全文获取类型
收费全文 | 947篇 |
免费 | 42篇 |
专业分类
化学 | 744篇 |
晶体学 | 21篇 |
力学 | 13篇 |
数学 | 63篇 |
物理学 | 148篇 |
出版年
2023年 | 8篇 |
2022年 | 21篇 |
2021年 | 27篇 |
2020年 | 32篇 |
2019年 | 41篇 |
2018年 | 40篇 |
2017年 | 30篇 |
2016年 | 51篇 |
2015年 | 34篇 |
2014年 | 59篇 |
2013年 | 62篇 |
2012年 | 80篇 |
2011年 | 95篇 |
2010年 | 36篇 |
2009年 | 37篇 |
2008年 | 50篇 |
2007年 | 41篇 |
2006年 | 23篇 |
2005年 | 28篇 |
2004年 | 23篇 |
2003年 | 16篇 |
2002年 | 14篇 |
2001年 | 5篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 9篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 5篇 |
1985年 | 7篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 2篇 |
1971年 | 2篇 |
1969年 | 2篇 |
1968年 | 4篇 |
1967年 | 3篇 |
1964年 | 2篇 |
1962年 | 2篇 |
1961年 | 5篇 |
排序方式: 共有989条查询结果,搜索用时 15 毫秒
141.
Solvent‐Dependent Structure of the I3− Ion Derived from Photoelectron Spectroscopy and Ab Initio Molecular Dynamics Simulations
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Naresh K. Jena Ida Josefsson Dr. Susanna K. Eriksson Prof. Anders Hagfeldt Prof. Hans Siegbahn Prof. Olle Björneholm Prof. Håkan Rensmo Dr. Michael Odelius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):4049-4055
Ab initio molecular dynamics (MD) simulations of the solvation of LiI3 in four different solvents (water, methanol, ethanol, and acetonitrile) are employed to investigate the molecular and electronic structure of the I3? ion in relation to X‐ray photoelectron spectroscopy (XPS). Simulations show that hydrogen‐bond rearrangement in the solvation shell is coupled to intramolecular bond‐length asymmetry in the I3? ion. By a combination of charge analysis and I 4 d core‐level XPS measurements, the mechanism of the solvent‐induced distortions has been studied, and it has been concluded that charge localization mediates intermolecular interactions and intramolecular distortion. The approach involving a synergistic combination of theory and experiment probes the solvent‐dependent structure of the I3? ion, and the geometric structure has been correlated with the electronic structure. 相似文献
142.
David Tong Jackie Wu Nathan Bazinski Donghyun Koo Naresh Vemula Prof. Dr. Brian L. Pagenkopf 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(67):15244-15247
Cycloadditions of strained carbocycles promoted by Lewis acids are powerful methods to construct heterocyclic frameworks. In fact, the formal [3+2] cycloadditions of donor–acceptor (DA) cyclopropanes with nitriles has seen particular success in synthesis. In this work, we report on the first [4+2] cycloaddition of nitriles with DA cyclobutanes by Lewis acid activation. Tetrahydropyridine derivatives were obtained in up to 91 % yield from various aryl-activated cyclobutane diesters and aliphatic or aromatic nitriles. 相似文献
143.
Velusamy B. Subramanian Naresh Kumar Katari Thirupathi Dongala Sreekantha B. Jonnalagadda 《Biomedical chromatography : BMC》2020,34(1):e4719
A quality by design (QbD) based high-resolution HPLC method is described for determination of impurities in apixaban (APX) in the tablet dosage form. Employing a simple and stability-indicating HPLC method, nine known impurities were quantified with good peak resolution. Mobile phase A (MP-A) was prepared with buffer and acetonitrile 90:10 v/v, while mobile phase B (MP-B) contained water and acetonitrile 10:90 v/v. The gradient program was 0 min, MP-A 75%, B 25%; 20 min, MP-A 65%, B 35%; 30 min, MP-A 40%, B 60%; 40min, MP-A 40%, B 60%; 42 min, MP-A 75%, B 25%; and 50 min, MP-A 75%, B 25%. The chromatographic separation was achieved using a Zorbax RX C18 250 × 4.6 mm column, 5 μm (1.0 ml min−1, 280 nm, 50 μl) and a column temperature of 40°C. Several separation studies were carried out using design of experiments to optimize the method. Validation results confirm the applicability of the developed method for quality analysis and stability studies of the regular product on the manufacturing stream. 相似文献
144.
145.
Sharma Deepak Sharma Naresh Brahmbhatt D. I. Gupta Vivek K. 《Crystallography Reports》2019,64(7):1047-1050
Crystallography Reports - The crystal structure of the title compound is determined by single crystal X-ray structure analysis. The structure was solved by direct method and refined to a final... 相似文献
146.
Kumari Maddineni Aruna Rao Chunduri Venkata Triloknadh Settypalli Harikrishna Nallapaneni Venkataramaiah Chintha Rajendra Wudayagiri Trinath Daggupati Suneetha Yeguvapalli 《Research on Chemical Intermediates》2018,44(3):1989-2008
Research on Chemical Intermediates - In an attempt to find potential neuroprotective agents, a series of novel 3-(1-((1-(substituted phenyl)-1H-1,2,3-triazol-4-yl) methoxyimino)... 相似文献
147.
Venkata Swamy Tangeti Kattaru Ramesh Babu G. V. Siva Prasad Tadikonda Ramu C. Venkata Rao 《Journal of the Iranian Chemical Society》2018,15(4):823-829
An efficient and rapid method was developed for the synthesis of C3-pyranopyrazole-substituted coumarins from one-pot five-component reaction of β-keto ester, hydrazine, O-hydroxy aromatic aldehydes, 6-methyl, 4-hydroxy pyranone and aromatic aldehyde in the presence of tri-ethylamine in solvent-free conditions. The microwave-assisted method reported herein offers advantageous shorter reaction times, higher yields and cleaner reaction compared with conventional heating methods. 相似文献
148.
Brendan Frett Nicholas McConnell Anupreet Kharbanda Gunaganti Naresh Benjamin Rounseville Christina Warner John Chang Natalie Debolske Hong-yu Li 《Tetrahedron》2018,74(35):4592-4600
Carbon-carbon bonds are integral for pharmaceutical discovery and development. Frequently, CC bond reactions utilize expensive catalyst/ligand combinations and/or are low yielding, which can increase time and expenditures in pharmaceutical development. To enhance CC bond formation protocols, we developed a highly efficient, selective, and combinatorially applicable Friedel-Crafts acylation to acetylate the C-3 position of imidazo[1,2-a]pyridines. The reaction, catalyzed by aluminum chloride, is both cost effective and more combinatorial friendly compared to acetylation reactions requiring multiple, stoichiometric equivalents of AlCl3. The protocol has broad application in the construction of acetylated imidazo[1,2-a]pyridines with an extensive substrate scope. All starting materials are common and the reaction requires inexpensive, conventional heating methods for adaptation in any laboratory. Further, the synthesized compounds are predicted to possess GABA activity through a validated, GABA binding model. The developed method serves as a superior route to generate C-3 acetylated imidazo[1,2-a]pyridine building-blocks for combinatorial synthetic efforts. 相似文献
149.
Sanjay Kumar D. Ananthasivan K. Venkata Krishnan R. Senapati Abhiram 《Journal of Thermal Analysis and Calorimetry》2018,131(3):2467-2476
Journal of Thermal Analysis and Calorimetry - The reaction mechanism and the determination of kinetic parameters of the citrate gel combustion synthesis of nanocrystalline urania (U3O8) are being... 相似文献
150.
Rouhana Nathalie Handagama Naresh Bienkowski Paul R. 《Applied biochemistry and biotechnology》1997,(1):809-821
A vapor-phase bioreactor has been developed utilizing porous metal membranes in a cylindrical design employing radial flow
as opposed to traditional axial flow for the vapor stream. The system was evaluated for the biodegradation ofp-xylene (p-xylene) from a water-saturated air stream byPseudomonas putida ATCC 23973 immobilized onto sand. The biocatalyst was placed in the annular space between two cylindrical, porous stainless-steel
membranes. Details of the reactor system are presented along with biological data verifying system performance. The feed flow
rate andp-xylene concentration were varied between 60 and 130 cm3/min and 15–150 ppm, respectively. Continuous reactor operation was maintained for 80–200 h with removal efficiencies (based
onp-xylene disappearance) between 80 and 95%. The effluent concentration histories were compared to determine the operating range
of the bioreactor. 相似文献