Reorganization of poly(ethylene terephthalate) structures and conformations to alter properties

The solid‐state morphologies, structures, and chain conformations of poly (ethylene terephthalate) (PET) have been reorganized/altered from those normally produced by solution and melt processing. This has been achieved by two distinct methods: (1) formation of a crystalline inclusion compound (IC) between guest PET and host γ‐cylodextrin (γ‐CD), followed by removal of the host γ‐CD and coalescence of the guest PET (c‐PET) and (2) rapid precipitation of PET from a warm trifluoracetic acid solution into a large excess of rapidly stirred acetone (p‐PET). Our prior observations (FTIR, NMR, DSC, X‐ray) demonstrated that c‐PET processed in this manner has a morphology, structure, and non‐crystalline chain conformations that are quite distinct from those of as‐received PET (asr‐PET). Where possible to compare, here we find that c‐ and p‐PETs behave very similarly, but very distinctly from asr‐PET. The reorganized c‐ and p‐PETs were found to be repeatedly rapidly crystallizable from the melt with a high level of crystallinity, and in their non‐crystalline regions to have tightly packed chains predominantly adopting highly extended kink conformations, which evidence no glass‐transition behavior. What is most unusual and somewhat puzzling is that their contrasting structures, morphologies, conformations, and thermal responses were observed to be independent of melt annealing, and persisted even after holding both samples above T_m for extended periods (hours). p‐PET, which can be produced in larger quantities than c‐PET, was utilized to measure additional macroscopic properties, such as melt viscosities, densities, and the stress‐strain and thermal shrinkage of melt‐pressed films, for comparison to those of asr‐PET. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 735–746, 2007     

怀孕期头发中一些元素含量的变化趋势

用同步辐射激发X射线荧光分析,对11个产妇怀孕期间头发内一些元素含量的变化趋势进行了测量,在各自对比的基础上,得到了一些结果。     

Influence of the Shape of the Orifice on the Local Heat Transfer Distribution of a Flat Plate Impinged by Under-Expanded Sonic Jets

Experiments are carried out for the circular, square, and equilateral triangular orifices of the same contraction ratio in order to explore the heat transfer characteristics for nozzle pressure ratios of 2.36, 3.04, 3.72, 4.4, and 5.08 at z/d = 2, 4, 6, and 8. The presence of vena contracta and shock cells and its locations are estimated from the impact pressure distribution along the axial direction. The pressure drop during the initial expansion is minimal for the equilateral triangular orifice. However, this pressure drop is comparable for the square and circular orifices. The heat transfer characteristics of the circular orifice are nearly axisymmetric, but that for non-circular jets are asymmetric, and the three dimensional effects are clearly observed. This is inferred through the spatial gradients of the Nusselt number and adiabatic wall temperature distributions. The linear correlations for the average Nusselt number are proposed for the circular, square, and equilateral triangular orifices.     

Effect of copper–graphene hybrid nanoplatelets in a miniature loop heat pipe

Journal of Thermal Analysis and Calorimetry - A novel hybrid nanofluid is prepared, and its effects on the heat transfer performance of flat rectangular loop heat pipe are experimentally...     

Comparison of heat transfer distributions on a flat plate impinged by under-expanded jets from a convergent nozzle and a circular orifice

Experiments are carried out for a circular orifice and a nozzle for the same contraction ratio to explore the heat transfer characteristics. The pressure ratios covered in this study are 2.36, 3.04, 3.72, 4.4 and 5.08 for jet to plate distances (z/d) of 2, 4, 6 and 8. The presence of vena contracta and absence of the stagnation bubble in the orifice flow are confirmed from the surface pressure distributions. It is found that higher Nusselt number for the orifice than the nozzle are due to different shock structures and shear layer dynamics. Peak Nusselt number is found as high as 84 % than that for the nozzle. In the wall jet region, the heat transfer rates for the orifice and nozzle are almost of the same order, thus producing steeper temperature gradients under similar operating conditions. The average heat transfer rates are almost 25 % higher for the orifice than that of the nozzle. The recovery factors are in general higher in case of orifice than the nozzle. However, this has not resulted in decreasing the heat transfer rates due to shear layer dynamics.     

An Efficient Synthesis of Pyrazolyl‐1,2,3‐thiadiazoles via Hurd–Mori Reaction

An efficient synthetic strategy has been developed for the synthesis of pyrazolyl‐1,2,3‐thiadiazoles via Hurd–Mori cyclization reaction. The reaction of various pyrazolyl‐phenylethanones with semicarbazide hydrochloride in the presence of sodium acetate/methanol gave the corresponding semicarbazones ( 3a – i ). These semicarbazones were further reacted with thionyl chloride via the Hurd–Mori cyclization conditions to accomplish the title products ( 4a – i ). The present protocol favored for the formation of both pyrazolyl semicarbazone derivatives and pyrazolyl‐1,2,3‐thiadiazole derivatives by forming C─S, N─S, and C═N bonds in excellent yields with variety of substrates. The final compounds were characterized by analytical and spectral studies.     

Synthesis of 6‐(5‐Methylisoxazol‐3yl)‐3‐alkyl Sulfanyl‐[1,2,4]triazolo‐[3,4‐b][1,3,4]thiadiazoles

A new series of isoxazole substituted fused triazolo‐thiadiazoles have been synthesized by the cyclocondensation of 5‐methylisoxazole‐3‐craboxylic acid and 4‐amino 1,2‐4‐triazole‐ 3,5‐dithiol using phosphorous oxychloride. The cyclised intermediate 6‐(5‐methylisoxazol‐3‐yl)‐[1,2,4]triazolo[3,4‐b][1,3,4]thiadiazole‐3‐thiol later on S‐alkylated with different alkyl halides in ethanol to give the title products in good to excellent yields.     

Pressure drop characteristics in a rotating smooth square channel with a sharp 180° bend

The results of an experimental study to investigate the local pressure drop characteristics in a square cross-sectioned smooth channel with a sharp 180° bend rotating about an axis normal to the free-stream direction are reported here. The sharp 180° turn was obtained by dividing a rectangular passage into two channels using a divider wall with a rounded tip at the location where the flow negotiates the turn. The study was carried out for three ratios of divider wall thickness to hydraulic diameter (W/D), namely, 0.24, 0.37 and 0.73 all with a rounded tip divider wall and only for a bend with a W/D ratio of 0.37, the influence of a sharp tip divider wall was studied. Experiments were conducted for a Reynolds number varying from 10 000 to 17 000 with the rotation number (ωD/V) varying from 0 to 0.38. The pressure drop distribution, normalized with the mainstream fluid dynamic pressure head, is presented for the leading, trailing and the outer surfaces. The results indicate that the local pressure drop characteristics in the bend region are significantly affected by a change in the rotation number but the influence of the Reynolds number is weak. The friction factor is less sensitive to rotation for the bend with a W/D ratio of 0.24 when compared to bends with W/D ratios of 0.37 and 0.73. Friction factor correlations are presented which fit the experimental data within 10% for the range of parameters studied.