-scale modelling (FE2) approaches. From the homogenisation concept, a set of volume average rules constrains the microscale PDE to be solved. They are considered to be the minimal set of loading conditions and can be specified by additional polynomial or periodic assumptions, for example, on the microscale displacement field. Whereas the resulting volume integrals can be transformed into surface integrals for so-called first-order homogenisation schemes, this is not possible for a second-order homogenisation of second gradient or micromorphic effective media substituting a heterogeneous microcontinuum represented by a volume element on the microscale. Several numerical examples compare the minimal loading condition concept with standard techniques discussed in literature. 相似文献
150.
Karel Kolomazník Ji?í Pecha Veronika Friebrová Dagmar Janá?ová Vladimír Va?ek 《Heat and Mass Transfer》2012,48(9):1505-1512
Biostimulators are substances able to enhance the immune system of cultivated crops and support plant metabolism. Their utilization helps to reduce the amount of chemicals used in agriculture. To perform the desired effect, a biostimulator must be able to penetrate into the plant tissue. The time of penetration however, is limited, since the biostimulator must remain in a liquid state. This is of great importance—especially in field conditions, where the treated plants are exposed to different weather condition and other extrinsic factors. A mathematical model based on diffusion mechanisms has been elaborated to describe the biostimulator transport process from penetration of the leaves into the plant’s inner tissues. By means of the effective diffusion coefficient of the prepared specific protein hydrolyzate, this model can be used to estimate the time necessary for the uptake of the minimal active amount of the biostimulator. 相似文献