全文获取类型
收费全文 | 101篇 |
免费 | 1篇 |
专业分类
化学 | 57篇 |
数学 | 17篇 |
物理学 | 28篇 |
出版年
2023年 | 4篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 3篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 5篇 |
2012年 | 7篇 |
2011年 | 3篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 2篇 |
2007年 | 4篇 |
2006年 | 5篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1972年 | 6篇 |
1971年 | 4篇 |
1970年 | 3篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 2篇 |
1966年 | 3篇 |
1964年 | 1篇 |
1963年 | 2篇 |
1962年 | 2篇 |
1961年 | 1篇 |
1960年 | 2篇 |
1958年 | 1篇 |
1934年 | 1篇 |
排序方式: 共有102条查询结果,搜索用时 38 毫秒
1.
The density of neutral oxygen atoms in the MESOX set-up, one device of the PROMES-CNRS solar facilities, was determined by a fiber-optics catalytic probe (FOCP). Plasma was created in a flowing air within a quartz tube with the outer diameter of 5 cm by a 2.45 GHz microwave generator with the output power up to 1000 W. The flow of air was varied between 4 and 20 l/h. The O-atom density was found to increase monotonously with the increasing discharge power, and it decreased with the increasing flow rate. The degree of dissociation of oxygen molecules in the plasma column depended largely on the flow rate. At the air flow of 4 l/h it was about 80% but it decreased to about 20% at the flow of 20 l/h. 相似文献
2.
A new method for the determination of nickel in the presence of cobalt, based on the masking of the cobalt with potassium cyanide and hydrogen peroxide, is proposed. The yellow, or orange-yellow, complex of cobalt(III) is formed, from which cobalt is not displaced upon the addition of silver nitrate. Tetracyanonickelate, however, reacts quantitatively with silver nitrate, and the displaced nickel can be determined directly with EDTA, using Murexide as indicator. Up to 30 mg of cobalt can be tolerated in the solution. 相似文献
3.
Liping Liao Bing Wu Dr. Evgeniya Kovalska Dr. Vlastimil Mazánek Dr. Martin Veselý Ivo Marek Lucie Spejchalová Prof. Dr. Zdeněk Sofer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(52):13235-13241
The intercalation of cations into layered-structure electrode materials has long been studied in depth for energy storage applications. In particular, Li+-, Na+-, and K+-based cation transport in energy storage devices such as batteries and electrochemical capacitors is closely related to the capacitance behavior. We have exploited different sizes of cations from aqueous salt electrolytes intercalating into a layered Nb2CTx electrode in a supercapacitor for the first time. As a result, we have demonstrated that capacitive performance was dependent on cation intercalation behavior. The interlayer spacing expansion of the electrode material can be observed in Li2SO4, Na2SO4, and K2SO4 electrolytes with d-spacing. Additionally, our results showed that the Nb2CTx electrode exhibited higher electrochemical performance in the presence of Li2SO4 than in that of Na2SO4 and K2SO4. This is partly because the smaller-sized Li+ transports quickly and intercalates between the layers of Nb2CTx easily. Poor ion transport in the Na2SO4 electrolyte limited the electrode capacitance and presented the lowest electrochemical performance, although the cation radius follows Li+>Na+>K+. Our experimental studies provide direct evidence for the intercalation mechanism of Li+, Na+, and K+ on the 2D layered Nb2CTx electrode, which provides a new path for exploring the relationship between intercalated cations and other MXene electrodes. 相似文献
4.
Milan Jakubek Zdeněk Kejík Robert Kaplánek Hana Veselá David Sýkora Pavel Martásek 《Supramolecular chemistry》2018,30(3):218-226
Perimidine-based chelators 1 and 2 were prepared, and their structures were confirmed by 1H and 13C NMR, MS spectroscopy and elemental analysis. These compounds were studied as specific synthetic receptors for the recognition of transition metal ions. They exhibited high affinity and selectivity towards Cu(II) ions. The conditional binding constants, linear dynamic range and detection limit were determined by UV–vis spectroscopy. These parameters demonstrated high potential of the prepared synthetic receptors for the recognition and determination of Cu(II) ions. The minimum detectable concentrations of Cu(II) ions for the synthetic receptors 1 and 2 were 270 and 75 nM (R 2 = 0.9915 and 0.9964) in aqueous medium (water/DMSO; 99:1 (v/v)), respectively. 相似文献
5.
M. Šícha V. Veselý J. Studnička J. Prostějovský M. Novák 《Czechoslovak Journal of Physics》1962,12(12):919-929
Zusammenfassung Es wurde ein Verfahren zur Erregung von stationären Schichten, der Schichtungswelle und der laufenden Schichten in der Gleichstromentladung ausgearbeitet, das auf der Einwirkung eines Hochfrequenzfeldes auf einen kurzen Abschnitt der positiven Säule beruht. Dieses Verfahren wurde zum Studium aller drei angeführten Schichtungsarten in Neon benützt, insbesondere jedoch zum Studium des Zusammenhanges zwischen den laufenden und den stationären Schichten.Bei stationären Schichten wurden zweifache Strukturen festgestellt und es wurde deren Abhängigkeit vom Entladungsstrom und von der Größe des erregenden Hochfrequenzfeldes verfolgt.Bei der Schichtungswelle wurde die Stelle deren Entstehung ermittelt und es wurde nachgewiesen, daß das Hochfrequenzfeld diese Welle lokal an der Stelle dessen Einwirkung auf die positive Säule hervorruft.Bei den laufenden Schichten wurde deren Resonanzfrequenz in Abhängigkeit vom Entladungsstrom und die Abhängigkeit der Wellenlänge der Schichten von der Frequenz untersucht.Es wurde festgestellt, daß der extrapolierte Wert der Wellenlänge für die Nullfrequenz erheblich niedriger ist als die Länge der stationären Schichten. Weiter wurde eine Übereinstimmung der Frequenz der laufenden Schichten in der Schichtungswelle mit der Resonanzfrequenz der künstlich hervorgerufenen laufenden Schichten festgestellt.
, , . , . . , . . , . , .相似文献
6.
Surface analysis of ripple pattern on PS and PEN induced with ring‐shaped mask due to KrF laser treatment 下载免费PDF全文
O. Neděla P. Slepička P. Sajdl M. Veselý V. Švorčík 《Surface and interface analysis : SIA》2017,49(1):25-33
The approach for ripple nanopattern construction on surface of two polymer substrates [polyethylene naphthalate (PEN) and polystyrene (PS)] exposed by a KrF pulse excimer UV laser through a contact lithographic mask with circular slit was proposed in this paper. Thin layer of gold was deposited on samples after the laser treatment. Changes in the morphology of the surface of both the shielded and exposed areas of the substrates, as well as the dimensions of the laser‐induced periodic surface structures, were determined (by atomic force microscopy, laser confocal microscopy and scanning electron microscopy), compared with observations and measurements made on samples treated directly (without a contact mask) under the same conditions. The morphology of the interface between the treated and untreated regions was also closely studied. Surface chemistry of treated samples was studied in detail by X‐ray Photoelectron Spectroscopy. The detailed study of surface chemistry of modified PEN and PS revealed a significant increase of oxygen concentration for laser treated PS and increase of carboxyl groups in case of PEN. The potential application of this research can be found in biotechnology, micro technology and several other fields. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
7.
Dr. Martin Kamlar Dr. Ivana Císařová Prof. Jan Veselý 《European journal of organic chemistry》2023,26(32):e202300400
We report a Brønsted acid-catalyzed synthesis of tetrasubstituted allenyl compounds decorated with heterocyclic sulfenyl group. The reaction proceeds readily from available propargylic alcohols in the presence of pentacarboxycyclopenatadienes (PCCPs) as organocatalysts. The developed strategy provides tetrasubstituted allene derivatives in high yields (from 55 to 98 %) and under mild reaction conditions. 相似文献
8.
A review of the developments during the period 1965-70 in use of heteropoly acid salts, ferrocyanides and synthetic zeolites as ion-exchangers. 相似文献
9.
Libor Veselý 《Czechoslovak Mathematical Journal》2002,52(4):721-729
We give a full characterization of the closed one-codimensional subspaces of c
0, in which every bounded set has a Chebyshev center. It turns out that one can consider equivalently only finite sets (even only three-point sets) in our case, but not in general. Such hyperplanes are exactly those which are either proximinal or norm-one complemented. 相似文献
10.
The diffusion ot Ti atoms in the Ni77Si3B20 metallic glass was studied by the Auger electron spectroscopy. The temperature dependence of the diffusion coefficient obeys the Arrhenius relation with the activation energyE=1·7 eV and the pre-exponential factorD
0=0·86 × ×10–4 m2 s–1. Possible mechanisms of the atomic transport in metallic glasses are discussedThe authors wish to thank Dr. P. Duhaj for providing the metallic glass samples. 相似文献