全文获取类型
收费全文 | 4958篇 |
免费 | 147篇 |
国内免费 | 44篇 |
专业分类
化学 | 3172篇 |
晶体学 | 31篇 |
力学 | 123篇 |
数学 | 1007篇 |
物理学 | 816篇 |
出版年
2023年 | 32篇 |
2022年 | 99篇 |
2021年 | 114篇 |
2020年 | 100篇 |
2019年 | 114篇 |
2018年 | 99篇 |
2017年 | 72篇 |
2016年 | 154篇 |
2015年 | 121篇 |
2014年 | 141篇 |
2013年 | 275篇 |
2012年 | 272篇 |
2011年 | 332篇 |
2010年 | 202篇 |
2009年 | 174篇 |
2008年 | 311篇 |
2007年 | 234篇 |
2006年 | 245篇 |
2005年 | 250篇 |
2004年 | 234篇 |
2003年 | 166篇 |
2002年 | 163篇 |
2001年 | 65篇 |
2000年 | 60篇 |
1999年 | 71篇 |
1998年 | 53篇 |
1997年 | 41篇 |
1996年 | 77篇 |
1995年 | 46篇 |
1994年 | 37篇 |
1993年 | 40篇 |
1992年 | 38篇 |
1991年 | 40篇 |
1990年 | 19篇 |
1989年 | 22篇 |
1988年 | 23篇 |
1987年 | 26篇 |
1986年 | 24篇 |
1985年 | 40篇 |
1984年 | 40篇 |
1983年 | 22篇 |
1982年 | 41篇 |
1981年 | 34篇 |
1980年 | 17篇 |
1979年 | 34篇 |
1978年 | 40篇 |
1977年 | 21篇 |
1976年 | 25篇 |
1974年 | 18篇 |
1973年 | 21篇 |
排序方式: 共有5149条查询结果,搜索用时 5 毫秒
101.
102.
We present a class of interacting nonlocal quantum field theories, in which the CPT invariance is violated while the Lorentz invariance is present. This result rules out a previous claim in the literature that the CPT violation implies the violation of Lorentz invariance. Furthermore, there exists the reciprocal of this theorem, namely that the violation of Lorentz invariance does not lead to the CPT violation, provided that the residual symmetry of Lorentz invariance admits the proper representation theory for the particles. The latter occurs in the case of quantum field theories on a noncommutative space–time, which in place of the broken Lorentz symmetry possesses the twisted Poincaré invariance. With such a CPT-violating interaction and the addition of a C-violating (e.g., electroweak) interaction, the quantum corrections due to the combined interactions could lead to different properties for the particle and antiparticle, including their masses. 相似文献
103.
We study the effect of gold doping on oxygen vacancy formation and CO adsorption on the (1 1 0) and (1 0 0) surfaces of ceria by using density functional theory, corrected for on-site Coulomb interactions (DFT + U). The Au dopant substitutes a Ce atom in the surface layer, leading to strong structural distortions. The formation of one oxygen vacancy near a dopant atom is energetically “downhill” while the formation of a second vacancy around the same dopant requires energy. When the surface is in equilibrium with gaseous oxygen at 1 atm and room temperature there is a 0.4 probability that no oxygen atom left the neighborhood of a dopant. This means that the sites where the dopant has not lost oxygen are very active in oxidation reactions. Above 400 K almost all dopants have an oxygen vacancy next to them and an oxidation reaction in such a system takes place by creating a second vacancy. The energy required to form a second vacancy is smaller on (1 1 0) than on (1 0 0). On the (1 1 0) surface, it is much easier to form a second vacancy on the doped surface than the first vacancy on the undoped surface. The energy required to form a second oxygen vacancy on (1 0 0) is comparable to that of forming the first vacancy on the undoped surface. Thus doping makes the (1 1 0) surface a better oxidant but it has a small effect on the oxidative power of the (1 0 0) surface. On the (1 1 0) surface CO adsorption results in formation of a carbonate-like structure, similar to the undoped surface, while on the (1 0 0) surface direct formation of CO2 is observed, in contrast to the undoped surface. The Au dopant weakens the bond of the surrounding oxygen atoms to the oxide making it a better oxidant, facilitating CO oxidation. 相似文献
104.
Endovascular optical coherence tomography (EV-OCT) is an emerging intravascular imaging technique for observing blood vessel walls. Fluctuating speckle noise, especially during rapid pull-back, can severely degrade the visibility of morphological structures. Moreover, the speckle pattern varies in different parts of the image due to beam divergence and is further complicated by interpolation through the coordinate transformation necessary for displaying the rotary scanning images, challenging the use of frequency domain analysis. In this study, a computationally efficient method using a generalized divergence regularization procedure is presented to suppress speckle noise in EV-OCT images. Results show substantial smoothing of the grainy appearance and enhanced visualization of deeper structures as demonstrated in porcine carotid arteries. 相似文献
105.
Patrick Homenya Markus Messerschmidt Muhammad Nawaz Tahir Victor Martinez Yajun Cheng Jochen S. Gutmann Michael Klein Stefan Jung Morris Wolff Reza Saadat Driss Nariaki Roman Bo?a G?star Klingelh?fer Wolfgang Tremel Franz Renz 《Hyperfine Interactions》2012,205(1-3):63-67
The nonanuclear coordination compound [MoIV{(CN)FeIII(3-methyl-saldptn)}8]Cl4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. M?ssbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e.g. in the field of information storage) was laid. 相似文献
106.
The existence of quantum spin liquids was first conjectured by Pomeranchuk some 70 years ago, who argued that frustration in simple antiferromagnetic theories could result in a Fermi-liquid-like state for spinon excitations. Here we show that a simple quantum spin model on a honeycomb lattice hosts the long sought for Bose metal with a clearly identifiable Bose surface. The complete phase diagram of the model is determined via exact diagonalization and is shown to include four distinct phases separated by three quantum phase transitions. 相似文献
107.
Victor A. Soltamov Ivan V. Ilyin Alexandra A. Soltamova Daniel O. Tolmachev Nikolai G. Romanov Alexandr S. Gurin Vladimir A. Khramtsov Eugene N. Mokhov Yurii N. Makarov Georgy V. Mamin Sergei B. Orlinskii Pavel G. Baranov 《Applied magnetic resonance》2013,44(10):1139-1165
The results of studies of shallow donors and deep-level color centers in bulk AlN crystals are presented. Two shallow donors (presumably oxygen located on the nitrogen site and carbon located on the aluminum site) are suggested to exhibit the DX-relaxation. Third shallow donor (presumably silicon on the Al site) shows the shallow donor behavior up to the room temperature and can be observed without light excitation at temperatures above 200 K. The values of the Bohr radius of the shallow donors are estimated. The structure of deep-level color centers (neutral nitrogen vacancy V N) in bulk AlN crystals is determined and analyzed by electron paramagnetic resonance, electron-nuclear double resonance, optical absorption and thermoluminescence induced by X-ray irradiation. Spin-dependent recombination processes in AlN crystals are studied by means of optically detected magnetic resonance. 相似文献
108.
LetV() be a smooth, non-constant function on the torus and letT be a hyperbolic toral automorphism. Consider a discrete one dimensional Schrödinger operatorH, whose potential at sitej is given bygV
j
=gV(T
j
). We prove that wheng0 is small andg
1/2
|E|2–g
1/2
, the Lyapunov exponent for the cocycle generated byH-E is proportional tog
2. The proof relies on a formula of Pastur and Figotin and on symbolic dynamics. 相似文献
109.
We formulate general conjectures about the relationship between the A-model connection on the cohomology of ad-dimensional Calabi-Yau complete intersectionV ofr hypersurfacesV
1
,...,V
r
in a toric varietyP
and the system of differential operators annihilating the special generalized hypergeometric series 0 constructed from the fan . Using this generalized hypergeometric series, we propose conjectural mirrorsV ofV and the canonicalq-coordinates on the moduli spaces of Calabi-Yau manifolds.In the second part of the paper we consider some examples of Calabi-Yau 3-folds having Picard number >1 in products of projective spaces. For conjectural mirrors, using the recurrent relation among coefficients of the restriction of the hypergeometric function 0 on a special line in the moduli space, we determine the Picard-Fuchs equation satisfied by periods of this special one-parameter subfamily. This allows to obtain some sequences of integers which can be conjecturally interpreted in terms of Gromov-Witten invariants. Using standard techniques from enumerative geometry, first terms of these sequence of integers are checked to coincide with numbers of rational curves on Calabi-Yau 3-folds. 相似文献
110.
Local structure theory calculations7 are applied to the study of cellular automata on the two-dimensional hexagonal lattice. A particular hexagonal lattice rule denoted (3422) is considered in detail. This rule has many features in common with Conway'sLife. The local structure theory captures many of the statistical properties of this rule; this supports hypotheses raised by a study ofLife itself(6). As inLife, the state of a cell under (3422) depends only on the state of the cell itself and the sum of states in its neighborhood at the previous time step. This property implies that evolution rules which operate in the same way can be studied on different lattices. The differences between the behavior of these rules on different lattices are dramatic. The mean field theory cannot reflect these differences. However, a generalization of the mean field theory, the local structure theory, does account for the rule-lattice interaction. 相似文献