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排序方式: 共有198条查询结果,搜索用时 31 毫秒
31.
A three-dimensional visualization of velocity gradients at the finest scales in a turbulent free-shear flow is obtained using a time-resolved scanning PIV system with near Kolmogorov-scale resolution. A minimal observation volume capable of capturing single velocity gradient structures is used. The structures are identified by iso-surfaces revealing four basic shapes in the makeup of the velocity gradients: sheets, tubes, square ribbons and spherical blobs. Their size is also obtained. The 3D local acceleration structure is visualized showing strong anti-alignment with the convective acceleration. The statistics of the velocity gradient, and higher order moments (skewness and kurtosis) are calculated and compared favorably with published experimental work and with homogeneous isotropic theory. 相似文献
32.
Cristina Vázquez Graciela Custo Laura Dawidowski Darío Gómez Marina Villegas Martha Ortiz Mayumi Miyagusuku 《Analytical sciences》2005,21(7):763-767
Multielemental composition and morphology of particulate matter samples were examined to detect the presence of two potential responsible pollutant emitters at four sites impacted during a pollution episode in the City of Campana, Argentina. Coke and smoke black are the main constituents associated to the industrial plants that were considered, a priori, as responsible pollutant emitters. Wavelength dispersive X-ray fluorescence (WDXRF) was employed for the analysis of metals in samples coming from both, suspected sources and four sites. On the basis of multielemental composition profiles, a screening analysis was undertaken for exploring similarities among sources and sample sites adopting the average concentration profile of the crustal rock as soil surrogate. Particle morphology was studied by scanning electron microscopy (SEM) in source samples and in those environmental samples selected through the screening analysis. Two types of collected samples were analyzed: 1) those with composition profiles closer to the potential sources and 2) those closer to the cluster rock. This strategy was adequate to identify the responsible source of the contamination episode. 相似文献
33.
I. Villegas‐Coss F. A. Ruiz‐Trevio S. Hernndez‐Lpez 《Journal of Polymer Science.Polymer Physics》2006,44(1):256-263
Polyarylates based on isophthalic (IA) and terephthalic (TA) acids and an equimolar mixture of the diols Bisphenol A (BPA) and 1,1 bi‐2‐naphthol (BN) were synthesized to produce BPA‐BN/IA and BPA‐BN/TA polymers and to measure their gas permeability coefficients, P(i), at several pressures and 35 °C, to the gases O2, N2, CH4, and CO2. For the BPA‐BN/IA membranes, at a 2 atm up‐stream pressure, the P(O2) and P(CO2) are 0.93 and 4.0 Barrers with O2/N2 and CO2/CH4 ideal separation factors of 6.7 and 27. For the BPA‐BN/TA, at a 2 atm up‐stream pressure, the P(O2) and P(CO2) are 2.0 and 9.9 Barrers with O2/N2 and CO2/CH4 ideal separation factors of 5.6 and 21. Comparing the selectivity–permeability balance of properties shown by the BPA/TA membranes with that shown by the copolymer BPA‐BN/TA, the balance moves in the direction of higher selectivity and lower permeability because of the incorporation of BN, which is a more rigid monomer than BPA. However, when the balance of properties for the pair O2/N2 shown by BPA‐BN/TA is compared with the one shown by other membranes such as those based on mixtures of diols and diacids, that is the bisphenol A‐naphthalene/I‐T polymers reported in the literature, the balance moves up and to the right of the typical selectivity–permeability trade‐off observed in the BPA‐polyarylate family. Thus, simultaneous incorporations of flexible and rigid monomers in both the diols and the diacids lead to more productive and more selective membranes. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 256–263, 2006 相似文献
34.
Alejandro Madrid Villegas Katy Díaz Peralta César González Tapia Karen Catalán Marín 《Natural product research》2015,29(6):586-588
The resinous exudate, three meroterpenes, namely bakuchiol (1), 3-hydroxybakuchiol (2), 12-hydroxyisobakuchiol (3), and one furanocoumarin, psoralen (4), were isolated from the leaves of culen (Psoralea glandulosa). In addition to these, two semi-synthetic derivatives, bakuchiol acetate (5) and bakuchiol methyl eter (6), were obtained from 1, and were subsequently evaluated in vitro for the inhibitory effect of resin and compounds on the mycelial growth of Botrytis cinerea Pers.: Fr. and Phytophthora cinnamomi Rands. The resinous exudate inhibited the mycelial growth of both the pathogens, while bakuchiol (1) exhibited an inhibitory effect on the mycelial growth of B. cinerea up to 94% at a concentration of 150 mg/L and psoralen (4) reduced the mycelial growth of P. cinnamomi up to 80% at a concentration of 150 mg/L. These compounds have the ability of blocking the development of mycelial growth and may be used as a potential biopesticide in the agricultural sector once the in vivo test results have been validated. 相似文献
35.
A new method for lead oxide (PbO) analysis in glasses, using a carbon screen printed electrode (SPE) is proposed. A suspension of the powdered glass sample in nitric acid is prepared using an ultrasonic probe, 100 µL of slurry are deposited on the SPE and the voltammetric measurement is carried out. Structural information of PbO in the glass matrix is obtained by CV. Lead quantification is performed by DPV. In the best conditions a LOD of 2.30 wt% of PbO was obtained. The method has been applied with good results in the analysis of historical glasses samples. 相似文献
36.
Anthony JM Garrett 《Contemporary Physics》2013,54(2):163-165
The dynamic electronic structure of atoms and molecules can be directly observed by means of the (e, 2e) reaction, which measures the distribution of energies and momenta of two electrons in coincidence after a knockout reaction initiated by an electron beam of known momentum incident on a molecular gas target. The molecular state for each event is identified by the electron separation energy. The recoil momentum for each event is known from the difference of measured initial and final momenta. It has been verified that values of this momentum are equal under suitable conditions to the momentum of the electron in the target immediately before knockout. Thus the spherically-averaged electron momentum distribution for each molecular orbital is measured. This is directly related to molecular orbitals calculated by the methods of quantum chemistry. Properties obtained by this method for different types of molecules are discussed. 相似文献
37.
38.
S.E. Paje J. Llopis M.A. Villegas M.A. García J.M. Fernández Navarro 《Applied Physics A: Materials Science & Processing》1998,67(4):429-433
2 O·10 CaO·74 SiO2 mol%) glass doped with 0.11 and 0.35 wt.% silver are investigated. Heating treatments are carried out in a temperature range
between 400 and 575 °C for times ranging from 30 to 300 min in different atmospheres and cooling rates. The starting glasses
show a colourless and transparent appearance, but after thermal treatments under a reducing atmosphere become coloured, confirming
the presence of silver colloids related to the 410-nm absorption band. On the other hand, the main effects of thermal treatments
on the PL spectra concern those from samples treated in a reducing atmosphere. Thus, the intensity of both excitation and
emission spectra chiefly diminishes in the 220–230 nm and 325–350 nm ranges, respectively. In addition, time-resolved spectra
show the main ultraviolet (UV) emission centred above 330 nm upon excitation with 228-nm light. In contrast to the starting
glass, we notice no shift or even slight shifts of the peak position to longer wavelengths with increasing delay time after
pulse excitation, even for delay times as short as 0.01 ms. The results are discussed on the basis of transitions in which
Ag+ ions are involved.
Received: 6 February 1998/Accepted: 9 March 1998 相似文献
39.
Oxides have become a key ingredient for new concepts of electronic devices. To a large extent, this is due to the profusion of new physics and novel functionalities arising from ultrathin oxide films and at oxide interfaces. We present here a perspective on selected topics within this vast field and focus on two main issues. The first part of this review is dedicated to the use of ultrathin films of insulating oxides as barriers for tunnel junctions. In addition to dielectric non-magnetic epitaxial barriers, which can produce tunneling magnetoresistances in excess of a few hundred percent, we pay special attention to the possibility of exploiting the multifunctional character of some oxides in order to realize ‘active’ tunnel barriers. In these, the conductance across the barrier is not only controlled by the bias voltage and/or the electrodes magnetic state, but also depends on the barrier ferroic state. Some examples include spin-filtering effects using ferro- and ferrimagnetic oxides, and the possibility of realizing hysteretic, multi-state junctions using ferroelectric barriers. The second part of this review is devoted to novel states appearing at oxide interfaces. Often completely different from those of the corresponding bulk materials, they bring about novel functionalities to be exploited in spintronics and electronics architectures. We review the main mechanisms responsible for these new properties (such as magnetic coupling, charge transfer and proximity effects) and summarize some of the most paradigmatic phenomena. These include the formation of high-mobility two-dimensional electron gases at the interface between insulators, the emergence of superconductivity (or ferromagnetism) at the interface between non-superconducting (or non-ferromagnetic) materials, the observation of magnetoelectric effects at magnetic/ferroelectric interfaces or the effects of the interplay and competing interactions at all-oxide ferromagnetic/superconducting interfaces. Finally, we link up the two reviewed research fields and emphasize that the tunneling geometry is particularly suited to probe novel interface effects at oxide barrier/electrode interfaces. We close by giving some directions toward tunneling devices exploiting novel oxide interfacial phenomena. 相似文献
40.
The vehicle routing problem with stochastic demands consists in designing transportation routes of minimal expected cost to satisfy a set of customers with random demands of known probability distributions. This paper proposes a simple yet effective heuristic approach that uses randomized heuristics for the traveling salesman problem, a tour partitioning procedure, and a set partitioning formulation to sample the solution space and find high-quality solutions for the problem. Computational experiments on benchmark instances from the literature show that the proposed approach is competitive with the state-of-the-art algorithm for the problem in terms of both accuracy and efficiency. In experiments conducted on a set of 40 instances, the proposed approach unveiled four new best-known solutions (BKSs) and matched another 24. For the remaining 12 instances, the heuristic reported average gaps with respect to the BKS ranging from 0.69 to 0.15 % depending on its configuration. 相似文献