Determination of the Effective Probabilities of Catalytic Reactions on the Surfaces of Heat Shield Materials in Dissociated Carbon Dioxide Flows

The effect of heterogeneous catalysis on the heat transfer to cold and heated surfaces in subsonic dissociated carbon dioxide jet flows is studied experimentally, using a 100 kW inductive plasma generator, and simulated numerically. The effective probabilities of the heterogeneous reactions CO + O → CO₂ and O + O → O₂ on molybdenum (T_w=300 K) and quartz (T_w=470–620 K) surfaces, the Buran heat shield tile coating (T_w = 1470—1670 K), and two oxidation-resistant carbon-carbon coating materials (T_w=1420—1840 K) are determined by comparing the experimental and calculated data on the heat fluxes at the stagnation point of models at a pressure of 0.1 atm.     

HF-plasmatron experiment and numerical simulation of heat transfer in underexpanded dissociated-nitrogen jets

Experiments on heat transfer in underexpanded supersonic jets of high-enthalpy nitrogen are performed on the VGU-4 induction high-frequency plasmatron at a pressure of 10.4 GPa in a compression chamber. At gas flow rates of 2.4 and 3.6 g/s and HF generator powers of 45 and 64 kW the heat fluxes to the copper, stainless steel, MPG-7 graphite, and quartz surfaces are measured at the stagnation point of a water-cooled cylindrical, flat-ended model, 20 mm in diameter. In the same regimes the stagnation pressures are measured. The effect of the surface catalyticity with respect to nitrogen atom recombination on the heat flux is demonstrated and the qualitative catalyticity scale of the studied materials is established. In the supersonic regimes nonequilibrium nitrogen plasma flow in the discharge channel of the plasmatron and the underexpanded jet flow past the model are numerically simulated for the experimental conditions. The experimental and calculated data on the stagnation pressures and the heat fluxes to cooled surfaces of the metals, graphite, and quartz are compared.     

Subgroups of a finite group whose algebra of invariants is a complete intersection

Let G be a finite subgroup of GL(V), where V is a finite-dimensional vector space over the field K and char KG. We show that if the algebra of invariants K(V)^G of the symmetric algebra of V is a complete intersection then K(V)^H is also a complete intersection for all subgroups H of G such that H={ Gv (v)=v for all v V^H}.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im. V. A. Steklova AN SSSR, Vol. 116, pp. 63–67, 1982.     

Bandgap widening of titania through semiconductor support interactions.

Silica-supported titania powders with 50, 36, 13 and 4 wt% of TiO2 (TiO2-50/SiO2, TiO2-36/SiO2, TiO2-13/SiO2 and TiO2-4/SiO2) were prepared by hydrolysis of TiCl4 in the presence of silica, followed by calcination at 500 degrees C. The formation of Ti-O-Si linkages was confirmed by diffuse reflectance infrared Fourier transform spectroscopy. Atomic force microscopy indicated the presence of titania crystals larger than 15 nm. All supported materials exhibited a blue-shift of the TiO2 absorption edge, which was attributed to an electronic semiconductor support interaction. Bandgap energies of TiO2-50/SiO2, TiO2-36/SiO2, TiO2-13/SiO2 and TiO(2)4/SiO2 were measured to be 3.28, 3.36, 3.40 and 3.42 eV, respectively, as compared to 3.15 eV for unsupported TiO2. From these values, and from the quasi-Fermi level of electrons, a high anodic shift of both the valence and the conduction band was estimated. X-ray photoelectron spectroscopy (XPS) measurements of oxygen 1s- and titanium 2p-binding energies confirmed the anodic shift of the band edges.     

Fatty acid composition of the main phospholipids of the Antarctic krill Euphausia superba

The Antarctic krillEuphausia superba Dana contains about 5% of its natural weight of extractable lipids, more than half of which are in the form of phospholipids — phosphatidylcholine (33–36% of the sum of the lipids), phosphatidylethanolamine (15–17%), lysophosphatidylcholine (3–4%), and others (2–3%) — while among the phosphorus-free components triacylglycerols predominate (32–35%). In the first two phospholipids the dominating fatty acid residue is the arachidonic acid residue (more than 40% of the sum of the acyl residues) and the amounts of residues of eicosapentaenoic acid (C_{20 : 5w3}) are about 13 and 28%, respectively. A simple procedure for isolating the phosphatidylcholine and phosphatidylethanolamine is proposed. For the analysis of the fatty acid a new method was used, consisting of the HPLC of their (7-diethylaminocoumarin-4-yl)hydrazides, with fluorometric detection.Scientific Research Laboratory of Biologically Active Substances of Hydrobionts, USSR Ministry of Health, Moscow. K. A. Timiryazev Moscow Agricultural Academy. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 181–187, March–April, 1990.     

Ring functionalization of cyclosiloxanes using electrochemically generated diorganyl silanones

Cathodic reduction of oxygen in the presence of dichloro- or dialkoxydiorganylsilanes R¹R²SiX₂ (X = Cl,OAlk) provides highly reactive intermediates, supposedly diorganyl silanones R¹R²Si=O, which readily react with cyclicpermethylsiloxanes (hexamethylcyclotrisiloxane D₃ and octamethylcyclotetrasiloxane D₄) to form ring-extended products bearing an additional R¹R²SiO fragment. In this way, various groups can beincorporated into the siloxanes framework: Ph, vinyl (Vi), Alk, OAlk, H and substituted alkyls. The process is more selective at low temperature (T ?–10°C) and when using dialkoxysilanes as starting compounds. The electrochemical activation of dichloro- and dialkoxysilanes for the reaction with siloxanes provides an alternative way to prepare functional cyclosiloxanes.     

Quantum chemical study of nickel(II) complexes with cyclic diimine ligands on the base of bis[3,3′-iminopropyl]methylamine

A quantum chemical study of spatial and electronic structures of molecules in the frame complexes, bis[3,3′(RR′)-ketiminepropyl]methylamine nickel dichlorides, where R = H, CH₃, and R′ = H, CH₃, has been performed by DFT(B3LYP/LANL2DZ) method. The molecules of these complexes were found to be in a triplet state. Energy stability of the endo form of the complex molecules was shown. In the molecule of bis[3,3′-aldiminopropyl]methylamine nickel dichloride (R = R′ = H), a considerable strengthening of the bond Ni-N(amine) takes place when passing from the diamagnetic into paramagnetic state, and all bonds Ni-N become equivalent with respect to interatomic distance values. The topology analysis of the electron density for the complexes with R = R′ =H and R = R′ = CH₃ was carried out. It is stated that all Ni-N bonds are covalent in the molecules of paramagnetic complexes.     

On fractal nature of the structure of nanoporous carbon obtained from carbides

The curves describing small-angle x-ray scattering at npor-C nanoporous carbon samples obtained from polycrystalline α-SiC, TiC, and Mo₂C and a 6H-SiC single crystal have been analyzed. An algorithm is developed for taking into account the corrections to experimental curves for the intensity of the primary beam transmitted through the sample and the height of the inlet slit in these measurements. Two systems of nanoclusters observed in the npor-C structure differ in the type of stacking of structural elements: small-scale mass fractals of a dimension 1<D ₂<3 and a size L ₂=50–90 Å, which depend on the type of the initial carbide, and large-scale nanoclusters having a size L ₁>550 Å. In most samples, large-scale nanoclusters can be regarded as objects with a fractal surface and a dimension 2<D ₁<13, which also depends on the type of the initial carbide. Large-scale nanoclusters in npor-C obtained from Mo₂C prove to be mass fractals with a dimension D ₁>2. Peculiarities of the structure formation of nanoporous carbon obtained from various carbides are discussed.     

Halves of a real Enriques surface

The real partE _ℝ of a real Enriques surfaceE admits a natural decomposition in two halves,E _ℝ=E _ℝ ⁽¹⁾ ∪E _ℝ ⁽²⁾ , each half being a union of components ofE _ℝ. We classify the triads (E _ℝ;E _ℝ ⁽¹⁾ ,E _ℝ ⁽²⁾ ) up to homeomorphism. Most results extend to surfaces of more general nature than Enriques surfaces. We use and study in details the properties of Kalinin's filtration in the homology of the fixed point set of an involution, which is a convenient tool not widely known in topology of real algebraic varieties.