Characterization and Thermal Behaviour of Garnets from Almandine–Pyrope Series at 1200°C

Hyperfine Interactions - The natural garnets from almandine (Fe3Al2Si3O12)–pyrope (Mg3Al2Si3O12) series with the iron to magnesium atomic ratio ranging from 0.2 to 1 were characterised and...     

Dislocation unpinning model of acoustic emission from alkali halide crystals

The present paper reports the dislocation unpinning model of acoustic emission (AE) from alkali halide crystals. Equations are derived for the strain dependence of the transient AE pulse rate, peak value of the AE pulse rate and the total number of AE pulse emitted. It is found that the AE pulse rate should be maximum for a particular strain of the crystals. The peak value of the AE pulse rate should depend on the volume and strain rate of the crystals, and also on the pinning time of dislocations. Since the pinning time of dislocations decreases with increasing strain rate, the AE pulse rate should be weakly dependent on the strain rate of the crystals. The total number of AE should increase linearly with deformation and then it should attain a saturation value for the large deformation. By measuring the strain dependence of the AE pulse rate at a fixed strain rate, the time constantτ _s for surface annihilation of dislocations and the pinning timeτ _p of the dislocations can be determined. A good agreement is found between the theoretical and experimental results related to the AE from alkali halide crystals.     

Thermal degradation of two liquid fuels and detonation tests for pulse detonation engine studies

The use of liquid fuels such as kerosene is of interest for the pulse detonation engine (PDE). Within this context, the aim of this work, which is a preliminary study, was to show the feasibility to initiate a detonation in air with liquid-fuel pyrolysis products, using energies and dimensions of test facility similars to those of PDEs. Therefore, two liquids fuels have been compared, JP10, which is a synthesis fuel generally used in the field of missile applications, and decane, which is one of the major components of standard kerosenes (F-34, Jet A1, ...). The thermal degradation of these fuels was studied with two pyrolysis processes, a batch reactor and a flow reactor. The temperatures varied from 600°C to 1,000°C and residence times for the batch reactor and the flow reactor were, respectively, between 10–30 s and 0.1–2 s. Subsequently, the detonability of synthetic gaseous mixtures, which was a schematisation of the decomposition state after the pyrolysis process, has been studied. The detonability study, regarding nitrogen dilution and equivalence ratio, was investigated in a 50 mm-diameter, 2.5 m-long detonation tube. These dimensions are compatible with applications in the aircraft industry and, more particularly, in PDEs. Therefore, JP10 and decane were compared to choose the best candidate for liquid-fuel PDE studies. This paper was based on work that was presented at the 20th International Colloquium on the Dynamics of Explosions and Reactive Systems, Montreal, Canada, July 31 – August 5, 2005.     

Asymptotic conditions for the electromagnetic form factors of hadrons represented by the VMD model

A system of linear homogeneous algebraic equations for the coupling constant ratios of vector mesons to hadrons is derived by imposing the assumed asymptotic behavior upon the VMD pole parameterization of an hadron electromagnetic form factor. A similar system of equations with a simpler structure of the coefficients, taken as even powers of the vector-meson masses, is derived by means of integral superconvergent sum rules for the imaginary part of the considered form factor using its appropriate -function approximation. Although both systems have been derived starting from different properties of the electromagnetic form factor and they each have their own appearances, it is shown explicitly that they are fully equivalent. Received: 20 March 2002 / Revised version: 3 December 2002 / Published online: 7 March 2003     

Investigation of anode and cathode jets influence on electric arc properties with current up to 500 kA

A number of phenomena connected with the formation of electrode jets in discharges in hydrogen at a current of 10/sup 5/-10/sup 6/ A, a current growth rate of 10/sup 10/ A/s, an initial pressure 0.1-4.0 MPa, and a discharge gap length of 5-40 mm were studied. After the secondary breakdown, the jets are observed through a discharge semitransparent channel, widening with velocity (4-7) /spl middot/ 10/sup 2/ m/s. Shockwave formation was detected at the interaction of jets with the surrounding gas and the opposite electrode. Plasma vapor pressure of metal near the end of the tungsten cathode 70 /spl mu/s after initiation of a discharge was 180 MPa. Thus, magnitude of brightness temperature was 59 /spl middot/ 10/sup 3/ K, with an average charge of ions-m~=3.1, and a concentration of metal vapors n=5.3/spl middot/10/sup 19/ cm/sup -3/. While those at the end of the anode 90 /spl mu/s after initiation of discharge: m~=2.6, n=7.4/spl middot/10/sup 19/ cm/sup -3/. Probable reasons of high-voltage drops near the electrodes (the summarized magnitude of which is /spl sim/1 kV) are discussed on the basis of experimental data. For the first time, the shadow method registered symmetric ejection of material from the all-cathode surface the maximum discharge current was observed.     

Use of anion-exchange high-performance liquid chromatography for the study of smooth muscle myosin light-chain kinase and its catalytic domain

Avian myosin light-chain kinase from smooth muscle of the gizzard and its catalytic domain, derived from the intact enzyme by trypsin digestion, was purified within 30-40 min by both analytical and preparative anion-exchange high-performance liquid chromatography. The proteins obtained were more than 95% pure and retained their biological activity. The high-performance anion-exchange chromatography protocols represent a significant decrease in purification time when compared with conventional ion-exchange chromatography.     

The free Malcev superalgebra on one odd generator and related superalgebras

A base of the universal multiplicative envelope of the free Malcev superalgebra ℳ on one odd generator is constructed. Some corollaries for skew-symmetric functions and central elements in free Malcev and free alternative algebras are obtained. Moreover, a base of the Poisson-Malcev superalgebra of ℳ is constructed. As a corollary, a set of elements that spans the free alternative superalgebra on one odd generator is obtained. __________ Translated from Fundamentalnaya i Prikladnaya Matematika, Vol. 10, No. 4, pp. 97–106, 2004.     

Nonturnpike Optimal Solutions and Their Approximations in Infinite Horizon

Recently, the authors have proposed a new necessary and sufficient condition for turnpike optimality in calculus of variations with singular Euler equation. The method is based on a characterization of the value function and generalizes the well known method based on the Green theorem. Furthermore, it allows the optimality of a competition between several turnpikes to be characterized. For a class of such problems not enjoying the turnpike property, we give an explicit formula for the value function and show how to characterize the optimal solution as the limiting solution of a family of perturbed problems satisfying the turnpike property. The considered problems are scalar with infinite horizon.     

Special features of magnetic susceptibility dispersion in nanocrystalline magnets

It is demonstrated theoretically that the initial (both elastic and viscous) magnetic susceptibility components for nanocrystalline magnets caused by the processes of rotations (in the region of linear response) have resonant rather than relaxation character typical already for the susceptibility component caused by displacements of domain boundaries. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 88–92, June, 2007.     

Possible spectroscopic manifestation of the angular group induced bond alteration (AGIBA) effect in toluene

The most obvious consequence of the concept of aromaticity is the common confidence that in aromatic compounds, bond lengths do not alternate and are between typical to the single and double ones. However, in 1994, performing crystal structure investigations of substituted pyridines and their salts, Krygowski and co‐workers have discovered a very surprising angular group induced bond alteration (AGIBA) effect: It appears that some angular substituents, like methoxy or nitrozo groups, can induce bond alternation in aromatic rings. Crystal studies do not allow one to operate with liquids that are more common in organic chemistry. This paper presents the first possible evidence of spectroscopic manifestations of the AGIBA effect. Raman spectra of the liquid toluene are analyzed. It is found that instead of being single, the line corresponding to the ring breathing vibrations is clearly split by 1.0–1.4 cm^?1, thus indicating the presence of two (cis‐ and trans‐) AGIBA isomers. The energy difference between these isomers estimated in temperature dependent Raman studies is found equal to 6.68 kJ mol^?1. The low‐wavenumber line therefore corresponds to the cis‐AGIBA isomer and the high‐wavenumber line to the trans‐AGIBA isomer stabilized by the AGIBA effect. Copyright © 2007 John Wiley & Sons, Ltd.