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排序方式: 共有236条查询结果,搜索用时 15 毫秒
31.
Neaţu F Li Z Richards R Toullec PY Genêt JP Dumbuya K Gottfried JM Steinrück HP Pârvulescu VI Michelet V 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(30):9412-9418
A novel class of heterogeneous gold catalysts supported on zeolite beta-NH4+ was prepared by the deposition-precipitation method. This new class of catalyst showed interesting catalytic activities for the intramolecular cycloisomerization of gamma-acetylenic carboxylic acids leading to functionalized gamma-alkylidene gamma-butyrolactones. Analysis of the supported gold species with in situ X-ray photoelectron spectroscopy (in situ XPS) suggests that cationic Au (possibly AuIII) can play an important role in such reactions. The high discrepancy in catalyst stability in favor of the Au supported on the zeolite system over bulk Au2O3 is explained by 1) the size of the particles and 2) the reversibility of the redox deactivating process (AuIII-->AuI) in the presence of oxygen for the supported system. The efficiency of this system allowed reaction under mild heterogeneous conditions. The potential for catalyst recycling was also highlighted. 相似文献
32.
Since its introduction in the nineties, the negative resist SU-8 has been increasingly used in micro- and nanotechnologies. SU-8 has made the fabrication of high-aspect ratio structures accessible to labs with no high-end facilities such as X-ray lithography systems or deep reactive ion etching systems. These low-cost techniques have been applied not only in the fabrication of metallic parts or molds, but also in numerous other micromachining processes. Its ease of use has made SU-8 to be used in many applications, even when high-aspect ratios are not required. Beyond these pattern transfer applications, SU-8 has been used directly as a structural material for microelectromechanical systems and microfluidics due to its properties such as its excellent chemical resistance or the low Young modulus. In contrast to conventional resists, which are used temporally, SU-8 has been used as a permanent building material to fabricate microcomponents such as cantilevers, membranes, and microchannels. SU-8-based techniques have led to new low-temperature processes suitable for the fabrication of a wide range of objects, from the single component to the complete lab-on-chip. First, this article aims to review the different techniques and provides guidelines to the use of SU-8 as a structural material. Second, practical examples from our respective labs are presented. 相似文献
33.
34.
Tang S Monot J El-Hellani A Michelet B Guillot R Bour C Gandon V 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(33):10239-10243
Ga-neration X: Well-defined neutral and cationic gallium(III) halide complexes have been synthesized and evaluated in catalysis. Both the (NHC)GaX(3) /AgSbF(6) catalytic mixture and isolated (NHC)GaX(2) (+) species function as exquisite π-Lewis acids in typical GaX(3) -catalyzed reactions. The cationic complexes are more active than GaX(3) and yet more resistant to hydrolysis, which allows lower catalytic loadings and faster reactions. 相似文献
35.
Montaignac B Praveen C Vitale MR Michelet V Ratovelomanana-Vidal V 《Chemical communications (Cambridge, England)》2012,48(52):6559-6561
Enantioselective metallo-organocatalyzed carbocyclizations of formyl-alkynes have been developed. The cooperation between aminocatalysis and a chiral copper(I) complex granted access to enantio-enriched cyclopentanes through the challenging formation of all-carbon quaternary stereocenters. 相似文献
36.
Isabelle Hladezuk Veronique Chastagner Stuart G. Collins Stephen J. Plunkett Alan Ford Sebastien Debarge Anita R. Maguire 《Tetrahedron》2012,68(7):1894-1909
Development of rhodium catalysed O–H insertion reactions employing α-diazophosphonates with appropriately protected adenosine, uridine and thymidine derivatives is described. This synthetic methodology leads, following deprotection, to novel phosphononucleoside derivatives bearing a carboxylic acid moiety adjacent to the phosphonate. Protection strategies are critical to the success of the key O–H insertion. There are two important aspects: avoiding competing insertion pathways or catalyst poisoning, and being able to achieve deprotection without degradation of the phosphononucleosides. 相似文献
37.
Nucleophile‐Dependent Regio‐ and Stereoselective Ring Opening of 1‐Azoniabicyclo[3.1.0]hexane Tosylate 下载免费PDF全文
Mi‐Kyung Ji Dietmar Hertsen Doo‐Ha Yoon Heesung Eum Hannelore Goossens Prof. Dr. Michel Waroquier Prof. Dr. Veronique Van Speybroeck Prof. Dr. Matthias D'hooghe Prof. Dr. Norbert De Kimpe Prof. Dr. Hyun‐Joon Ha 《化学:亚洲杂志》2014,9(4):1060-1067
1‐[(1R)‐(1‐Phenylethyl)]‐1‐azoniabicyclo[3.1.0]hexane tosylate was generated as a stable bicyclic aziridinium salt from the corresponding 2‐(3‐hydroxypropyl)aziridine upon reaction with p‐toluenesulfonyl anhydride. This bicyclic aziridinium ion was then treated with various nucleophiles including halides, azide, acetate, and cyanide in CH3CN to afford either piperidines or pyrrolidines through regio‐ and stereoselective ring opening, mediated by the characteristics of the applied nucleophile. On the basis of DFT calculations, ring‐opening reactions under thermodynamic control yield piperidines, whereas reactions under kinetic control can yield both piperidines and pyrrolidines depending on the activation energies for both pathways. 相似文献
38.
Dr. Valérie Alain‐Rizzo Delphine Drouin‐Kucma Cédric Rouxel Dr. Issa Samb Jérémy Bell Dr. Patrick Y. Toullec Dr. Véronique Michelet Dr. Isabelle Leray Dr. Mireille Blanchard‐Desce 《化学:亚洲杂志》2011,6(4):1080-1091
A series of rod‐shaped and related three‐branched push–pull derivatives containing phosphane oxide or phosphane sulfide (PO or PS)—as an electron‐withdrawing group conjugated to electron‐donating groups, such as amino or ether groups, with a conjugated rod consisting of arylene–vinylene or arylene–ethynylene building blocks—were prepared. These compounds were efficiently synthesized by a Grignard reaction followed by Sonogashira coupling. Their photophysical properties including absorption, emission, time‐resolved fluorescence, and two‐photon absorption (TPA) were investigated with special attention to structure–property relationships. These fluorophores show high fluorescence quantum yields and solvent‐dependent experiments reveal that efficient intramolecular charge transfer occurs upon excitation, thereby leading to highly polar excited states, the polarity of which can be significantly enhanced by playing on the end groups and conjugated linker. Rod‐shaped and related three‐branched systems show similar fluorescence properties in agreement with excitation localization on one of the push–pull branches. By using stronger electron donors or replacing the arylene–ethynylene linkers with an arylene–vinylene one induces significant redshifts of both the low‐energy one‐photon absorption and TPA bands. Interestingly, a major enhancement in TPA responses is observed, whereas OPA intensities are only weakly affected. Similarly, phosphane oxide derivatives show similar OPA responses than the corresponding sulfides but their TPA responses are significantly larger. Finally, the electronic coupling between dipolar branches promoted by common PO or PS acceptor moieties induces either slight enhancement of the TPA responses or broadening of the TPA band in the near infrared (NIR) region. Such behavior markedly contrasts with triphenylamine‐core‐mediated coupling, which gives evidence for the different types of interactions between branches. 相似文献
39.
Emeline Appert Dr. Agnès Martin-Mingot Dr. Omar Karam Dr. Fabien Zunino Dr. Bastien Michelet Dr. Fodil Bouazza Prof. Sébastien Thibaudeau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(49):e202201583
The field of medicinal chemistry is currently witnessing a deuterium rush owing to the remarkable properties of this element as bioisoster of hydrogen atom. Aromatic hydrogen isotope exchange (HIE) is one of the most studied strategies nowadays as it promises to access deuterium-modified drugs directly from their non-labeled parents. While most of the recent studies focus on metal-catalyzed C−H activation strategy, the use of superacidic conditions has been largely overlooked. This study shows that the use of TfOD as reaction medium allows the late-stage polydeuteration of a broad library of pharmaceuticals bearing a wide array of functional groups, complementing existing procedures. 相似文献
40.
Super-Oxidizing Covalent Triazine Framework Electrocatalyst for Two-Electron Water Oxidation to H2O2
Ruqia Khan Dr. Jeet Chakraborty Dr. Kuber Singh Rawat Prof. Rino Morent Prof. Nathalie De Geyter Prof. Veronique Van Speybroeck Prof. Pascal Van Der Voort 《Angewandte Chemie (International ed. in English)》2023,62(47):e202313836
Electrochemical two-electron water oxidation (2e WOR) is gaining surging research traction for sustainable hydrogen peroxide production. However, the strong oxidizing environment and thermodynamically competitive side-reaction (4e WOR) posit as thresholds for the 2e WOR. We herein report a custom-crafted covalent triazine network possessing strong oxidizing properties as a proof-of-concept metal-free functional organic network electrocatalyst for catalyzing 2e WOR. As the first-of-its-kind, the material shows a maximum of 89.9 % Faradaic Efficiency and 1428 μmol/h/cm2 H2O2 production rate at 3.0 V bias potential (vs reversible hydrogen electrode, RHE), which are either better or comparable to the state-of-the-art electrocatalysts. We have experimentally confirmed a stepwise 2e WOR mechanism which was further computationally endorsed by density functional theory studies. 相似文献