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11.
12.
There is a need to develop broadly applicable, highly sensitive detection methods for microchip CE that do not require analyte derivatization. LIF is highly sensitive but typically requires analyte derivatization. Electrochemistry provides an alternative method for direct analyte detection; however, in its most common form, direct current (DC) amperometry, it is limited to a small number of easily oxidizable or reducible analytes. Pulsed amperometric detection (PAD) is an alternative waveform that can increase the number of electrochemically detectable analytes. Increasing sensitivity for electrochemical detection (EC) and PAD requires the isolation of detection current (nA) from the separation current (muA) in a process generally referred to as current decoupling. Here, we present the development of a simple integrated decoupler to improve sensitivity and its coupling with PAD. A Pd microwire is used as the cathode for decoupling and a second Au or Pt wire is used as the working electrode for either EC or PAD. The electrode system is easy to make, requiring no clean-room facilities or specialized metallization systems. Sensitive detection of a wide range of analytes is shown to be possible using this system. Using this system we were able to achieve detection limits as low as 5 nM for dopamine, 74 nM for glutathione, and 100 nM for glucose. 相似文献
13.
Nonlinear Dynamics, Psychology, and Life Sciences - 相似文献
14.
By subtly varying crystallization conditions, four distinct cadmium acetate coordination networks with unit cell formulas Cd(87)(H(2)O)(36)(EtOH)(18)(OH)(12)(CH(3)CO(2))(162) (1), Cd(87)(H(2)O)(72)(OH)(12)(CH(3)CO(2))(162) (2), Cd(10)(H(2)O)(6)(OH)(2)(CH(3)CO(2))(18) (3), and Cd(20)(H(2)O)(20)(OH)(4)(CH(3)CO(2))(36) (4) have been isolated. The coordination networks exhibit interesting structural diversity and have been investigated by powder X-ray diffraction, elemental analysis, thermal gravimetric analysis, infrared spectroscopy, and single-crystal X-ray diffraction. All four complexes are composed of secondary building units with the general formula [Cd(4)(OAc)(9)(μ(3)-OH)](2-). Complexes 1 and 2 exhibit a remarkable three-dimensional network composed of aligned columns, each 4.5 nm long, containing three different cadmium acetate clusters. Complexes 3 and 4 extend in two-dimensions with each unit cell repeating a different linkage isomer of the [Cd(4)(OAc)(9)(μ(3)-OH)](2-) cluster. 相似文献
15.
Valerie Belton Stephen P. Vickers 《The Journal of the Operational Research Society》1993,44(9):883-896
Both Data Envelopment Analysis (DEA) and Multiple Criteria Analysis (MCA) can be used to assess the efficiency with which units perform similar tasks. This paper describes an approach derived from the integration of data envelopment analysis and a multi-attribute value function. This approach is implemented as a visual interactive decision support system, the use of which is illustrated by a practical application. The authors feel that this approach overcomes some of the limitations of the original DEA approach and, in particular, increases users' understanding of DEA. The approach is particularly well suited to the analysis of the efficiency of a small number of units. 相似文献
16.
A. J. Vickers S. Alleston R. Gupta P. O. Müller D. Erasme 《Optical and Quantum Electronics》1996,28(7):983-989
A model is presented which determines the output from a semiconductor laser as a function of the direct current (d.c.) and radio frequency (r.f.) current applied to the laser. It is shown that by adjusting these two components the output optical pulse from a laser can be shifted in time without change to the pulse shape or height. Experimental results are presented which support the model. It is suggested how these results can be used to produce a semiconductor pump-probe source, which is essential for the development of optical probing. 相似文献
17.
Time-resolved fluorescence measurements are made with an optical-fiber probe approximately 16 m long. Fluorescence lifetimes for 1.00 μM solutions of rhodamine-B and rose bengal in ethanol were found to be 2.78 ± 0.04 ns and 0.77 ± 0.07 ns, respectively, similarin accuracy and precision to values obtained with conventional techniques. Calculations are used to investigate the limitations in remote determinations caused by temporal broadening. Results indicate that fiber lengths approaching 1 km can be used without significant loss in accuracy or precision. 相似文献
18.
Douglas McHugh Sherry SJ Hu Neta Rimmerman Ana Juknat Zvi Vogel J Michael Walker Heather B Bradshaw 《BMC neuroscience》2010,11(1):44
Background
Microglia provide continuous immune surveillance of the CNS and upon activation rapidly change phenotype to express receptors that respond to chemoattractants during CNS damage or infection. These activated microglia undergo directed migration towards affected tissue. Importantly, the molecular species of chemoattractant encountered determines if microglia respond with pro- or anti-inflammatory behaviour, yet the signaling molecules that trigger migration remain poorly understood. The endogenous cannabinoid system regulates microglial migration via CB2 receptors and an as yet unidentified GPCR termed the 'abnormal cannabidiol' (Abn-CBD) receptor. Abn-CBD is a synthetic isomer of the phytocannabinoid cannabidiol (CBD) and is inactive at CB1 or CB2 receptors, but functions as a selective agonist at this Gi/o-coupled GPCR. N-arachidonoyl glycine (NAGly) is an endogenous metabolite of the endocannabinoid anandamide and acts as an efficacious agonist at GPR18. Here, we investigate the relationship between NAGly, Abn-CBD, the unidentified 'Abn-CBD' receptor, GPR18, and BV-2 microglial migration. 相似文献19.
Shan N Ingram JD Easun TL Vickers SJ Adams H Ward MD Thomas JA 《Dalton transactions (Cambridge, England : 2003)》2006,(23):2900-2906
Using a [Ru(II)([9]aneS3)] templating moiety, kinetically-locked, metallomacrocycles incorporating adenine based ligands have been synthesised through self-assembly. The kinetically robust nature of these structures is confirmed by electrochemical studies: each can be reversibly oxidised in a four-member redox series, containing two formally mixed valence states. Unusually, the electrochemically derived comproportionation constants for these mixed valence states are very different, suggesting that intermetallic coupling differs between the two states. Spectroelectochemistry studies confirm that while the [Ru(II)2Ru(III)] state is valence localised, the [Ru(II)Ru(III)2] state is electronically delocalised. Mechanisms by which this switching effect could occur, which involve the unusual connectivities in these mixed valence species, are presented. 相似文献
20.
M. Henini P. A. Crump P. J. Rodgers B. L. Gallagher A. J. Vickers G. Hill 《Journal of Crystal Growth》1995,150(1-4):446-450
We report on a series of Be-doped GaAs/AlGaAs two-dimensional hole gas (2DHG) structures grown on (110), (111)B, (211)B and (311)B oriented substrates and compare their properties with high-mobility samples grown on (311)A using Si doping. The samples were prepared and grown under the same conditions so as to render them comparable. They are found to have mobilities which are strongly anisotropic within the plane. The highest mobility is found on the (110) surface with 100,000 cm2 V−1 s−1, while the (211) surface gave the lowest values 10,000 cm2 V−1 s−1. However, the later samples are found to have quantum Hall effect critical currents of >70 μA: an exceptionally high value for a hole gas which makes them suitable for metrology. All the samples show strong low-field positive magnetoresistance with resistance increases of up to 30% at magnetic fields of only 0.1 T. The presence of this feature on all the different planes shows that it does not depend upon the details of the band structure. It is identified with the lifting of the degeneracy of the spin sub-bands by the asymmetrical potential giving rise to a classical two-band magnetoreresistance. 相似文献