New tin templates for the synthesis of macrocyclic polythiaether-polythiaester ligands

The preparation of new tin templates, stannathianes 1-3 is described. New templates have been successfully applied to the synthesis of macrocyclic polythialactones 4-9 by cyclization of corresponding stannathianes 1-3 with pimeloyl dichloride.     

Study of nanocrystalline diamond film growth in rf hybrid laser deposition systems in O2, H2 and H2+Ar ambients

Pulsed laser deposition (PLD) and hybrid pulsed laser deposition (HPLD) systems were used for nanocrystalline diamond (NCD) film growth on Si(100) and sapphire(0001) substrates. The PLD system was based on a KrF excimer laser (=248 nm,20 ns), which ablated a graphite target in pure oxygen or hydrogen ambient. The HPLD system was based on a combination of PLD and additional capacitively coupled radio-frequency discharges (13.56 MHz) in argon–hydrogen ambient. Radio-frequency power was applied to two plane parallel electrodes or directly to the substrate holder. The working atmosphere pressure was varied from 1 Pa to 220 Pa and the substrate temperature was varied from 20 °C to 660 °C. X-ray diffraction analysis, Raman spectroscopy and a profilometer were used to study the deposited film properties. A band around 1180 cm^-1, which can be attributed to NCD, occurred in the Raman spectra. A characteristic diamond peak at 1332 cm^-1 was not observed. Films prepared by HPLD showed better compositional homogeneity (from Raman analysis) than films created by PLD. PACS 52.80.Pi; 81.07.Bc; 81.15.Fg     

Oxygen as a morphogenic factor in sponges: expression of a tyrosinase gene in the sponge Suberites domuncula

Sponges live in a symbiotic relationship with microorganisms, especially bacteria. Here we show, using the demosponge Suberites domuncula as a model, that the sponge expresses the enzyme tyrosinase which synthesizes diphenols from monophenolic compounds. It is assumed that these products serve as carbon source for symbiotic bacteria to grow.     

Absorption of solar radiation by solar neutrinos

We calculate the absorption probability of photons radiated from the surface of the Sun by a left-handed neutrino with definite mass and a typical momentum for which we choose |p₁| = 0.2 MeV, producing a heavier right-handed antineutrino. Considering the two transitions and we obtain the two oscillation lengths L₁₂ = 4960.8 m, L₂₃ = 198.4 m, the two absorption probabilities P₁₂^abs. = 2.5 x 10^-67, P₂₃^abs. = 1.2 x 10^-58 and the two absorption ranges au, au, using a neutrino mass differences of meV, meV and associated transition dipole moments. We collect all necessary theoretical ingredients, i.e. neutrino mass and mixing scheme, induced electromagnetic transition dipole moments, quadratic charged lepton mass asymmetries and their interdependence.Received: 4 November 2003, Revised: 23 March 2004, Published online: 5 May 2004     

Modeling,Mathematical and Numerical Analysis of Electrorheological Fluids

Many electrorheological fluids are suspensions consisting of solid particles and a carrier oil. If such a suspension is exposed to a strong electric field the effective viscosity increases dramatically. In this paper we first derive a model which captures this behaviour. For the resulting system of equations we then prove local in time existence of strong solutions for large data. For these solutions we finally derive error estimates for a fully implicit time-discretization.     

Oscillation criteria for sublinear differential equations with damping

We present some criteria for the oscillation of the second order nonlinear differential equation [a(t)ψ(x(t))x'(t)]' + p(t)x'(t) + q(t)f (x(t)) =0, t≧t ₀> 0 with damping where a∈C ¹ ([t ₀,∞)) is a nonnegative function, p, q∈ C([t ₀,∞)) are allowed to change sign on [t ₀,∞), ψ, f∈C(R) with ψ(x) ≠ 0, xf(x)/ψ(x) > 0 for x≠ 0, and ψ, f have continuous derivatives on R{0} with [f(x) / ψ(x)]' ≧ 0 for x≠ 0. This criteria are obtained by using a general class of the parameter functions H(t,s) in the averaging techniques. An essential feature of the proved results is that the assumption of positivity of the function ψ(x) is not required. Consequently, the obtained criteria cover new classes of equations to which known results do not apply.     

Regge oscillations in integral cross sections for proton impact on atomic hydrogen

The integral cross sections for elastic scattering and spin exchange for proton impact on atomic hydrogen show several oscillations in the energy range 0.01-1.0 eV that cannot be associated with resonances or the glory effect. A complex angular momentum analysis using computed Regge trajectories shows that each peak of the oscillatory structure is predominantly associated with at most three trajectories. In this way, the peaks are related to the L=0 bound states of H+ 2. The complex angular momentum theory for integral cross sections that we introduce shows that such oscillations are a general feature of potential scattering.     

Mechanism of hopping transport in disordered mott insulators

By using a combination of detailed experimental studies and simple theoretical arguments, we identify a novel mechanism characterizing the hopping transport in the Mott insulating phase of Ca2-xSrxRuO4 near the metal-insulator transition. The hopping exponent alpha shows a systematic evolution from a value of alpha=1/2 deeper in the insulator to the conventional Mott value alpha=1/3 closer to the transition. This behavior, which we argue to be a universal feature of disordered Mott systems close to the metal-insulator transition, is shown to reflect the gradual emergence of disorder-induced localized electronic states populating the Mott-Hubbard gap.