EMR对混沌同步保密通信系统干扰的初步研究

 使用GTEM Cell实验系统,研究了连续波电磁辐射对基于混沌同步理论的保密通信系统的电磁干扰。混沌保密通信系统采用由典型的Chua氏混沌电路构造混沌同步系统,采用掩盖法对模拟信号进行加密传输。实验发现：在100MHz~150MHz的频率范围内,超过一定功率密度的电磁辐射会导致系统的混沌加密功能失效,此后即使停止电磁辐射,系统仍无法自行恢复到混沌加密状态。     

Synthesis,Redox and Optical Properties of Low‐Bandgap Platinum(II) Polyynes with 9‐Dicyanomethylene‐Substituted Fluorene Acceptors

In view of the strong electron‐withdrawing nature of the cyano substituent, a blue donor/acceptor‐type organometallic polymer (trans‐[—Pt(PBu₃)₂—C≡C—R—C≡C—]_n (R = 9‐dicyanomethylenefluorene‐2,7‐diyl)) was prepared in good yield by CuI‐catalyzed polymerization involving the dehydrohalogenating coupling of trans‐[Pt(PBu₃)₂Cl₂] and H—C≡C—R—C≡C—H. The thermal, redox and photoconducting properties of the polymer are reported. Electronic absorption studies indicate that it has a bandgap of 1.58 eV which is the lowest among any of the metal polyyne polymers reported in the literature. The derivatization of the polymer backbone with electron deficient dicyano‐substituted electron acceptor in the side chain is found to be effective to tune the bandgap of this class of materials while maintaining their solubility and processability.