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91.
Rao TR Krishna ChR Reddy ChV Thampy US Reddy YP Rao PS Ravikumar RV 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1116-1122
Optical and physical properties of Ni2+ doped 20ZnO+xLi2O+(30-x)Na2O+50B2O3 (5≤x≤25) glasses are carried out at room temperature. Powder XRD pattern of all the glass samples confirms the amorphous nature. Several physical parameters are evaluated for all the glasses with respect to the composition. The optical absorption spectra confirm the site symmetry of the Ni2+ doped glasses are near octahedral. Crystal field and inter-electronic repulsion parameters are also evaluated. It is interesting to observe that the optical band gap and Urbach energies exhibit the mixed alkali effect. The FT-IR spectral investigations of Ni2+ doped glasses exhibit characteristic vibrations of BO3 and BO4 units. 相似文献
92.
Nanostructured MnO(2) exhibits a high turnover frequency for oxygen evolution under visible light and high stability in strong acidic conditions. 相似文献
93.
Hrudananda Jena R. Venkata Krishnan R. Asuvathraman K. Nagarajan K. V. Govindan Kutty 《Journal of Thermal Analysis and Calorimetry》2011,106(3):875-879
Ba10−x
Cs
x
(PO4)6Cl2, (x = 0, 0.5) chloroapatite ceramics were prepared by sonochemical method of synthesis. The measured room temperature lattice
parameters of Ba10 (PO4)6Cl2 and Ba9.5Cs0.5 (PO4)6Cl2−δ are practically the same; that is, a = 10.26 (8), c = 7.65 (7) and a = 10.27 (7), c = 7.65 (5), respectively. Heat capacity measurements were carried out on these materials by differential scanning calorimetry
(DSC) in the temperature range 298–800 K. The heat capacity values of Ba9.5Cs0.5(PO4)6Cl2−δ are found to be slightly higher at all temperatures than those of Ba10(PO4)6Cl2. From the heat capacity data, other thermodynamic functions such as enthalpy and entropy increments were computed. The heat
capacity values of Ba10(PO4)6Cl2 and Ba9.5Cs0.5(PO4)6Cl2−δ at 298 K are 0.3912 and 0.4310 J K−1 g−1, respectively. Thermal expansion property of the doped and undoped barium chloroapatites was measured by using a home built
dilatometer which uses LVDT as displacement sensor. The bulk thermal expansion of Ba10(PO4)Cl2 and Ba9.5Cs0.5(PO4)Cl2−δ is observed to be about 0.9% in the temperature range of 298–973 K. 相似文献
94.
The spatial stability properties of a mixed convection boundary layer developing over a heated horizontal plate is studied here under linear and quasi-parallel flow assumption. The main aim of the present work is to find out if there is a critical buoyancy parameter that would indicate the importance of heat transfer in destabilizing mixed convection boundary layers, when the buoyancy effect is given by Boussinesq approximation. The undisturbed flow used here is that given by the similarity solution of [ 1 ] that implies the wall temperature to vary as the inverse square root of the distance from the leading edge of the plate. The stability of this flow has been investigated by using the compound matrix method (CMM)—that allows finding all the modes in the chosen range in the complex wave number plane for spatial stability analysis. Presented neutral curves for mixed convection boundary layer show the existence of two types of disturbances present simultaneously, for large buoyancy parameter. One notices very unstable high-frequency mode when the buoyancy parameter exceeds the above-mentioned critical value. This unstable thermal mode is in addition to the hydrodynamic mode of isothermal flow given by corresponding similarity profile. The calculated critical buoyancy parameter is shown to qualitatively match with experimental results. 相似文献
95.
Polysubstituted 2-carboxylate and 2-phosphonate pyrroles are prepared by aromatization of the corresponding 3-oxo 2-carboxylate and 2-phosphonate NH-pyrrolidines using air. Reaction of electrophiles with 3-oxo pyrrolidine dianions readily introduces substituents, regioselectively at C-4 in these pyrrolidines. 相似文献
96.
M. M. Dhingra G. Govil C. L. Khetrapal K. Venkata Ramiah 《Proceedings Mathematical Sciences》1965,62(2):90-96
Proton magnetic resonance studies of the solutions of (a) 2-amino, 3-methyl pyridine and (b) 2-amino, 6-methyl pyridine in carbontetrachloride show that in these molecules there is an equilibrium between monomers and hydrogen-bonded dimers. The equilibrium constants for the two cases have been obtained. Evidence has also been obtained to show that chloroform forms hydrogen bond with the ring nitrogen of these compounds. These NMR results have been compared with those obtained earlier from infra-red studies. 相似文献
97.
T. Kiran Kumar S. Venkataratnam K. Venkata Reddy 《Radiation Physics and Chemistry》1996,48(6):707-710
Effective atomic numbers (Zeff) of different clay minerals are calculated for total photon interaction in the energy region 10 keV–10 MeV. The variation of Zeff with energy is discussed by comparing with the similar studies made for alloys and compounds from our laboratory. 相似文献
98.
The motion of a rigid plastic cantilever beam which is surrounded by a damping medium and struck transversely at the tip by a moving mass is studied. The elementary theory, which disregards effects due to rate of straining and geometry changes is used. The governing equations of motion are integrated numerically. For comparison the case of discrete damping provided at the tip only is also solved. Results are presented for a wide range of parameters. 相似文献
99.
S.Aanantha Ramu K.Janardhana Iyengar 《International Journal of Solids and Structures》1976,12(2):125-133
The dynamical behaviour of a simply supported, orthotropic, circular plate subjected to strong blast is considered. The blast is assumed to impart an axisymmetric transverse, velocity which has a general Gaussian distribution spatially. It is concluded that the rate of growth of plastic regimes and the final plastic deformation strongly depend upon the initial Gaussian distribution parameter. 相似文献
100.