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81.
Guimes Rodrigues Filho Júlia G. Vieira Daniel A. Cerqueira Sidney J.L. Ribeiro 《Polymer Degradation and Stability》2007,92(2):205-210
In the present work, methylcellulose produced from sugar cane bagasse was characterized by FTIR, WAXD, DTA and TGA techniques. Two samples were synthesized: methylcellulose A and methylcellulose B. The only difference in the process was the addition of fresh reactants during the preparation of methylcellulose B. The ratio between the absorption intensities of the C-H stretching band at around 2900 cm−1 and O-H stretching at around 3400 cm−1 for methylcellulose B is higher than for methylcellulose A, indicating that methylcellulose B showed an increase in the degree of substitution (DS). Methylcellulose A presents a more heterogeneous structure, which is similar to the original cellulose as seen through FTIR and DTA. Methylcellulose B showed thermal properties similar to commercial methylcellulose. The modification of methylcellulose preparation method allows the production of a material with higher DS, crystallinity and thermal stability in relation to the original cellulose and to methylcellulose A. 相似文献
82.
In this paper we are concerned with a special class of bicriterion path problems. For the considered class of bicriterion problems at least one of the objectives is type MAXMIN. For the other one, besides an objective type MAXMIN also a MINSUM and a MINRATIO type objective are considered. Two algorithms are presented for the considered class of bicriterion path problems. The first one only determines the minimal complete set of nondominated paths and the second one determines the entire set of nondominated paths. Both algorithms can be used for any type of bicriterion path problems, since one of the objectives is type MAXMIN and an algorithm exists to determine the best path for the other objective. Computational statistics for the three types of considered bicriterion path problems are also presented. 相似文献
83.
We report both experimental and theoretical studies of the optical properties in KCl of a defect-associated In center whose sole previously identified optical transition was a strong absorption band peaking at 610 nm. With the aid of an optical tagging technique, we have been able to identify with that center two new but much weaker absorption bands peaking at 860 and 960 nm, respectively. We show that the energy splittings, relative strengths, and less perfectly, the polarizations of those three transitions make fit to the In0(1) center model, i.e., the model, initially developed for the Tl0(1) center, of a neutral atom perturbed by the field of an adjacent anion vacancy. However, in contrast to the Tl0(1) center, the In0(1) center lacks a significant emission, excluding its use as a laser gain medium. 相似文献
84.
This paper describes the development and validation of a sequential injection (SI) anodic stripping voltammetry (ASV) method
using the hanging mercury drop electrode for accumulation of the heavy metal cations Cu(II), Pb(II) and Cd(II). The method
was applied to wastewater samples after proper acid digestion in open vessels to eliminate matrix effects. For a deposition
time of 90 s at the flow rate of 10 μl s−1, the detection limits of the method were 0.06, 0.09 and 0.16 μmol L−1 for Cd, Pb and Cu, respectively. Under these conditions the linear dynamic range was between 0.20 and 9.0 μmol L−1 and the sampling frequency was 30 analyses per hour. The relative standard deviation of the method was 3%(n=7) at the concentration level of 2.0 μmol L−1. The accuracy of the method was evaluated by spiking the samples with known amounts of the metal cations, and by comparison
with an independent analytical technique, the inductively coupled plasma atomic emission spectroscopy (ICP-AES). Average recoveries
were around of 84%, and the results showed no evidence of systematic errors in comparison to the ICP-AES. 相似文献
85.
A. R. Vieira Brigitte Hiller M. C. Nemes Marcos Sampaio 《International Journal of Theoretical Physics》2013,52(10):3494-3503
Arbitrary regularization dependent parameters in Quantum Field Theory are usually fixed on symmetry or phenomenology grounds. We verify that the quadratically divergent behavior responsible for the lack of naturalness in the Standard Model (SM) is intrinsically arbitrary and regularization dependent. While quadratic divergences are welcome for instance in effective models of low energy QCD, they pose a problem in the SM treated as an effective theory in the Higgs sector. Being the very existence of quadratic divergences a matter of debate, a plausible scenario is to search for a symmetry requirement that could fix the arbitrary coefficient of the leading quadratic behavior to the Higgs boson mass to zero. We show that this is possible employing consistency of scale symmetry breaking by quantum corrections. Besides eliminating a fine-tuning problem and restoring validity of perturbation theory, this requirement allows to construct bounds for the Higgs boson mass in terms of $\delta m^{2}/m^{2}_{H}$ (where m H is the renormalized Higgs mass and δm 2 is the 1-loop Higgs mass correction). Whereas $\delta m^{2}/m^{2}_{H}<1$ (perturbative regime) in this scenario allows the Higgs boson mass around the current accepted value, the inclusion of the quadratic divergence demands $\delta m^{2}/m^{2}_{H}$ arbitrarily large to reach that experimental value. 相似文献
86.
Matheus Vieira 《Archiv der Mathematik》2013,101(6):581-590
In this paper we prove that on a complete smooth metric measure space with non-negative Bakry–Émery–Ricci curvature if the space of weighted L 2 harmonic one-forms is non-trivial, then the weighted volume of the manifold is finite and the universal cover of the manifold splits isometrically as the product of the real line with a hypersurface. 相似文献
87.
In this paper we study a generalization of an index integral involving the product of modified Bessel functions and associated Legendre functions. It is applied to a convolution construction associated with this integral, which is related to the classical Kontorovich–Lebedev and generalized Mehler–Fock transforms. Mapping properties and norm estimates in weighted L p -spaces, 1 ≤ p ≤ 2, are investigated. An application to a class of convolution integral equations is considered. Necessary and sufficient conditions are found for the solvability of these equations in L 2. 相似文献
88.
Cinnamic acid and its derivatives react with hydroxyl radical (HO?), in neutral medium, to give hydroxylation products, whether on the benzene ring or on the exocyclic chain, and decarboxylation products. The latter compounds are also obtained after oxidation of the same substrates by the SO4?? radical anion. Evidence was provided for the protecting effects afforded by cinnamic acid and hydroxylated derivatives against oxidative reaction mediated by HO?. By using adenine as a model compound, the results obtained suggest that the high protective effect is due to an antioxidising cascade process. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
89.
Flávia R. O. Silva Camila T. Nabeshima Maria H. Bellini Nestor Schor Nilson D. Vieira Jr Lilia C. Courrol 《Journal of fluorescence》2013,23(1):131-135
This paper describes the elimination of porphyrins by feces. It was demonstrated that porphyrin accumulates substantially more in tumors than in normal tissues, and consequently more PPIX reaches the blood of patients and animals with tumors, and then, it needs to be eliminated. The fluorescence of feces revealed that there are large amounts of PPIX in the excreta of animals with cancer comparing with healthy animals. The autofluorescence of feces porphyrin extracted with acetone was analyzed using fluorescence spectroscopy of animals inoculated with DU145 cells into the prostate and healthy animals to monitor the PPIX concentration. Emission spectra were obtained by exciting the samples at 405 nm. Significant differences were observed in autofluorescence intensities measured in the 575–725 nm spectral regions for the studied groups. The results showed a noninvasive, simple, rapid and sensitive method to detect cancer by feces analysis. 相似文献
90.
P.M.A. Farias B.S. Santos A.A.S. Vieira A.G. Castro-Neto A.H.G.B. Da Cunha J.C.O.F. Amaral 《Applied Surface Science》2008,255(3):691-693
We present and discuss the application of colloidal semiconductor quantum dots for diagnostic purposes, with special emphasis for cancer. We prepared and applied core-shell cadmium sulfide-cadmium hydroxide (CdS/Cd(OH)2) semiconductor quantum dots in aqueous medium. Tissue and cells labeling was evaluated by laser scanning confocal microscopy as well as by conventional fluorescence microscopy. The procedure presented in this work, shown to be a promising tool for fast, low-cost and precise cancer diagnostic protocols. 相似文献