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41.
Dr. Amit A. Vernekar Tandrila Das Sourav Ghosh Prof. Dr. Govindasamy Mugesh 《化学:亚洲杂志》2016,11(1):72-76
Nanomaterials‐based enzyme mimetics (nanozymes) have attracted considerable interest due to their applications in imaging, diagnostics, and therapeutic treatments. Particularly, metal‐oxide nanozymes have been shown to mimic the interesting redox properties and biological activities of metalloenzymes. Here we describe an efficient synthesis of MnFe2O4 nanomaterials and show how the morphology can be controlled by using a simple co‐precipitation method. The nanomaterials prepared by this method exhibit a remarkable oxidase‐like activity. Interestingly, the activity is morphology‐dependent, with nanooctahedra (NOh) exhibiting a catalytic efficiency of 2.21×109 m ?1 s?1, the highest activity ever reported for a nanozyme. 相似文献
42.
Amit A. Vernekar Prof. Dr. Govindasamy Mugesh 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(47):15122-15132
Facile and efficient reduction of graphene oxide (GO) and novel applications of the reduced graphene oxide (RGO) based materials are of current interest. Herein, we report a novel and facile method for the reduction of GO by using a biocompatible reducing agent dithiothreitol (DTT). Stabilization of DTT by the formation of a six‐membered ring with internal disulfide linkage upon oxidation is responsible for the reduction of GO. The reduced graphene oxide is characterized by several spectroscopic and microscopic techniques. Dispersion of RGO in DMF remained stable for several weeks suggesting that the RGO obtained by DTT‐mediated reduction is hydrophobic in nature. This method can be considered for large scale production of good quality RGO. Treatment of RGO with hemin afforded a functional hemin‐reduced graphene oxide (H‐RGO) hybrid material that exhibited remarkable protective effects against the potentially harmful peroxynitrite (PN). A detailed inhibition study on PN‐mediated oxidation and nitration reactions indicate that the interaction between hemin and RGO results in a synergistic effect, which leads to an efficient reduction of PN to nitrate. The RGO also catalyzes the isomerization of PN to nitrate as the RGO layers facilitate the rapid recombination of .NO2 with FeIV=O species. In the presence of reducing agents such as ascorbic acid, the FeIV=O species can be reduced to FeIII, thus helping to maintain the PN reductase cycle. 相似文献
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There are many reports1 of the pyrolysis of fluorinated organic compounds, including the defluorination of cyclic fluorocarbons over iron to give aromatic compounds. Extending this technique we have investigated the flow pyrolysis of some readily accessible unsaturated fluorocarbons, such as I, II, and III, and found these to be synthetically useful routes to fluorinated dienes, cyclobutenes, and furans. Pyrolyses were carried out using a nitrogen flow over platinum, iron or caesium fluoride heated at 430–700°. The various products can all be rationalized in terms of intermediate allylic radicals, and the solid substrate influences which allylic radicals are formed.We are also investigating the chemistry of those now accessible compounds, such as IV, V, and VI, and some of the preliminary results are described. For example the fluoride ion induced dimerisation of IV gave two major products VII and VIII via a particular interesting mechanism. 相似文献
45.
B. B. Idage S. P. Vernekar N. D. Ghatge 《Journal of polymer science. Part A, Polymer chemistry》1983,21(7):2145-2155
Rates of decomposition of di(3-hydroxybutyl)-2,2′-azobisisobutyrate, di(4-hydroxybutyl)-2,2′-azobisisobutyrate, di(2-hydroxyethyl)-2,2′-azobisisobutyrate, di(2-chloroethyl)-2,2′-azobisisobutyrate, and di(2-hydroxypropyl)-2,2, all of which are useful in the polymerization of butadiene and isoprene, were measured by nitrogen evolution technique at 60, 70, and 80°C, respectively, in each of the three solvents, namely, toluene, dioxane, and N,N-dimethylformamide. The thermal decompositions of these azo compounds in solution were first order, and the Arrhenius equation was used to calculate their activation energies. 相似文献
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has been studied by using a complete active space MCSCF wave function generated by distributing eight electrons among eight orbitals. 相似文献