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21.
Baioni AP Vidotti M Fiorito PA Ponzio EA de Torresi SI 《Langmuir : the ACS journal of surfaces and colloids》2007,23(12):6796-6800
Nanoparticles of a Prussian blue (PB) analogue, copper hexacyanoferrate, were synthesized by using ultrasonic radiation and characterized by spectroscopic and electrochemical techniques. The nanoparticles (ca. 10 nm diameter) were immobilized onto transparent indium tin oxide electrodes by electrostatic layer-by-layer deposition. These modified electrodes showed interesting electrochromic properties, changing the coloration during the redox process from brown to orange when oxidized. The nanostructured electrode presented high stability, in contrast to that observed for PB nanoparticles; this fact must be related to the maintenance of the electrostatic assembly because the oxidized compound, CuII/FeIII(CN)6, still possesses a negative excess of charge due to the high number of cyanide groups that link the nanoparticles with the polycation, assuring the integrity of the whole electrostatic assembled film. 相似文献
22.
Mora JF Van Berkel GJ Enke CG Cole RB Martinez-Sanchez M Fenn JB 《Journal of mass spectrometry : JMS》2000,35(8):939-952
Editorial Comment Last month we presented, as a Special Feature, a set of five articles that constituted a Commentary on the fundamentals and mechanism of electrospray ionization (ESI). These articles produced some lively discussion among the authors on the role of electrochemistry in ESI. Six authors participated in a detailed exchange of views on this topic, the final results of which constitute this month's Special Feature. We particularly hope that younger scientists will find value in this month's Special Feature, not only for the science that it teaches but also what it reveals about the processes by which scientific conclusions are drawn. To a degree, the contributions part the curtains on these processes and show science in action. We sincerely thank the contributors to this discussion. The give and take of intellectual debate is not always easy, and to a remarkable extent this set of authors has maintained good humor and friendships, even when disagreeing strongly on substance. Graham Cooks and Richard Caprioli Copyright 2000 John Wiley & Sons, Ltd. 相似文献
23.
Van Berkel GJ Quirke JM Adams CL 《Rapid communications in mass spectrometry : RCM》2000,14(10):849-858
A survey of derivatization strategies and prospective derivatization reactions for conversion of simple alkenes and alkynes to 'electrospray-active' species is presented. General synthetic strategies are discussed and illustrative examples of prospective derivatives prepared from model compounds are presented along with their electrospray ionization (ES) mass spectra. The identified derivatives of these neutral, nonpolar analytes are either ionic or are ionizable in solution through Bronsted acid/base chemistry, by Lewis acid/base chemistry, or by chemical or electrochemical electron-transfer chemistry. Once ionized, the derivatives are expected to be amenable to detection by electrospray ionization-mass spectrometry. Derivatives are identified for positive and negative ion analysis of both alkenes and alkynes. Copyright 2000 John Wiley & Sons, Ltd. 相似文献
24.
Franciele Wolfart Amanda Maciel Noemi Nagata Marcio Vidotti 《Journal of Solid State Electrochemistry》2013,17(5):1333-1338
This paper concerns the deposition of metal alloys formed by nickel and copper on electrode surface aiming at the development of electrocatalytic systems. Such alloys were formed on platinum electrodes by direct reduction of Ni2+ and Cu2+ sulfate salts in different proportions in a simple and straightforward electrochemical treatment. After the deposition, the conversion to the electrocatalytic oxide form was done in alkaline solutions by cyclic voltammograms. The experimental parameters, such as deposition time and the proportion of copper and nickel in the synthetic solution, were investigated toward the catalytic oxidation of glucose. The materials were characterized by electrochemical experiments, infrared and Raman spectroscopies, and X-ray diffraction, showing that the material is not a simple mixture of nickel and copper oxides. The modified electrodes showed remarkable electrocatalytic properties, indicating an interesting application in the sensor and fuel cell development. 相似文献
25.
Camila Pesqueira Bruna M. Hryniewicz Larissa Bach-Toledo Luciane Novaes Tenrio Luís F. Marchesi Talita Mazon Marcio Vidotti 《Molecules (Basel, Switzerland)》2022,27(18)
Polypyrrole (PPy) is an interesting conducting polymer due to its good environmental stability, high conductivity, and biocompatibility. The association between PPy and metallic nanoparticles has been widely studied since it enhances electrochemical properties. In this context, gold ions are reduced to gold nanoparticles (AuNPs) directly on the polymer surface as PPy can be oxidized to an overoxidized state. This work proposes the PPy electrochemical synthesis followed by the direct reduction of gold on its surface in a fast reaction. The modified electrodes were characterized by electronic microscopic and infrared spectroscopy. The effect of reduction time on the electrochemical properties was evaluated by the electrocatalytic properties of the obtained material from the oxidation of ascorbic acid (AA) and electrochemical impedance spectroscopy studies. The presence of AuNPs improved the AA electrocatalysis by reducing oxidation potential and lowering charge transfer resistance. EIS data were fitted using a transmission line model. The results indicated an increase in the electronic transport of the polymeric film in the presence of AuNPs. However, PPy overoxidation occurs when the AuNPs’ deposition is higher than 30 s. In PPy/AuNPs 15 s, smaller and less agglomerated particles were formed with fewer PPy overoxidized, confirming the observed electrocatalytic behavior. 相似文献