Features of the Quenching of the Triplet States of Water-Soluble Porphyrins by Molecular Oxygen

Using the methods of time-resolved absorption spectroscopy, we have investigated the features of quenching, by molecular oxygen, of the excited triplet states of water-soluble 5,10,15,20-tetrakis-(4-N-methylpyridyl)-porphyrin (H₂TMPyP) and 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin (H₂TSPP) in water–ethanol solutions. It has been revealed that for both compounds the rate constant of quenching of the triplet states increases with increasing viscosity of the medium. Quenching of the excited triplet states of the dissociated (in water) and undissociated (in ethanol) forms of water-soluble porphyrins occurs with a different efficiency, and the rate constant of quenching the triplet states by molecular oxygen k _T thereby is higher for the dissociated form. It has been shown by means of mathematical modeling that the experimental results obtained can be described in terms of the change in the rate constants of intracomplex transitions in the porphyrin–oxygen collisional complex at varied solution viscosity and their difference for the dissociated and undissociated forms of water-soluble porphyrin.     

Karhunen–Loeve representations of turbulent channel flows using the method of snapshots

For three‐dimensional flows with one inhomogeneous spatial coordinate and two periodic directions, the Karhunen–Loeve procedure is typically formulated as a spatial eigenvalue problem. This is normally referred to as the direct method (DM). Here we derive an equivalent formulation in which the eigenvalue problem is formulated in the temporal coordinate. It is shown that this so‐called method of snapshots (MOS) has some numerical advantages when compared to the DM. In particular, the MOS can be formulated purely as a matrix composed of scalars, thus avoiding the need to construct a matrix of matrices as in the DM. In addition, the MOS avoids the need for so‐called weight functions, which emerge in the DM as a result of the non‐uniform grid typically employed in the inhomogeneous direction. The avoidance of such weight functions, which may exhibit singular behaviour, guarantees satisfaction of the boundary conditions. The MOS is applied to data sets recently obtained from the direct simulation of turbulence in a channel in which viscoelasticity is imparted to the fluid using a Giesekus model. The analysis reveals a steep drop in the dimensionality of the turbulence as viscoelasticity is increased. This is consistent with the results that have been obtained with other viscoelastic models, thus revealing an essential generic feature of polymer‐induced drag reduced turbulent flows. Published in 2006 by John Wiley & Sons, Ltd.     

Existence regions of regimes with anomalously high rates of plasma generation in grid plasma switch elements

Results are presented from a systematic investigation of the conditions under which anomalously high rates of plasma generation are observed in the anode region of a low-voltage Knudsen arc in grid plasma switch elements. The phenomenon develops over a wide range of currents and switched voltages under conditions for which the plasma density in the cathode-grid region is noticeably higher than the density in the anode region. and its onset is characterized by a pronounced pressure threshold of ∼2×10⁻² Torr. The results are analyzed from the standpoint of the possible mechanisms for anomalous plasma generation — collisional nonresonance diffusion of electrons in velocity space, leading to enrichment of the distribution function in fast particles, and the collapse of Langmuir waves in the gap at the high energies of the beam produced when the wires of the grid are bridged by the quenching pulse and and the current is blocked. Zh. Tekh. Fiz. 67, 15–21 (June 1997)     

Excitation of metal spectra in combined glow discharge

Consideration is given to the special features of the excitation of spectra of metals (Ag, Au, Fe, Hg, Pt, and Sb) that manifest themselves in investigating spectral sources with combined glow discharge (glow discharge and capillary discharge). It is established that the proposed method for introducing a substance into a plasma makes it possible to realize two fundamentally different regimes: without evaporation and with complete evaporation and matrix atomization. It is shown that a spectral source of combined glow discharge with a nonequilibrium plasma has significant advantages for the most important analytical characteristics over quasi-equilibrium combined discharge at atmospheric pressure. The gold and platinum sensitivity in combined glow discharge is 10⁻⁷%, and the reproducibility of spectral determinations is 0.001–0.100, depending on the measurement range. A fractional separation of elements that makes it possible to analyze the phase composition of substances, particularly metals, with high sensitivity is revealed in glow discharge. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 2, pp. 143–147, March–April, 1997.     

Universal elementary constituents of potential transformations shifting waves (qualitative theory)

It is shown that the potential perturbation that shifts a chosen standing wave in space is a block of potential barrier and well for every wave bump between neighbouring knots. The algorithms shifting the range of the primary localization of a chosen bound state in a potential well of finite width are as well applicable to the scattering functions if states of the continuous spectrum are considered as bound states normalized to unity but distributed on an infinite interval with vanishing density. The potential perturbations of the same type on the half-axis concentrate the scattering wave at the origin, thus creating a bound state embedded into the continuous spectrum (zero width resonance).     

New critical dimensions forq-deformed bosonic string

Applying the mass shell condition forq-deformed open and closed strings, new critical space-time dimensions are derived. Supported by the Algerian Ministry of High Education and Research under contract N^oD2501/17/01/93. Permanent address.     

Self-energy correction to the hyperfine splitting of the 1 s and 2 s states in hydrogenlike ions

The one-loop self-energy correction to the hyperfine splitting of the 1 s and 2 s states of hydrogenlike ions is calculated for both point and finite nuclei. The results of the calculation are combined with other corrections to find the ground state hyperfine splitting in lithiumlike ²⁰⁹Bi⁸⁰⁺ and ¹⁶⁵Ho⁶⁴⁺. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 1, 19–22 (10 July 1997) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Resonance enhancement of diffuse scattering of x-rays in a waveguide heterostructure

The diffuse scattering of x rays in a four-layer waveguide-type heterostructure is investigated. The dynamic enhancement of diffuse scattering is detected experimentally in regions corresponding to the excitation of waveguide modes for both the incident and scattered waves. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 4, 219–223 (25 August 1997)     

Investigation of thin-film electroluminescent structures on rough subsrates

Results of experimental investigations of the volt-brightness characteristics, frequency dependences of brightness, and the directional radiation pattern of electroluminescent MSDM, MSCM, and MSDCM emitters, where M stands for the first transparent and second nontransparent electrodes, S is a semiconductor, D is a thin-film dielectric, and C is a silicone-based composite liquid dielectric with a powdered segnetoelectric filler, developed on conventional “smooth” and rough glass substrates are presented. It is shown that electroluminescent structures on rough surfaces have a brightness approximately two times higher than that of similar structures developed on a “smooth” substrate. Ul’yanovsk State University, 42, L. Tolstoi St., Ul’yanovsk, 432700, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 4, pp. 507–512, July–August, 1997.     

Experimental study of the emission spread at gyrotron cathodes by current-voltage characteristics

A scheme for automated study of current-voltage characteristics of gyroresonance devices is developed. The effective emission spread at the cathodes of powerful gyrotrons is studied by analysis of current-voltage characteristics. Experimental data on the effective emission spread parameter for different modes are given. The permissible emission spread at the cathodes of powerful gyrotrons is estimated, and the dependence of the electron beam parameters on the cathode emission spread is presented. A complex measurement technique showing the contribution of different physical mechanisms to the cathode emission spread is proposed. Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 40, No. 4, pp. 506–516, April, 1997.