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91.
92.
L. R. Bitner V. A. Vedernikov T. I. Danilina G. V. Manyakhina Z. A. Shandra 《Russian Physics Journal》1976,19(12):1535-1538
The mechanism by which electron — ion bombardment affects the growth of a silicon nitride film obtained by reactive sputtering in an apparatus based on a Penning discharge is investigated. The temperature and the degree of irradiation of the substrate are determined as functions of the distance from the substrate to the aperture in the anode. It is established that the presence or absence of bombardment leads to a difference in the formation of reactively sputtered silicon nitride films.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 11–15, December, 1976.The authors thank Yu. E. Kreindel' for his interest in the work and for useful discussions. 相似文献
93.
T-shaped 14 valence electron (eta2-L)PtMe+ (based on DFT geometry optimization, L = [2.1.1]-2,6-pyridinophane) reacts with benzene to give (eta3-L) PtIV(Ph)2H+ and methane; the latter cation is in thermal equilibrium with the N-protonated PtII tautomer (eta2-L-H)Pt(Ph)2+, and these complexes react with ethane or cyclopentane to produce benzene and (L)PtH(olefin)+. 相似文献
94.
V. N. Nuriev O. V. Fedorov A. A. Moiseeva A. Ya. Freidzon N. A. Kurchavov A. I. Vedernikov A. V. Medved’ko E. S. Pod’yacheva S. Z. Vatsadze S. P. Gromov 《Russian Journal of Organic Chemistry》2017,53(11):1726-1737
The reaction of tetraethyl [1,3-phenylenedi(methylene)]bis(phosphonate) with formyl derivatives of benzocrown-ethers or formyl derivatives of o-dimethoxybenzene lead to high yield formation of the respectful bis(crown ether) containing 1,3-distyrylbenzenes or tetramethoxy-substituted 1,3-distyrenebenzenes. NMR spectra and quantum-chemical calculations showed the prevalence of unsymmetrical syn/anti,(syn,anti),syn/anti-conformations in 1,3-distyrylbenzenes. 1,3-Distyrylbenzenes absorb in shorter wavelength spectral region and have a weaker fluorescence than 1,4-distyrylbenzenes. The difficulty in the electrochemical reduction of 1,3-distyrylbenzenes comparing with 1,4-distyrylbenzenes is due to a less effective conjugation system in the metaderivatives. 相似文献
95.
L.?S.?Atabekyan N.?A.?Lobova A.?I.?Vedernikov V.?G.?Avakyan S.?P.?GromovEmail author A.?K.?Chibisov 《Russian Chemical Bulletin》2017,66(1):47-55
Photophysical processes and photochemical reactions in the N-ammonioalkyl derivatives of the azacrown-containing styryl dyes and their complexes with lead and barium perchlorates in MeCN and CH2Cl2 were studied by 1Н NMR spectroscopy, absorption spectroscopy, luminescence spectroscopy, laser kinetic spectroscopy, and quantum chemistry. Molecules of the styryl dyes and their complexes are able to undergo normal (fast) and delayed fluorescence and trans–cis-photoisomerization. The molecules in the triplet state participate in degradation processes of the electron excitation energy. 相似文献
96.
97.
Doklady Physics - Conversion possibility of the chemical energy of combustion products of a hydrogen–oxygen mixture into electrical energy with the use of continuous spin detonation has been... 相似文献
98.
A. I. Vedernikov L. G. Kuz’mina Yu. A. Strelenko J. A. K. Howard S. P. Gromov 《Russian Chemical Bulletin》2010,59(5):927-940
Novel 15-hydroxybenzomonothia-15-crown-5 containing the sulfur atom linked with the benzene ring and its S-oxide were synthesized. The stability constants for the complexes of the obtained benzocrown ethers and a reference 15-hydroxybenzo-15-crown-5
with Na, Ca, AgI, Cd, HgII, and PbII perchlorates were determined by 1H NMR titration. In MeCN-d3, the benzothiacrown ether demonstrates a high selectivity towards the thio- and oxothiophilic Hg2+ (logK
1 = 7.1) and Pb2+ ions (logK
1 = 7.4). In MeCN-d3-D2O mixtures, the stabilities of the most of complexes decrease sharply due to competitive hydration of the metal cations except
for the “soft” Ag+ and Hg2+ ions having low affinity for the “hard” oxygen atoms and, on the contrary, very high affinity for the “soft” SII atoms. This results in the change in selectivity of complexation: at the water content in solution of 20%, the benzothiacrown
ether binds preferably the Hg2+ (logK
1 = 5.0) and Ag+ ions (logK
1 = 2.7). In MeCN-d3, the benzothiacrown-derived sulfoxide is a weak and non-selective complexing agent towards all the metal cations under study;
the reference 15-hydroxybenzo-15-crown-5 forms more stable complexes with the oxophilic sodium, calcium, and lead(ii) cations. The conformational features of the benzocrown ethers and their metal complexes established by NMR spectroscopy
and X-ray diffraction are discussed. The found characteristics of the complexing ability of benzomonothia-15-crown-5 where
the sulfur atom is in conjugation with the benzene ring reveal that the macrocyclic ligands with such a structure are promising
as high-selective and efficient complexing agents for the “soft” mercury(ii) and silver(i) cations in acetonitrile-water mixtures. 相似文献
99.
S. N. Dmitrieva M. V. Churakova N. A. Kurchavov A. I. Vedernikov L. G. Kuz’mina A. Ya. Freidzon A. A. Bagatur’yants Yu. A. Strelenko J. A. K. Howard S. P. Gromov 《Russian Chemical Bulletin》2010,59(6):1192-1206
A number of N-alkylnitrobenzoaza-15-crown-5 with the macrocycle N atom conjugated with the benzene ring were obtained. The structural and
complexing properties of these compounds were compared with those of model nitrobenzo- and N-(4-nitrophenyl)aza-15-crown-5 using X-ray diffraction, 1H NMR spectroscopy, and DFT calculations. The macrocyclic N atom of benzoazacrown ethers are characterized by a considerable
contribution of the sp3-hybridized state and a pronounced pyramidal geometry; the crownlike conformation of the macrocycle
is preorganized for cation binding, which facilitates complexation. The stability constants of the complexes of crown ethers
with the NH4
+, EtNH3
+, Na+, K+, Ca2+, and Ba2+ ions were determined by 1H NMR titration in MeCN-d3. The most stable complexes were obtained with alkaline-earth metal cations, which is due to the higher charge density at
these cations. The characteristics of the complexing ability of N-alkylnitrobenzoaza-15-crown-5 toward alkaline earth metal cations are comparable with analogous characteristics of nitrobenzo-15-crown-5
and are much better than those of N-(4-nitrophenyl)aza-15-crown-5. 相似文献
100.
Khaskin E Zavalij PY Vedernikov AN 《Journal of the American Chemical Society》2006,128(40):13054-13055
Anionic dimethyldi(2-pyridyl)borato dimethylplatinum(II) complexes react vigorously in 3:1 RH/water mixtures to produce PtII aryl (RH = C6H6, para-F2C6H4) or hydrido PtII olefin complexes (RH = cyclo-CnH2n; n = 5,6); the Na+ cation accelerates the reaction rates dramatically. 相似文献