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31.
J. Mohanty H. Pal S. K. Nayak S. Chattopadhyay A. V. Sapre 《Chemical physics letters》2003,370(5-6):641-646
Fluorescence quenching of methoxycalixarenes (MOCX) by chloroalkanes (CA) has been investigated in acetonitrile solutions. Observed quenching is attributed to photoinduced dissociative electron transfer (DET) interaction, which is supported by the characterization of the Cl− ions and by the radical scavenging experiments. Comparing the Cl− yields with different DET systems, it is inferred that both concerted and stepwise DET mechanisms operate simultaneously in MOCX–CA systems. A correlation of the quenching constants with the free-energy changes following a suitable DET theory supports the above inference. 相似文献
32.
Cerium(IV) ammonium nitrate in substoichiometric amounts, promotes the intramolecular cyclization of epoxypropyl cinnamyl ethers to the corresponding 3,4,5-trisubstituted tetrahydropyran derivatives in moderate to good yields. 相似文献
33.
Vijay K. Goyal Rakesh K. Kapania 《International Journal of Solids and Structures》2008,45(10):2799-2817
Because of the inherent complexity of fiber-reinforced laminated composites, it can be challenging to manufacture composite structures according to their exact design specifications, resulting in unwanted material and geometric uncertainties. Thus the understanding of the effect of uncertainties in laminated structures on their static and dynamic responses is highly important for a reliable design of such structures. In this research, we focus on the probabilistic stability analysis of laminated structures subject to subtangential loading, a combination of conservative and nonconservative tangential loads, using the dynamic criterion. In order to study the dynamic behavior by including uncertainties into the problem, three models were developed: exact Monte Carlo simulation, sensitivity-based Monte Carlo simulation, and probabilistic FEA. These methods were integrated into the existing finite element analysis. Also, perturbation and sensitivity analysis have been used to study nonconservative problems to study the stability analysis using the dynamic criterion. 相似文献
34.
Pal Jen Wei 《Journal of Non》2008,354(33):3911-3918
Through the arrangement of the applied load, experimental nanoindentation results of polymethylmethacrylate (PMMA) and polyurethane (PU) employed to establish a mechanical model. The proposed model consists of irreversible delayed plastic (viscoplastic) deformation, irreversible viscous deformation, and reversible delayed elastic (viscoelastic) deformations. The phase lag exhibited between the responding depth and the oscillating load is found to be linear proportional to frequency in the range of 1-50 Hz. The residual cavity profile of the PMMA scanned by an atomic force microscope gives a validity of accommodation assumption applied in the present model. The effects of overshooting, which occurred in the dwelling process, are also discussed. 相似文献
35.
The vertical migration of 85Sr, 137Cs and 131I in some arable and undisturbed single-contaminated soils was studied by gamma-spectrometry measurements under lysimetric laboratory conditions during irrigation of the soil profiles with wet atmospheric precipitation for about one year, except 131I. A new simple exponential compartment (box) model was derived, which makes it possible to calculate the migration rate constants and migration rates in the individual soil layers (vertical sections) as well as the total vertical migration rate constants and total vertical migration rates of radionuclides in the bulk soil horizon. The relaxation times of radionuclides in respective soil horizons can also be evaluated. 相似文献
36.
In view of persisting discrepancy between experimental and theoretical results, specially in the weak radiative decays of∑ + andΞ 0, we analyse these decays within the framework of the QCD inspired quark-diquark model. On introducing a slightSU(6) breaking we obtainα(∑ +→p+γ)≈?0.9 which is in excellent agreement with experimental value. Other decays are also improved in this scheme. 相似文献
37.
R. U. Khan P. Chakrabarti B. B. Pal 《Applied Physics A: Materials Science & Processing》1987,42(4):303-309
Large signal characterisation of double heterostructure DDR Impatt diode has been carried out in the millimeter-wave range considering the MITATT mode of operation. The structure of the device is p+-p2-p1-n1-n2-n+ where impact ionisation and tunneling takes place in the p1-n1 region. In this study we have considered two well-known heterostructures, e.g., InP/GaInAs/InP and InP/InGaAsP/InP and one nonconventional structure GaAs/InP/GaAs. The theoretical results of the performances of these devices as regards of output power, efficiency, and negative conductance revealed that the structures are quite promising as the source of power in the millimeter-wave range. The analysis may be used for other mm wave DDR heterostructure Impatts. 相似文献
38.
J. Pal C. C. Dey S. Bose B. K. Sinha M. B. Chatterjee D. P. Mahapatra 《Zeitschrift für Physik A Hadrons and Nuclei》1987,356(3):281-286
The analogue of the 0+ ground state in 118Sn has been observed in the compound nucleus 118Sb through 117Sn(p,n γ) 117Sb reaction. The neutron decays of this analogue resonance have been studied from the deexciting γ-rays of the residual nucleus 117Sb. From off resonance excitation functions, spin assignments have been made to states in 117Sb, on the basis of Hauser-Feshbach formalism. The resonance parameters of the isobaric analogue resonance have been determined, including the total, proton and neutron decay widths. 相似文献
39.
Anupama Chaurasia Krishna K. Verma 《Fresenius' Journal of Analytical Chemistry》1995,351(2-3):335-337
2,4-Dinitrophenylhydrazine has been suggested as a new reagent for the flow-injection spectrophotometric determination of residual chlorine based on its oxidation to 2,4-dinitrophenyldiazonium ion. The measurement of the decrease in colour intensity under reversed flow-injection (reagent injection) conditions has been used for the determination of 0.1–10 mg/l Cl present as free or combined chlorine, and for its speciation. The limit of detection was 0.05 mg/l Cl. Copper (II), iron (III) and many other ions have been found not to vitiate the results. 相似文献
40.
Ferenc Sztaricskai Gyula Batta Zoltan Dinya Istvan F. Pelyvas Pal Herczegh Tamas E. Gunda Istvan Koczka 《Chemistry of Heterocyclic Compounds》1998,34(11):1296-1307
Starting from 3,5-dimethylisoxazole the carboxylic acids I and V, the amino acids VIII (L-) and IX (D-), and the ureido acids X (L-) and XI (D-) were prepared, which were used for the synthesis of the new cephalosporins XVIIb, XXa-c (L-), and XXIb (D-). Thein vitro antibacterial activity of these semi-synthetic antibiotics was studied. The resorption of XVIIb was investigated in mice.Research Group for Antibiotics of the Hungarian Academy of Sciences, H-4010 Debrecen, P.O. Box 70, Hungary. Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1524–1535, November, 1998. 相似文献