全文获取类型
收费全文 | 1868篇 |
免费 | 93篇 |
国内免费 | 22篇 |
专业分类
化学 | 1374篇 |
晶体学 | 11篇 |
力学 | 17篇 |
数学 | 263篇 |
物理学 | 318篇 |
出版年
2023年 | 15篇 |
2022年 | 30篇 |
2021年 | 53篇 |
2020年 | 42篇 |
2019年 | 43篇 |
2018年 | 41篇 |
2017年 | 36篇 |
2016年 | 74篇 |
2015年 | 50篇 |
2014年 | 63篇 |
2013年 | 119篇 |
2012年 | 133篇 |
2011年 | 152篇 |
2010年 | 86篇 |
2009年 | 65篇 |
2008年 | 124篇 |
2007年 | 115篇 |
2006年 | 99篇 |
2005年 | 91篇 |
2004年 | 81篇 |
2003年 | 61篇 |
2002年 | 65篇 |
2001年 | 25篇 |
2000年 | 50篇 |
1999年 | 27篇 |
1998年 | 16篇 |
1997年 | 25篇 |
1996年 | 29篇 |
1995年 | 26篇 |
1994年 | 17篇 |
1993年 | 12篇 |
1992年 | 18篇 |
1991年 | 7篇 |
1990年 | 10篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 4篇 |
1986年 | 9篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1934年 | 2篇 |
排序方式: 共有1983条查询结果,搜索用时 15 毫秒
141.
Mui Siang Soh Sonsoles Amor Garcia Santamaria Evan Laurence Williams Marta Pérez‐Morales Henk J. Bolink Alan Sellinger 《Journal of Polymer Science.Polymer Physics》2011,49(7):531-539
A new class of solution processable dendrimers based on cyclic phosphazene (CP) cores have been prepared and used as host materials for blue and green organic light emitting diodes (OLEDs). The dendrimers are prepared in high yield from minimal step reactions, are soluble in common solvents for solution processing, are amorphous, and have excellent thermal properties necessary for application in OLEDs. OLED efficiencies of 10.3 cd/A (4.2 lm/W) and 35.3 cd/A (33.5 lm/W) were achieved using commercially available FIrpic and Ir(mppy)3 as blue and green phosphorescent emitters, respectively. These efficiencies were 2× higher than control devices prepared using poly(N‐vinylcarbazole), the most commonly used host material in solution processed phosphorescent OLEDs. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
142.
Jorge Bustamante José M. Quesada Lorena Morales de la Cruz 《Journal of Approximation Theory》2010,162(8):1495-1508
We present direct theorems for some sequences of positive linear operators in weighted spaces. The results, given in terms of some Ditzian–Totik moduli of smoothness, include estimations in norms and Becker type estimations. 相似文献
143.
A J Conejo F J Nogales M Carrión J M Morales 《The Journal of the Operational Research Society》2010,61(2):235-245
Organized trading for electricity includes both the pool and the futures market. Pool prices are volatile while the prices of the futures-market products are comparatively more stable. Thus, futures-market products constitute hedging instruments to reduce the risk suffered by any market agent. Electricity market agents engage in both pool and futures market transactions seeking to maximize their respective profits/utilities for a given risk level on profit variability. To make informed decisions, the market agent must gather as much accurate information as possible on the pool prices covering the whole time horizon spanned by the futures-market product. This paper provides a novel technique to represent conveniently the uncertainty associated with pool prices during long- or medium-term horizons through a set of scenarios, that is, pool price realizations. The proposed technique uses the prices of the futures-market products as long-term explanatory variables and exploits the short-term structure of the pool prices. 相似文献
144.
M. S. Batista M. A. Morales E. Baggio-Saitovich E. A. Urquieta-González 《Hyperfine Interactions》2001,134(1):161-166
The Fe species present in Fe/ZSM-5 catalysts prepared by ionic exchange in aqueous solution or in the solid state are investigated. The samples were characterized by XRD, EPR, Mössbauer Spectroscopy (MOS-S) and chemical analysis. XRD showed that the peak intensity decreased with the increase in Fe content in the samples. EPR and MOS-S showed that the Fe atoms in all the activated samples appear as Fe+3, independently of the method used in the catalyst preparation. The MOS-S data also showed that Fe/ZSM-5, prepared by ion exchange in the solid state presented lower hematite content and more Fe species in charge-compensation sites, the responsible for the catalytic activity, as confirmed by the behavior in the propane oxidation. 相似文献
145.
Victoria Hernández-Mederos Pedro L. del Ángel Jorge Estrada-Sarlabous 《Numerical Algorithms》2008,48(1-3):29-47
In this paper we propose an advancing front method for generating an isotropic triangular mesh on a regular parametric surface. Starting from a point on the surface, the method computes a set of points in the intersection curve between the surface and the sphere centered at that point with a prescribed radius. From this set we select the vertices of a cell composed by triangles approximately equilateral. The mesh grows repeating the described computation with boundary vertices of the cell as starting points. Compared to methods proposed by other authors, the current method may be considered as an improvement, since it is more efficient and flexible. Furthermore, the resulting mesh is closer to being isotropic. Additionally, we obtain a sufficient condition ensuring that a surface triangulation is of Delaunay type. 相似文献
146.
Jorge Antonio Guerrero‐Álvarez Wendy Paloma Mas‐Ku Cesar Garcías‐Morales Armando Ariza‐Castolo 《Magnetic resonance in chemistry : MRC》2010,48(5):356-361
The relative acidities of the cis and trans isomers of a series of 1,5‐oxazaspiro[5.5]undecane derivatives were determined by measuring ΔpK in acid‐base titrations followed by 1 H NMR. Relative structural stabilities were determined by measuring substituent chemical shift and γ‐gauche effects in 13C, 15N, and 17O NMR. Crystallographic characterization of a model spiro[5.5]undecane is presented to support the basicity in solid state. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
147.
Revenue management (RM) enhances the revenues of a company by means of demand-management decisions. An RM system must take into account the possibility that a booking may be canceled, or that a booked customer may fail to show up at the time of service (no-show). We review the Passenger Name Record data mining based cancellation rate forecasting models proposed in the literature, which mainly address the no-show case. Using a real-world dataset, we illustrate how the set of relevant variables to describe cancellation behavior is very different in different stages of the booking horizon, which not only confirms the dynamic aspect of this problem, but will also help revenue managers better understand the drivers of cancellation. Finally, we examine the performance of the state-of-the-art data mining methods when applied to Passenger Name Record based cancellation rate forecasting. 相似文献
148.
Background
Lesion studies in human and non-human primates have linked several different regions of prefrontal cortex (PFC) with the ability to inhibit inappropriate motor responses. However, recent functional neuroimaging studies have specifically implicated right inferior PFC in response inhibition. Right frontal dominance for inhibitory motor control has become a commonly accepted view, although support for this position has not been consistent. Particularly conspicuous is the lack of data on the importance of the homologous region in the left hemisphere. To investigate whether the left inferior frontal gyrus (IFG) is critical for response inhibition, we used neuropsychological methodology with carefully characterized brain lesions in neurological patients. 相似文献149.
150.
Nicholas E. Leadbeater Sharon J. Pillsbury Erik Shanahan Victoria A. Williams 《Tetrahedron》2005,61(14):3565-3585
In the light of the controversy in the area and since reports using simultaneous cooling in conjunction with microwave heating are appearing in the literature, we were keen to assess the methodology, looking at temperature measurement issues as well as the use of the technique in three classes of reaction, namely a Heck coupling, a Diels-Alder cycloaddition and a Michael addition. We present our initial findings here. 相似文献