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511.
Dipti R. Patil Madhukar B. Deshmukh Sonali M. Salunkhe Prashant V. Anbhule 《Journal of heterocyclic chemistry》2011,48(6):1342-1346
An efficient and simple method has been reported for the synthesis of 2,3,4‐trisubstituted quinolines through zwitterion intermediate under reflux condition in presence of sulfuric acid. The formed dicarboxylate subsequently undergoes transesterification in various alcohols with good yields. Most of the synthesized compounds are newly reported characterized by spectroscopic method. J. Heterocyclic Chem., (2011). 相似文献
512.
Chikhalikar S Bhawe V Ghotekar B Jachak M Ghagare M 《The Journal of organic chemistry》2011,76(10):3829-3836
The nucleophilic vinylic substitution reaction of the aliphatic enaminone 3-dimethylamino-2-formyl acrylonitrile 1 with the nucleophiles malononitrile and ethyl cyanoacetate produced the two unusual reaction adducts 3a and 3b in good to moderate yield under milder reaction conditions. Upon reaction with aromatic amines, these adducts yielded enamines 4 and 5, which eventually cyclized in the presence of base to produce the novel pyridin-2(1H)-one derivatives 8 and 9. 相似文献
513.
Ramhari V. Rote Deepak P. Shelar Sandeep R. Patil Santosh S. Shinde Raghunath B. Toche Madhukar N. Jachak 《Journal of fluorescence》2011,21(1):453-459
Novel pyrazolo-pyrrolo-pyrimidine (PPP) derivatives having remarkable photophysical properties are designed with the help of theoretical semiempirical calculations. These compounds then synthesized successfully and studied effect of substituents on its photophysical properties. Figure
514.
Heterocyclic orthoaminoaldehyde such as 4-amino-3-(4-phenyl)-1-phenyl-1H-Pyrazolo[3,4-b]pyridine-5-carbaldehyde was synthesized by multistep reactions involving reduction of azido derivative 2 with LAH to yield aminoalcohol 3 and oxidation of it with MnO(2) to aminoaldehyde 4.The pyridine ring annulated on to 4 by Friedl?nder condensation using acetophenones in presence of base to obtained pyrazolo[3,4-h][1,6]naphthyridine 5 in excellent yield. Study of photophysical properties of 5 revealed that the absorption and emission of them depends up on the substituents present on benzene ring in newly annulated pyridine ring. 相似文献
515.
Ameya M. Mahadeshwar Sangram S. Patil Vishwadeep C. Handikherkar Vikas M. Phalle 《声与振动》2018,52(5):12-21
Wide range of rotating machinery contains an inherent amount of unbalance which leads to increase in the vibration level and related faults. In this work, the effect of different operating conditions viz. the unbalanced weight, radius, speed and position of the rotor disc on the unbalance in rotating machine are studied experimentally and analyzed by using Response Surface Methodology (RSM). RSM is a technique which consists of mathematical and statistical methods to develop the relationship between the inputs and outputs of a system by distinct functions. L27 Orthogonal Array (OA) was developed by using Design of Experiments (DOE) according to which experimentation has been carried out. Three accelerometer sensors were mounted to record the vibration responses (accelerations) in radially vertical, horizontal and axial directions. The responses recorded as root mean square values are then analysed using RSM. The relationship between response and operating factors has been established by developing a second order, non-linear mathematical model. Analysis of variance (ANOVA) has been performed for verification of the developed mathematical models. Results obtained from the analysis show that the unbalance weight and speed are most significant operating conditions that contribute the most to the effect the unbalance has on the rotating spindle. 相似文献
516.
The aim of this study to focused on bioinspired synthesis of silver nanoparticles (AgNPs) as a viable alternative to eradicate the existing physicochemical processes. In this context, the bioinspired AgNPs were synthesized using leaf extract of M. indica. Optimization of the experimental conditions for the rapid and high yield of AgNPs in minimum investment of time and expense have been carried out along with their antibacterial efficacy evaluated. For this reason, the variation of parameters like the concentration of the silver precursors, reducing agent, time, pH, and temperature of synthesis were realized. Synthesized AgNPs were characterized by UV-Visible spectroscopy, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM) techniques. UV-Visible spectra gave surface plasmon resonance (SPR) at 440 nm for AgNPs. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) techniques were further confirmed the synthesis and crystalline nature of AgNPs respectively. Transmission electron microscopy (TEM) observed spherical shapes of synthesized AgNPs within range 5~20 nm. The results of the current study indicate that optimization process play a pivotal role in the AgNPs synthesis and biogenic synthesized AgNPs might be used against bacterial pathogens. 相似文献
517.
Quantum communication with terahertz (THz) frequency signals has many advantages like reduced attenuation and scintillation effects in certain atmospheric conditions along with very high level of data security. In this work, we propose a scheme to realize Quantum Memory (QM) for efficient storage of terahertz (THz) frequency signals using Electromagnetically Induced Transparency (EIT) in an ultracold atomic medium of 87Rb Rydberg atoms prepared in a Two Dimensional Magneto Optical Trap (2D-MOT). The uniqueness of our scheme lies in the choice of the energy levels involved in the EIT process, all three of which have been chosen to be the Rydberg levels (enabling signal beam to be in THz) in a lambda type arrangement. This first of its kind proposal reveals that atomic media are a potential candidate for devising QMs which can store THz frequency signals. We have estimated that the Optical Depth (OD) in our scheme can reach a very high value of 690, very high maximum obtainable storage efficiency (η) of ~99%, the group velocity () can be as low as 5.07 × 103 m/s, and the Delay Bandwidth Product (DBP) can be as high as 9.5. All of these estimates emphasize the feasibility of our scheme as a QM device for efficient storage of THz pulses. 相似文献
518.
519.
Lihua Lin Pongpen Kaewdee Vikas Nandal Ryota Shoji Hiroyuki Matsuzaki Kazuhiko Seki Mamiko Nakabayashi Naoya Shibata Xiaoping Tao Xizhuang Liang Yiwen Ma Takashi Hisatomi Tsuyoshi Takata Prof. Kazunari Domen 《Angewandte Chemie (International ed. in English)》2023,62(42):e202310607
Photocatalytic water splitting is an ideal means of producing hydrogen in a sustainable manner, and developing highly efficient photocatalysts is a vital aspect of realizing this process. The photocatalyst Y2Ti2O5S2 (YTOS) is capable of absorbing at wavelengths up to 650 nm and exhibits outstanding thermal and chemical durability compared with other oxysulfides. However, the photocatalytic performance of YTOS synthesized using the conventional solid-state reaction (SSR) process is limited owing to the large particle sizes and structural defects associated with this synthetic method. Herein, we report the synthesis of YTOS particles by a flux-assisted technique. The enhanced mass transfer efficiency in the flux significantly reduced the preparation time compared with the SSR method. In addition, the resulting YTOS showed improved photocatalytic H2 and O2 evolution activity when loaded with Rh and Co3O4 co-catalysts, respectively. These improvements are attributed to the reduced particle size and enhanced crystallinity of the material as well as the slower decay of photogenerated carriers on a nanosecond to sub-microsecond time range. Further optimization of this flux-assisted method together with suitable surface modification is expected to produce high-quality YTOS crystals with superior photocatalytic activity. 相似文献