全文获取类型
收费全文 | 801篇 |
免费 | 36篇 |
国内免费 | 1篇 |
专业分类
化学 | 640篇 |
晶体学 | 23篇 |
力学 | 15篇 |
数学 | 69篇 |
物理学 | 91篇 |
出版年
2023年 | 5篇 |
2022年 | 10篇 |
2021年 | 18篇 |
2020年 | 19篇 |
2019年 | 32篇 |
2018年 | 29篇 |
2017年 | 24篇 |
2016年 | 36篇 |
2015年 | 31篇 |
2014年 | 50篇 |
2013年 | 63篇 |
2012年 | 55篇 |
2011年 | 66篇 |
2010年 | 23篇 |
2009年 | 24篇 |
2008年 | 32篇 |
2007年 | 31篇 |
2006年 | 20篇 |
2005年 | 26篇 |
2004年 | 22篇 |
2003年 | 17篇 |
2002年 | 18篇 |
2001年 | 10篇 |
1995年 | 11篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1990年 | 3篇 |
1989年 | 11篇 |
1988年 | 4篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1984年 | 4篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 9篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 5篇 |
1975年 | 6篇 |
1974年 | 4篇 |
1972年 | 4篇 |
1970年 | 3篇 |
1969年 | 4篇 |
1968年 | 4篇 |
1961年 | 5篇 |
1957年 | 3篇 |
排序方式: 共有838条查询结果,搜索用时 15 毫秒
71.
D. Mohan Ganga Radhakrishnan S. Rajadurai K. Venkata Rao Gordon G. Cameron 《Journal of polymer science. Part A, Polymer chemistry》1989,27(6):2123-2133
Polyacrylamide has been grafted onto casein in phosphate buffer medium using potassium peroxodisulfate as initiator. The influence of synthetic variables on percent grafting, grafting efficiency, rates of conversion of monomer, and the rates of graft copolymerization have been discussed. A possible kinetic scheme based on experimental results has been derived. 相似文献
72.
T. V. Ramana Murty 《Czechoslovak Journal of Physics》1989,39(9):991-997
The analysis of flow past a continuously moving semi-infinite flat plate in the presence of transverse magnetic field has been presented. Model solutions have been derived and the resulting equations are integrated numerically. Velocity profiles are displayed graphically and the numerical values of the transverse velocity skin friction are given in the form of tables. It has been observed that an increase inM (magnetic field parameter) leads to a decrease in velocity.The author wishes to express his thanks to Dr. H. N. Siddiquie, Director, and Dr. J. S. Sastry, Head, Physical Oceanography Division, for their keen interest and encouragement throughout this work. 相似文献
73.
Biswanath Das Kongara Ravinder Reddy Bommena Ravikanth Akella Venkata Subrahmanya Sarma Balasubramanian Sridhar 《Helvetica chimica acta》2008,91(6):1137-1143
Chemical investigation on two samples of the flowers of Parthenium hysterophorus afforded two new pseudoguaianolides (one from each sample) together with several known constituents. The structures of the new compounds were established by extensive spectroscopic (1D‐ and 2D‐NMR) studies. The X‐ray crystallographic analysis of one of these compounds was also accomplished. 相似文献
74.
In this Letter, we describe the novel synthetic approach to the tricyclic core of (±)-galanthamine from the easily available starting material isovanillin. 相似文献
75.
76.
Garbapu Suresh Ratnakaram Venkata Nadh Navuluri Srinivasu Durgaprasad Yennity 《合成通讯》2017,47(17):1610-1621
A new and efficient synthetic route for dual-Src/Abl kinase inhibitor dasatinib (Sprycel®), an anticancer drug, is described. This commercially viable process yields dasatinib monohydrate free of potential impurities with consistent yield of 68% in route A and 61% in route B with HPLC purity >99.80% over four stages. 相似文献
77.
Temperature-modulated differential scanning calorimetry (TMDSC) is known to have the ability to measure heat capacity of materials
more accurately than the conventional differential scanning calorimeter. However, the accuracy of the measured heat capacity
displays significant dependence on various experimental parameters such as period of modulation (p), amplitude of modulation (a), geometry of sample (g), heating rate (r), etc. One of the key features of this system is the ability to measure heat capacity under quasi-isothermal conditions.
In the present investigation, heat capacity of a well-established system namely sapphire and thoria was measured by TMDSC
under dynamic mode and also under quasi-isothermal mode. The experimental parameters, mentioned above p, a, g, and r are varied to establish the conditions for measuring heat capacity accurately. 相似文献
78.
G. Panneerselvam R. Venkata Krishnan K. Nagarajan M. P. Antony 《Journal of Thermal Analysis and Calorimetry》2010,101(1):169-173
Dysprosium hafnate is a candidate material for as control rods in nuclear reactor because dysprosium (Dy) and hafnium (Hf)
have very high absorption cross-sections for neutrons. Dysprosium hafnate (Dy2O3·2HfO2-fluorite phase solid solution) was prepared by solid-state as well as wet chemical routes. The fluorite phase of the compound
was characterized by using X-ray diffraction (XRD). Thermal expansion characteristics were studied using high temperature
X-ray diffraction (HTXRD) in the temperature range 298–1973 K. Heat capacity measurements of dysprosium hafnate were carried
out using differential scanning calorimetry (DSC) in the temperature range 298–800 K. The room temperature lattice parameter
and the coefficient of thermal expansion are 0.5194 nm and 7.69 × 10−6 K−1, respectively. The heat capacity value at 298 K is 232 J mol−1 K−1. 相似文献
79.
T. Raghavendra RaoCh. Rama Krishna U.S. Udayachandran ThampyCh. Venkata Reddy Y.P. ReddyP. Sambasiva Rao R.V.S.S.N. Ravikumar 《Physica B: Condensed Matter》2011,406(11):2132-2137
The effect of Li2O content in vanadyl doped 20ZnO+xLi2O+(30−x)Na2O+50B2O3 (5≤x≥25) glasses has been studied with respect to their physical and structural properties. The absence of sharp peaks in XRD spectra of these glass samples confirms the amorphous nature. The physical parameters like density, refractive index, ionic concentration and electronic polarizability vary non-linearly with x mol% depending on the diffusivities of alkali ions. EPR and optical absorption spectra reveal that the resonance signals are characteristics of VO2+ ions in tetragonally compressed octahedral site. Spin-Hamiltonian, crystal field, tetragonal field and bonding parameters are found to be in good agreement with the other reported glass systems. The tetragonal distortion (g⊥-g∥) and Dt reveals that their values vary non-linearly with Li2O content and reaches a minimum at x=10 mol%. An anomaly of character has been observed in all the properties of vanadyl doped glass systems, which gives a clear indication of mixed alkali effect. 相似文献
80.
P. Saravanan G. Venkata RamanaK. Srinivasa Rao B. SreedharV.T.P. Vinod V. Chandrasekaran 《Journal of magnetism and magnetic materials》2011,323(15):2083-2089
Self-assembled Sm-Co nanoparticles in the form of spherical aggregates (referred as nanospheres) with diameter ranging from 50 to 180 nm were achieved by means of polyol technique. The size distribution of the Sm-Co nanospheres can be regulated close to ∼100 nm by controlling the molar ratio of Sm:Co precursor. The spherical aggregates exhibited Sm2Co7 phase as a major constituent; while the aggregates obtained at higher Co concentration showed co-existence of Co-phase with Sm2Co7 phase. Upon annealing, the biphasic nature of nanospheres (Sm2Co7/Co) transformed into Sm2Co17 structure. By varying the Sm:Co precursor ratio from 1:5 to 1:9, the coercivity (Hc) and magnetization (Ms) values of the as-synthesized nanospheres can be tuned from 336 to 140 Oe and from 63.7 to 108 emu/g, respectively, and these values significantly improved after annealing. Maximum values of Hc (1050 Oe) at the Sm:Co molar ratio of 1:5 and Ms of 184.6 emu/g at the Sm:Co molar ratio of 1:9 were achieved in the annealed samples. 相似文献